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  • 11
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 34 (2007): L10601, doi:10.1029/2006GL028790.
    Description: Air-water gas transfer influences CO2 and other climatically important trace gas fluxes on regional and global scales, yet the magnitude of the transfer is not well known. Widely used models of gas exchange rates are based on empirical relationships linked to wind speed, even though physical processes other than wind are known to play important roles. Here the first field investigations are described supporting a new mechanistic model based on surface water turbulence that predicts gas exchange for a range of aquatic and marine processes. Findings indicate that the gas transfer rate varies linearly with the turbulent dissipation rate to the inline equation power in a range of systems with different types of forcing - in the coastal ocean, in a macro-tidal river estuary, in a large tidal freshwater river, and in a model (i.e., artificial) ocean. These results have important implications for understanding carbon cycling.
    Description: This research was performed and the manuscript prepared with support from: the National Science Foundation (OCE-03-27256, OCE-05-26677, ATM 01-20569, and DEB-05-32075), the Office of Naval Research Young Investigator Program (N00014-04-1-0621), the Hudson River Foundation (010/02A), NOAA (NA03OAR4320179), the Marie Curie Training Site Fellowship (HPMFCT- 2002-01865), the NERC (NER/B/S/2003/00844), the David and Lucille Packard Foundation, and the LDEO Climate Center.
    Keywords: Air-sea gas exchange ; Turbulent dissipation rate ; Carbon
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 12
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C07009, doi:10.1029/2008JC005008.
    Description: Results from a rain and gas exchange experiment (Bio2 RainX III) at the Biosphere 2 Center demonstrate that turbulence controls the enhancement of the air-sea gas transfer rate (or velocity) k during rainfall, even though profiles of the turbulent dissipation rate ɛ are strongly influenced by near-surface stratification. The gas transfer rate scales with ɛ inline equation for a range of rain rates with broad drop size distributions. The hydrodynamic measurements elucidate the mechanisms responsible for the rain-enhanced k results using SF6 tracer evasion and active controlled flux technique. High-resolution k and turbulence results highlight the causal relationship between rainfall, turbulence, stratification, and air-sea gas exchange. Profiles of ɛ beneath the air-sea interface during rainfall, measured for the first time during a gas exchange experiment, yielded discrete values as high as 10−2 W kg−1. Stratification modifies and traps the turbulence near the surface, affecting the enhancement of the transfer velocity and also diminishing the vertical mixing of mass transported to the air-water interface. Although the kinetic energy flux is an integral measure of the turbulent input to the system during rain events, ɛ is the most robust response to all the modifications and transformations to the turbulent state that follows. The Craig-Banner turbulence model, modified for rain instead of breaking wave turbulence, successfully predicts the near-surface dissipation profile at the onset of the rain event before stratification plays a dominant role. This result is important for predictive modeling of k as it allows inferring the surface value of ɛ fundamental to gas transfer.
    Description: This work was funded by a generous grant from the David and Lucile Packard Foundation and the Lamont-Doherty Earth Observatory Climate Center. Additional funding was provided by the National Science Foundation (OCE-05-26677) and the Office of Naval Research Young Investigator Program (N00014-04-1-0621).
    Keywords: Turbulence ; Rain ; Gas transfer
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 13
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C01025, doi:10.1029/2002JC001616.
    Description: Gas transfer rates were determined from relaxed eddy accumulation (REA) measurements of the flux of dimethylsulfide (DMS) over the northeastern Pacific Ocean. This first application of the REA technique for the measurement of DMS fluxes over the open ocean produced estimates of the gas transfer rate that are on average higher than those calculated from commonly used parameterizations. The relationship between the total gas transfer rate and wind speed was found to be gas kgas = 0.53 (±0.05) U102. Because of the effect of the airside resistance, the waterside transfer rate was up to 16% higher than kgas. Removal of the airside transfer component from the total transfer rate resulted in a relation between wind speed and waterside transfer of k660 = 0.61 (±0.06) U102. However, DMS fluxes showed a high degree of scatter that could not readily be accounted for by wind speed and atmospheric stability. It has to be concluded that these measurements do not permit an accurate parameterization of gas transfer as a function of wind speed.
    Description: Funding for this work came from the Netherlands Organization for Scientific Research (NWO) and from the NOP project: ‘Micrometeorology of air/sea fluxes of carbon dioxide’ No. 951203. This work was also supported in part by the Office of Naval Research Grant No. N00014-00-1-0403, NOAA CICOR Grant No. NA87RJ0445, and the U.S. National Science Foundation Grant ATM- 0120569.
    Keywords: Dimethylsulfide ; DMS ; Relaxed eddy accumulation ; Micrometeorology
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 14
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C08S18, doi:10.1029/2003JC001806.
    Description: Rain has been shown to significantly enhance the rate of air-water gas exchange in fresh water environments, and the mechanism behind this enhancement has been studied in laboratory experiments. In the ocean, the effects of rain are complicated by the potential influence of density stratification at the water surface. Since it is difficult to perform controlled rain-induced gas exchange experiments in the open ocean, an SF6 evasion experiment was conducted in the artificial ocean at Biosphere 2. The measurements show a rapid depletion of SF6 in the surface layer due to rain enhancement of air-sea gas exchange, and the gas transfer velocity was similar to that predicted from the relationship established from freshwater laboratory experiments. However, because vertical mixing is reduced by stratification, the overall gas flux is lower than that found during freshwater experiments. Physical measurements of various properties of the ocean during the rain events further elucidate the mechanisms behind the observed response. The findings suggest that short, intense rain events accelerate gas exchange in oceanic environments.
    Description: Funding was provided by a generous grant from the David and Lucile Packard Foundation.
    Keywords: Gas exchange ; Rain ; SF6 ; Turbulence ; Stratification
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 15
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C08S09, doi:10.1029/2003JC001960.
    Description: The most commonly used flux-profile relationships are based on Monin-Obukhov (MO) similarity theory. These flux-profile relationships are required in indirect methods such as the bulk aerodynamic, profile, and inertial dissipation methods to estimate the fluxes over the ocean. These relationships are almost exclusively derived from previous field experiments conducted over land. However, the use of overland measurements to infer surface fluxes over the ocean remains questionable, particularly close to the ocean surface where wave-induced forcing can affect the flow. This study investigates the flux profile relationships over the open ocean using measurements made during the 2000 Fluxes, Air-Sea Interaction, and Remote Sensing (FAIRS) and 2001 GasEx experiments. These experiments provide direct measurement of the atmospheric fluxes along with profiles of water vapor and temperature. The specific humidity data are used to determine parameterizations of the dimensionless gradients using functional forms of two commonly used relationships. The best fit to the Businger-Dyer relationship [ Businger, 1988 ] is found using an empirical constant of a q = 13.4 ± 1.7. The best fit to a formulation that has the correct form in the limit of local free convection [e.g., Wyngaard, 1973 ] is found using a q = 29.8 ± 4.6. These values are in good agreement with the consensus values from previous overland experiments and the Coupled Ocean-Atmosphere Response Experiment (COARE) 3.0 bulk algorithm [ Fairall et al., 2003 ]; e.g., the COARE algorithm uses empirical constants of 15 and 34.2 for the Businger-Dyer and convective forms, respectively. Although the flux measurements were made at a single elevation and local similarity scaling is applied, the good agreement implies that MO similarity is valid within the marine atmospheric surface layer above the wave boundary layer.
    Description: The FAIRS work was supported by the Office of Naval Research grant N00014-00-1-0403 while the GasEx work was supported by the National Science Foundation grant OCE-9986724.
    Keywords: Air-sea fluxes ; Flux profile relationships ; Marine boundary layer
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 16
    Publication Date: 2022-05-26
    Description: Dataset: Benthic and acidification data from the Palmyra Atoll
    Description: Benthic Ecosystem and Acidification Measuring System (BEAMS) data from two sites on the western terrace of the Palmyra Atoll collected during 2014 (BEAMS project) For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/666280
    Description: NSF Division of Ocean Sciences (NSF OCE) OCE-1316006, NSF Division of Ocean Sciences (NSF OCE) OCE-1316047
    Repository Name: Woods Hole Open Access Server
    Type: Dataset
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  • 17
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L03611, doi:10.1029/2010GL046179.
    Description: The metabolism of Cayo Enrique Reef, Puerto Rico, was studied using in situ methods during March 2009. Benthic O2 fluxes were used to calculate net community production using both the boundary layer gradient and enclosure techniques. The boundary layer O2 gradient and the drag coefficients were used to calculate productivity ranging from −12.3 to 13.7 mmol O2 m−2 h−1. Productivity measurements from the enclosure method ranged from −11.0 to 12.9 mmol O2 m−2 h−1. During the study, the mean hourly difference between the methods was 0.65 mmol O2 m−2 h−1 (r2 = 0.92), resulting in well-reconciled estimates of net community production between the boundary layer (−33.1 mmol m−2 d−1) and enclosure (−46.3 mmol m−2 d−1) techniques. The results of these independent approaches corroborate quantified rates of metabolism at Cayo Enrique Reef. Close agreement between methods demonstrates that boundary layer measurements can provide near real-time assessments of coral reef health.
    Keywords: Coral reefs ; Productivity ; Boundary layer methods
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 18
    Publication Date: 2024-02-17
    Keywords: 33GC20101121-track; Algorithm; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from GLOBALVIEW-CO2; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the NCEP/NCAR 40-Year Reanalysis Project; extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at equilibrator temperature (wet air); Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Gulf Challenger; LATITUDE; LONGITUDE; Pressure, atmospheric; Pressure, atmospheric, interpolated; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity; Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; UNH_CO2_20101121; xCO2 (air), interpolated; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 8634 data points
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  • 19
    Publication Date: 2024-02-17
    Keywords: 33GC20120111-track; Algorithm; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from GLOBALVIEW-CO2; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the NCEP/NCAR 40-Year Reanalysis Project; extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at equilibrator temperature (wet air); Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Gulf Challenger; LATITUDE; LONGITUDE; Pressure, atmospheric; Pressure, atmospheric, interpolated; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity; Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; UNH_CO2_20120111; xCO2 (air), interpolated; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 16790 data points
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  • 20
    Publication Date: 2024-02-17
    Keywords: 33GC20110616-track; Algorithm; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from GLOBALVIEW-CO2; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the NCEP/NCAR 40-Year Reanalysis Project; extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at equilibrator temperature (wet air); Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Gulf Challenger; LATITUDE; LONGITUDE; Pressure, atmospheric; Pressure, atmospheric, interpolated; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity; Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; UNH_CO2_20110616; xCO2 (air), interpolated; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 24518 data points
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