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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geostandards and geoanalytical research 4 (1980), S. 0 
    ISSN: 1751-908X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Sixteen international and six inter-laboratory geochemical reference samples have been analysed for their selenium content. No previous Sedata are available for thirteen of them. Selenium has been separated from silicate matrix by volatilization and was determined with flameless atomic absorption spectrometry. An outline of the procedure is given. The limit of detection is 10 ng Se per 1 g of sample. Time required for one full analysis is 1.2 to 2.5 hours depending on amount of sample to be volatilized.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Earth and Planetary Science Letters 79 (1986), S. 93-106 
    ISSN: 0012-821X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1359-0189
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The Lau Basin is a typical example of an active back-arc basin between a remnant (Lau ridge) and an active volcanic arc (Tofua volcanic arc) (Fig. la). The northern spreading axis at the centre of the basin consists of tholeiitic basalt. The southern segment, located 75 km closer to the Tofua ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 116 (1994), S. 365-380 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Chemical data of 39 fresh basaltic glasses from the East Pacific Rise (EPR) between 6 and 30°S and Pb, Sr, and Nd isotopic compositions of 12 basalt glasses are presented. Major and trace element data indicate a wide compositional range, including primitive basalts (Mg#=0.67) and highly evolved FeTi-basalts (Mg#=0.34) [molMg/(Mg+Fe2+)]. The compositional range can be attributed to low-pressure fractional crystallization. Fractionation-corrected major element concentrations provide evidence for varying mantle melting conditions. Calculations of the melting conditions suggest melt generation in a rising upper mantle column between 20 and 10 kbar, at temperatures between 1430 and 1280°C, and total degrees of partial melting between 17 and 20% by weight. Leached and hand-picked basalt glasses display large variations in 87Sr/86Sr (0.70235–0.70270), 143Nd/144Nd (0.51312–0.51323), and 206Pb/204Pb (18.064–18.665), but are similar to other N-type MORB from the EPR. The isotopic ratios of basalts from 13 to 23°S show strong correlations and delineate two systematic trends. From 23 to 17°S, 87Sr/86Sr and Pb isotope ratios increase and 143Nd/144Nd decrease in agreement with previous results (Mahoney et al. 1989). A reverse trend is indicated by basalts from 17 to 13°S. However, K/Ti and (La/Sm)N continuously increase from 23 to 13°S. This opposite behavior indicates a recent decoupling of isotopic and minor element ratios in the mantle between 13 and 17°S. North of 13.5°S (Garrett Fracture Zone), isotopic data show no systematic variation with ridge location and display an overall weaker covariation. The results suggest that the isotopic variations and ridge segmentation appear to be unrelated and that major ridge offsets apparently coincide with changes in mantle melting conditions (P, T, F) (F, degrees of melting). There is no evidence for a systematic relationship between calculated melting conditions and second order ridge segmentation. Our isotopic data provide further evidence for regionally confined chemical variations in the mantle at 5 to 30°S. We interpret the isotopic trends as reflecting melting of distinct smallvolume and old enriched mantle components. In contrast, variations in trace elements are attributed to young mantle differentiation processes.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 301 (1980), S. 436-436 
    ISSN: 1618-2650
    Keywords: Best. von Bor in Silicaten ; Spektralphotometrie ; Stellungnahme
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 332 (1988), S. 140-143 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An ICP-AES method for the determination of 12 rare earth elements and Y is described. Following a Na2O2-sinter dissolution of silicate materials the REE and Y were separated and concentrated using ion-exchange chromatography. The dissolution and separation procedures are described in detail. Numerous tests show good recovery of the REE. Spectral interferences were quantified and discussed. The precision is better than 5% (r.s.d.) for all measured REE, except Pr. The accuracy was tested by analyzing more than 30 international reference samples, the results are in good agreement with published data. In this paper we present our latest data from 6 new reference samples.
    Type of Medium: Electronic Resource
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  • 8
    Publication Date: 2016-12-21
    Description: Alkaline volcanic rocks including nephelinites, basanites and trachybasalts dredged from the volcanic pedestal of Rakahanga Atoll and from a volcanic edifice with 100 satellite volcanoes at the eastern edge of the Manihiki Plateau, ca. 40 km southwest of the atoll, fall well within the category of EM-type ocean island basalts. They indicate a hotspot involvement during the formation of the plateau basement. The rocks are thought to be products of explosive eruptions which took place subaerially or in shallow water in the Aptian. The volcanoes, together with other volcanic eruption centers, most likely were responsible for the formation of the 230 m thick volcaniclastite layer which rests on the basement for at least 5000 km2 of the eastern part of the Manihiki Plateau. Erosion has prevented any substantial sediment cover on the volcanic cone field and most of the slope of Rakahanga and thin pelagic limestones were deposited instead at least since the Maastrichtian.
    Type: Article , PeerReviewed
    Format: text
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  • 9
    Publication Date: 2016-05-17
    Description: IN 1989, the submersible Nautile discovered one of the most active hydrothermal fields on the modern ocean floor, in the Lau back-arc basin (Fig. 1). The field contains high-temperature white and black smokers, and as we report here, its characteristics contrast strongly with those of the hydrothermal fields found at normal mid-ocean ridges. The main differences are the acidity (pH as low as 2), chemistry and temperature (up to 400 °C) of the hydrothermal fluids, the composition of the ore deposits, and the volcanic and tectonic environments. The fluids also have very high concentrations of trace metals, and primary gold is present in the accompanying mineral deposits. Our data show that these back-arc deposits in the Lau Basin are intermediate between typical mid-ocean-ridge mineralization and massive sulphide deposits of the Kuroko type.
    Type: Article , PeerReviewed
    Format: text
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  • 10
    Publication Date: 2012-02-23
    Description: Huge amounts of CH4 bound in natural gas hydrates lead to the idea of using hydrate bearing sediments as an energy resource. Natural gas hydrates remain stable as long as they are in mechanical, thermal and chemical equilibrium with their environments. Thus, for the production of gas from hydrate bearing sediments, at least one of these equilibrium states must be disturbed by depressurization, thermal stimulation or addition of chemicals such as CO2. In the framework of the German national gas hydrate research project SUGAR (Submarine Gas Hydrate Reservoirs), all three reaction routes – alone or in combination – are tested. The aim is to find the most flexible and efficient, but also environmentally friendly method for gas production from hydrates. One method in this context is the thermal stimulation using in situ combustion. Therefore, a heat exchange reactor was designed and tested for the catalytic oxidation of methane. Furthermore, a large scale reservoir simulator (Volume 425 l) was realized, to synthesize hydrates in sediments under conditions similar to nature and to test the efficiency of the reactor. Thermocouples placed in the reservoir simulator collect data regarding the expansion of the heat front, respectively. These data are used for numerical simulations for up scaling from laboratory to field conditions. However, thermal stimulation may be used alone or in combination with CO2 sequestration. Therefore, laboratory studies on the methane production from pure hydrate phases as well as hydrate bearing sediments by use of CO2 injection are investigated using several analytic tools such as Nuclear Magnetic Resonance spectroscopy, confocal Raman spectroscopy and X-ray diffraction. In this study we present the experimental set up of the large scale reservoir simulator and the reactor design. Preliminary results show that the catalytic oxidation of CH4 in a countercurrent heat exchange reactor operated as a temperature controlled, autothermal reaction outside of the flammability limits of CH4 is a safe and promising tool for the thermal stimulation of hydrates. In addition, preliminary results from the laboratory studies on the CO2-CH4 swapping process in pure and pore-filling gas hydrates are presented focussing on the kinetics of this process.
    Type: Conference or Workshop Item , NonPeerReviewed
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