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  • 1
    Publication Date: 2024-01-13
    Description: This dataset contains concentrations of dissolved trace metals (Al, Mn, Co, Ni, Cu, Zn, Cd, and Pb), macro-nutrients (Si and PO4), major elements (Li, Ca, K, Mg, and Sr) and Pb isotope compositions (206Pb/207Pb, 208Pb/206Pb) from a time-series station (Station A, ~700 m water depth) at the Gulf of Aqaba, northern Red Sea. Vertical water column profiles were collected between January 2017 and November 2018 on a monthly-daily resolution as part of the GEOTRACES REDMAST campaign. Seawater samples were collected using GO-Flo bottles, filtered (0.2 µm) and acidified to pH〈1.8. Samples for trace metal concentrations and Pb isotopes were pre-concentrated using the the NOBIAS chelate PA-1 resin and measured using an Agilent 7500cx Magnetic Sector ICP-MS and a Thermo-Scientific Neptune Plus Multi Collector ICP-MS, respectively (Benaltabet, T., Lapid, G., & Torfstein, A. (2020). Seawater Pb concentration and isotopic composition response to daily time scale dust storms in the Gulf of Aqaba, Red Sea. Marine Chemistry, 227, 103895.‏). Macro-nutrient concentrations were measured using a Flow Injection Quik-Chem 8500 Auto-analyzer (Grasshoff, K., Kremling, K., & Ehrhardt, M. (Eds.). (2009). Methods of seawater analysis. John Wiley & Sons.‏). Major elements were analyzed as their ratio to Na by sample-standard bracketing using an Agilent Technology Varian-720 ICP-OES (Steiner, Z., Turchyn, A. V., Harpaz, E., & Silverman, J. (2018). Water chemistry reveals a significant decline in coral calcification rates in the southern Red Sea. Nature communications, 9(1), 3615.‏).
    Keywords: Aluminium; Cadmium; Calcium; Cobalt; Copper; DATE/TIME; Density, sigma-theta (0); DEPTH, water; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; GOFLO; Go-Flo bottles; Gulf_of_Aqaba-Station-A; isotope compositions; LATITUDE; Lead; Lead-206/Lead-207 ratio; Lead-208/Lead-206 ratio; Lithium; LONGITUDE; macronutrients; Magnesium; major elements; Manganese; Nickel; oceanographic time series; Pb isotopes; Phosphate; Potassium; Red Sea; Salinity; seawater; Silicate; Standard deviation; Strontium; Temperature, water; trace metals; Zinc
    Type: Dataset
    Format: text/tab-separated-values, 4819 data points
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2022-01-31
    Description: Lead concentrations [Pb] and isotope ratios (Pb-206/Pb-207, Pb-208/Pb-207) have been measured in samples of total suspended particulate (TSP) aerosols, seawater, and suspended and sinking particles in the Gulf of Aqaba (GOA), Red Sea. Isotope ratios of Pb in seawater and in the soluble fraction of Pb in atmospheric TSP were similar suggesting that TSP is an important source of Pb in this area. Pb concentrations in seawater measured in this study (max 76.8 pmol kg(-1)) were much lower than those recorded at the same location in 2003-2004 (up to 1000 pmol kg(-1)). Changes in Pb isotope ratios in TSP depositions in these years indicate that leaded gasoline was responsible for the high dissolved Pb in GOA more than a decade ago and that recent regulation reduced Pb contamination. The similarity in Pb isotope ratios in suspended and sinking particles implies close interactions between these two size fractions. This study demonstrates the effect of the phasing out of leaded gasoline on TSP and seawater Pb chemistry in the Northern GOA; the rate of change in dissolved Pb concentrations in the GOA is faster than that reported for the open ocean possibly due to higher particle scavenging and the relatively short residence time of deep water in the Basin.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Limitation Availability
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