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  • 1
    Online Resource
    Online Resource
    Asociacion Meteorologica Espanola ; 2018
    In:  Acta de las Jornadas Científicas de la Asociación Meteorológica Española Vol. 1, No. 35 ( 2018-02-09)
    In: Acta de las Jornadas Científicas de la Asociación Meteorológica Española, Asociacion Meteorologica Espanola, Vol. 1, No. 35 ( 2018-02-09)
    Abstract: Los espectrofotómetros Brewers tienen como principal tarea medir la columna total de ozono (TOC). Estos instrumentos son calibrados respecto a instrumentos de referencia viajeros como el Brewer #017, operado por IOS y calibrado frente a la triada de Canadá o, más reciente, con respecto al Brewer #185 que forma parte de la Triada del Centro de Calibración Regional Brewer para Europa (RBCC-E) situado en el Observatorio Atmosférico de Izaña y perteneciente a la Agencia Estatal de Meteorología (AEMET).En este trabajo se pretende, en primer lugar, mostrar cómo es el ciclo anual del ozono estratosférico en las Islas Canarias, indicando su período de máxima y mínima concentración y, en segundo lugar, mostrar el grado de acuerdo entre las medidas de ozono llevadas a cabo por los tres instrumentos, Brewer #157, #183 y #185 que forman la triada RBCC-E. En este sentido, y teniendo en cuenta que cada Brewer realiza a lo largo del día un elevado número de observaciones, se visto adecuado calcular su valor medio.En este trabajo se han empleado dos conjuntos de datos para evaluar el grado de acuerdo entre los tres instrumentos. El primer conjunto de datos incluye todas las medidas hechas por los Brewers mientras el segundo sólo considera las medidas que de manera simultánea han sido realizadas por los tres instrumentos. Los resultados indican que este segundo conjunto de datos muestra una mejor estimación del acuerdo existente entre los tres Brewers. No obstante, ambos conjuntos indican que la desviación entre los valores medios diarios de los tres Brewers #157, #183 y #185 que forman la RBCC-E es ~0.5%.
    Type of Medium: Online Resource
    ISSN: 2605-2202 , 2605-2199
    URL: Issue
    Language: Unknown
    Publisher: Asociacion Meteorologica Espanola
    Publication Date: 2018
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  • 2
    In: Atmospheric Measurement Techniques, Copernicus GmbH, Vol. 15, No. 15 ( 2022-08-11), p. 4547-4567
    Abstract: Abstract. Retrieving high-precision concentrations of atmospheric trace gases from FTIR (Fourier transform infrared) spectrometry requires a precise knowledge of the instrumental performance. In this context, this paper examines the impact on the ozone (O3) retrievals of several approaches used to characterize the instrumental line shape (ILS) function of ground-based FTIR spectrometers within NDACC (Network for the Detection of Atmospheric Composition Change). The analysis has been carried out at the subtropical Izaña Observatory (IZO, Spain) by using the 20-year time series of the high-resolution FTIR solar absorption spectra acquired between 1999 and 2018. The theoretical quality assessment and the comparison to independent O3 observations available at IZO (Brewer O3 total columns and electrochemical concentration cell, ECC, sondes) reveal consistent findings. The inclusion of a simultaneous retrieval of the ILS parameters in the O3 retrieval strategy allows, on the one hand, a rough instrumental characterization to be obtained and, on the other hand, the precision of the FTIR O3 products to be slightly improved. The improvement is of special relevance above the lower stratosphere, where the cross-interference between the O3 vertical distribution and the instrumental performance is more significant. However, it has been found that the simultaneous ILS retrieval leads to a misinterpretation of the O3 variations on daily and seasonal scales. Therefore, in order to ensure the independence of the O3 retrievals and the instrumental response, the optimal approach to deal with the FTIR instrumental characterization is found to be the continuous monitoring of the ILS function by means of independent observations, such as gas cell measurements.
    Type of Medium: Online Resource
    ISSN: 1867-8548
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2022
    detail.hit.zdb_id: 2505596-3
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  • 3
    In: Atmospheric Measurement Techniques, Copernicus GmbH, Vol. 11, No. 7 ( 2018-07-13), p. 4059-4072
    Abstract: Abstract. Total ozone column measurements can be made using Brewer spectrophotometers, which are calibrated periodically in intercomparison campaigns with respect to a reference instrument. In 2003, the Regional Brewer Calibration Centre for Europe (RBCC-E) was established at the Izaña Atmospheric Research Center (Canary Islands, Spain), and since 2011 the RBCC-E has transferred its calibration based on the Langley method using travelling standard(s) that are wholly and independently calibrated at Izaña. This work is focused on reporting the consistency of the measurements of the RBCC-E triad (Brewer instruments #157, #183 and #185) made at the Izaña Atmospheric Observatory during the period 2005–2016. In order to study the long-term precision of the RBCC-E triad, it must be taken into account that each Brewer takes a large number of measurements every day and, hence, it becomes necessary to calculate a representative value of all of them. This value was calculated from two different methods previously used to study the long-term behaviour of the world reference triad (Toronto triad) and Arosa triad. Applying their procedures to the data from the RBCC-E triad allows the comparison of the three instruments. In daily averages, applying the procedure used for the world reference triad, the RBCC-E triad presents a relative standard deviation equal to σ = 0.41 %, which is calculated as the mean of the individual values for each Brewer (σ157 = 0.362 %, σ183 = 0.453 % and σ185 = 0.428 %). Alternatively, using the procedure used to analyse the Arosa triad, the RBCC-E presents a relative standard deviation of about σ = 0.5 %. In monthly averages, the method used for the data from the world reference triad gives a relative standard deviation mean equal to σ = 0.3 % (σ157 = 0.33 %, σ183 = 0.34 % and σ185 = 0.23 %). However, the procedure of the Arosa triad gives monthly values of σ = 0.5 %. In this work, two ozone data sets are analysed: the first includes all the ozone measurements available, while the second only includes the simultaneous measurements of all three instruments. Furthermore, this paper also describes the Langley method used to determine the extraterrestrial constant (ETC) for the RBCC-E triad, the necessary first step toward accurate ozone calculation. Finally, the short-term or intraday consistency is also studied to identify the effect of the solar zenith angle on the precision of the RBCC-E triad.
    Type of Medium: Online Resource
    ISSN: 1867-8548
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2505596-3
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  • 4
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 22, No. 1 ( 2022-01-10), p. 295-317
    Abstract: Abstract. The objective of this study is to derive methane (CH4) emissions from three landfills, which are found to be the most significant CH4 sources in the metropolitan area of Madrid in Spain. We derive CH4 emissions from the CH4 enhancements observed by spaceborne and ground-based instruments. We apply satellite-based measurements from the TROPOspheric Monitoring Instrument (TROPOMI) and the Infrared Atmospheric Sounding Interferometer (IASI) together with measurements from the ground-based COllaborative Carbon Column Observing Network (COCCON) instruments. In 2018, a 2-week field campaign for measuring the atmospheric concentrations of greenhouse gases was performed in Madrid in the framework of Monitoring of the Greenhouse Gases Concentrations in Madrid (MEGEI-MAD) project. Five COCCON instruments were deployed at different locations around the Madrid city center, enabling the observation of total column-averaged CH4 mixing ratios (XCH4). Considering the prevalent wind regimes, we calculate the wind-assigned XCH4 anomalies for two opposite wind directions. Pronounced bipolar plumes are found when applying the method to NO2, which implies that our method of wind-assigned anomaly is suitable to estimate enhancements of trace gases at the urban level from satellite-based measurements. For quantifying the CH4 emissions, the wind-assigned plume method is applied to the TROPOMI XCH4 and to the lower tropospheric CH4 / dry-air column ratio (TXCH4) of the combined TROPOMI+IASI product. As CH4 emission strength we estimate 7.4 × 1025 ± 6.4 × 1024 molec. s−1 from the TROPOMI XCH4 data and 7.1 × 1025 ± 1.0 × 1025 molec. s−1 from the TROPOMI+IASI merged TXCH4 data. We use COCCON observations to estimate the local source strength as an independent method. COCCON observations indicate a weaker CH4 emission strength of 3.7 × 1025 molec. s−1 from a local source (the Valdemingómez waste plant) based on observations from a single day. This strength is lower than the one derived from the satellite observations, and it is a plausible result. This is because the analysis of the satellite data refers to a larger area, covering further emission sources in the study region, whereas the signal observed by COCCON is generated by a nearby local source. All emission rates estimated from the different observations are significantly larger than the emission rates provided via the official Spanish Register of Emissions and Pollutant Sources.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2022
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 5
    Online Resource
    Online Resource
    Asociacion Meteorologica Espanola ; 2018
    In:  Acta de las Jornadas Científicas de la Asociación Meteorológica Española Vol. 1, No. 35 ( 2018-02-09)
    In: Acta de las Jornadas Científicas de la Asociación Meteorológica Española, Asociacion Meteorologica Espanola, Vol. 1, No. 35 ( 2018-02-09)
    Abstract: En noviembre del 2003 y bajo el amparo de la Organización Mundial Meteorología (OMM) y el Programa para la Observación Global de la Atmósfera (GAW) se estableció el Centro de calibración Regional Brewer para Europa (RBCC-E) en el Observatorio Atmosférico de Izaña (IZO) perteneciente a la Agencia Estatal de Meteorología. El RBCC-E es la referencia europea lo que le permite utilizar sus observaciones para calibrar estos Brewers. El RBCC-E organiza intercomparaciones anuales, que alternan su sede entre la estación de Radiosondeo El Arenosillo (Huelva) perteneciente al Instituto Nacional de Técnica Aeroespacial (INTA) y el Observatorio Atmosférico de Arosa (Suiza) operado por Meteoswiss.La XII Campaña de calibración se realizó en El Arenosillo entre los días del 29 de mayo al 7 de Junio, 2017.  En esta campaña participaron más de 20 Brewers pertenecientes a 11 organizaciones tanto servicios meteorológicos nacionales como instituciones privadas. Además, se pudo realizar una calibración espectral en el rango ultravioleta gracias a la participación de la referencia estándar viajera QASUME perteneciente al centro de calibración Mundial para ultravioleta (WCC-UV).En este trabajo se presenta una visión general del estado inicial y final de la calibración del Brewer#102, indicando los principales parámetros que han sido tenidos en cuenta en su calibración: lámpara estándar, corrección de filtros, resultados del test de dispersión y transferencia de la nueva ETC (Constante extra-terrestre). También, y debido a que el instrumento es un Brewer de monocromador simple se calculó su corrección por stray light.
    Type of Medium: Online Resource
    ISSN: 2605-2202 , 2605-2199
    URL: Issue
    Language: Unknown
    Publisher: Asociacion Meteorologica Espanola
    Publication Date: 2018
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  • 6
    In: Atmospheric Measurement Techniques, Copernicus GmbH, Vol. 11, No. 6 ( 2018-06-27), p. 3759-3768
    Abstract: Abstract. In this contribution we present the wavelength calibration of the travelling reference Brewer spectrometer of the Regional Brewer Calibration Center for Europe (RBCC-E) at PTB in Braunschweig, Germany. The wavelength calibration is needed for the calculation of the ozone absorption coefficients used by the Brewer ozone algorithm. In order to validate the standard procedure for determining Brewer's wavelength scale, a calibration has been performed by using a tunable laser source at PTB in the framework of the EMRP project ENV59 ATMOZ “Traceability for the total column ozone”. Here we compare these results to those of the standard procedure for the wavelength calibration of the Brewer instrument. Such a comparison allows validating the standard methodology used for measuring the ozone absorption coefficient with respect to several assumptions. The results of the laser-based calibrations reproduces those obtained by the standard operational methodology and shows that there is an underestimation of 0.8 % of the ozone absorption coefficients due to the use of the parametrized slit functions.
    Type of Medium: Online Resource
    ISSN: 1867-8548
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2505596-3
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  • 7
    In: Atmospheric Measurement Techniques, Copernicus GmbH, Vol. 11, No. 9 ( 2018-09-11), p. 5167-5180
    Abstract: Abstract. Non-ideal angular response of a spectroradiometer is a well-known error source of spectral UV measurements and for that reason instrument specific cosine error correction is applied. In this paper, the performance of the cosine error correction method of Brewer spectral UV measurements in use at the Finnish Meteorological Institute (FMI) is studied. Ideally, the correction depends on the actual sky radiation distribution, which can change even during one spectral scan due to rapid changes in cloudiness. The FMI method has been developed to take into account the changes in the ratio of direct to diffuse sky radiation and it derives a correction coefficient for each measured wavelength. Measurements of five Brewers were corrected for the cosine error and the results were compared to the reference travelling spectroradiometer (QASUME). Measurements were performed during the RBCC-E (Regional Brewer Calibration Center – Europe) X Campaign held at El Arenosillo, Huelva (37∘ N, 7∘ W), Spain, in 2015. In addition, results of site audits of FMI's Brewers in Sodankylä (67∘ N, 27∘ E) and Jokioinen (61∘ N, 24∘ E) during 2002–2014 were studied. The results show that the spectral cosine error correction varied between 4 and 14 %. After that the correction was applied to Brewer UV spectra the relative differences between the QASUME and the Brewer diminished even by 10 %. The study confirms that the method, originally developed for measurements at high latitudes, can be used at mid-latitudes as well. The method is applicable to other Brewers as far as the required input parameters, i.e. total ozone, aerosol information, albedo, instrument specific angular response and slit function are available.
    Type of Medium: Online Resource
    ISSN: 1867-8548
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2505596-3
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  • 8
    In: Current Applied Physics, Elsevier BV, Vol. 14, No. 1 ( 2014-1), p. 72-81
    Type of Medium: Online Resource
    ISSN: 1567-1739
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2014
    detail.hit.zdb_id: 2039065-8
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  • 9
    In: Atmospheric Measurement Techniques, Copernicus GmbH, Vol. 15, No. 8 ( 2022-04-28), p. 2557-2577
    Abstract: Abstract. Accurate observations of atmospheric ozone (O3) are essential to monitor in detail its key role in atmospheric chemistry. The present paper examines the performance of different O3 retrieval strategies from FTIR (Fourier transform infrared) spectrometry by using the 20-year time series of the high-resolution solar spectra acquired from 1999 to 2018 at the subtropical Izaña Observatory (IZO, Spain) within NDACC (Network for the Detection of Atmospheric Composition Change). In particular, the effects of two of the most influential factors have been investigated: the inclusion of a simultaneous atmospheric temperature profile fit and the spectral O3 absorption lines used for the retrievals (the broad spectral region of 1000–1005 cm−1 and single micro-windows between 991 and 1014 cm−1). Additionally, the water vapour (H2O) interference in O3 retrievals has been evaluated, with the aim of providing an improved O3 strategy that minimises its impact and, therefore, could be applied at any NDACC FTIR station under different humidity conditions. The theoretical and experimental quality assessments of the different FTIR O3 products (total column (TC) amounts and volume mixing ratio (VMR) profiles) provide consistent results. Combining a simultaneous temperature retrieval with the optimal selection of single O3 micro-windows results in superior FTIR O3 products, with a precision of better than 0.6 %–0.7 % for O3 TCs as compared to coincident NDACC Brewer observations taken as a reference. However, this improvement can only be achieved provided the FTIR spectrometer is properly characterised and stable over time. For unstable instruments, the temperature fit is found to exhibit a strong negative influence on O3 retrievals due to the increase in the cross-interference between the temperature retrieval and instrumental performance (given by the instrumental line shape function and measurement noise), which leads to a worsening of the precision of FTIR O3 TCs of up to 2 %. This cross-interference becomes especially noticeable beyond the upper troposphere/lower stratosphere, as documented theoretically as well as experimentally by comparing FTIR O3 profiles to those measured using electrochemical concentration cell (ECC) sondes within NDACC. Consequently, it should be taken into account for the reliable monitoring of the O3 vertical distribution, especially over long-term timescales.
    Type of Medium: Online Resource
    ISSN: 1867-8548
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2022
    detail.hit.zdb_id: 2505596-3
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  • 10
    In: Journal of Instrumentation, IOP Publishing, Vol. 17, No. 01 ( 2022-01-01), p. P01013-
    Abstract: The semiconductor tracker (SCT) is one of the tracking systems for charged particles in the ATLAS detector. It consists of 4088 silicon strip sensor modules. During Run 2 (2015–2018) the Large Hadron Collider delivered an integrated luminosity of 156 fb -1 to the ATLAS experiment at a centre-of-mass proton-proton collision energy of 13 TeV. The instantaneous luminosity and pile-up conditions were far in excess of those assumed in the original design of the SCT detector. Due to improvements to the data acquisition system, the SCT operated stably throughout Run 2. It was available for 99.9% of the integrated luminosity and achieved a data-quality efficiency of 99.85%. Detailed studies have been made of the leakage current in SCT modules and the evolution of the full depletion voltage, which are used to study the impact of radiation damage to the modules.
    Type of Medium: Online Resource
    ISSN: 1748-0221
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 2235672-1
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