Description: Arctic deep-sea sediments often record intervals of negative inclination of natural remanence that are tens of centimeters thick, implying magnetic excursions with durations of tens of thousand years that far exceed excursion durations estimated elsewhere, and the lack of tight age control usually provides excessive freedom in the labeling of Arctic excursions. Fortuitous variations in sedimentation rate have been invoked to explain the “amplified” excursions. Alternating field demagnetization of natural remanent magnetization (NRM) of sediment cores 08JPC, 10JPC, 11JPC, and 13JPC recovered by the Healy Oden Trans-Arctic Expedition in August 2005 (HOTRAX05) to the Mendeleev-Alpha Ridge yields apparent magnetic “excursions” in sediments deposited in the Brunhes Chron. Thermal demagnetization of the NRM, however, implies multiple magnetization components with negative inclination components usually “unblocked” below ?350°C. Analysis of isothermal remanent magnetization acquisition curves from magnetic extracts indicates two magnetic coercivity components superimposed on one another. Magnetic experiments conducted under high and low temperatures show features that are characteristic for (titano)magnetite and titanomaghemite. Presence of the two magnetic phases is further confirmed by elemental mapping on a scanning electron microscope equipped for X-ray energy dispersive spectroscopy (EDS) and by high-resolution X-ray diffraction (XRD). It is unlikely that anomalously thick intervals of negative inclination in these Brunhes-aged sediments are caused by unusual behavior of the magnetic field in the Arctic area. We therefore attribute low and negative NRM inclinations in these cores to partially self-reversed chemical remanent magnetizations, apparently carried by titanomaghemite and acquired during the oxidation of detrital (titano)magnetite grains. The high Ti contents and high oxidation states indicated by EDS and XRD data provide the conditions required for partial self-reversal by ionic reordering during diagenetic maghemitization, and this process appears to have affected all HOTRAX05 cores collected from the Mendeleev-Alpha Ridge.

Description: Inclination patterns of natural remanent magnetization (NRM) in Quaternary sediment cores from the Arctic Ocean have been widely used for stratigraphic correlation and the construction of age models, however, shallow and negative NRM inclinations in sediments deposited during the Brunhes Chron in the Arctic Ocean appear to have a partly diagenetic origin. Rock magnetic and mineralogical studies demonstrate the presence of titanomagnetite and titanomaghemite. Thermal demagnetization of the NRM indicates that shallow and negative inclination components are largely "unblocked" below ~300 °C, consistent with a titanomaghemite remanence carrier. Following earlier studies on the Mendeleev-Alpha Ridge, shallow and negative NRM inclination intervals in cores from the Lomonosov Ridge and Yermak Plateau are attributed to partial self-reversed chemical remanent magnetization (CRM) carried by titanomaghemite formed during seafloor oxidation of host (detrital) titanomagnetite grains. Distortion of paleomagnetic records due to seafloor maghemitization appears to be especially important in the perennially ice covered western (Mendeleev-Alpha Ridge) and central Arctic Ocean (Lomonosov Ridge) and, to a lesser extent, near the ice edge (Yermak Plateau). On the Yermak Plateau, magnetic grain size parameters mimic the global benthic oxygen isotope record back to at least marine isotope stage 6, implying that magnetic grain size is sensitive to glacial-interglacial changes in bottom-current velocity and/or detrital provenance.

Description: Lack of foraminiferal carbonate in marine sediments deposited at high latitudes results in traditional oxygen isotope stratigraphy not playing a central role in Quaternary age control for a large portion of the globe. This limitation has affected the interpretation of Quaternary sediment drifts off the Antarctic Peninsula in a region critical for documenting past instability of the West Antarctic Ice Sheet (WAIS) and Antarctic Peninsula Ice Sheet (APIS). Here we use piston cores recovered from these sediment drifts in 2015 during cruise JR298 of the RRS James Clark Ross to test the usefulness for age control of relative paleointensity (RPI) data augmented by scant d18O data. Thermomagnetic and magnetic hysteresis data, as well as isothermal remanent magnetization (IRM) acquisition curves, indicate the presence of prevalent magnetite and subordinate oxidized magnetite ("maghemite") in the cored sediments. The magnetite is likely detrital. Maghemite is an authigenic mineral, associated with surface oxidation of magnetite grains, which occurs preferentially in the oxic zone of the uppermost sediments, and buried oxic zones deposited during prior interglacial climate stages. Low concentrations of labile organic matter apparently led to arrested pore-water sulfate reduction explaining oxic zone burial and downcore survival of the reactive maghemite coatings. At some sites, maghemitization has a debilitating effect on RPI proxies whereas at other sites maghemite is less evident and RPI proxies can be adequately matched to the RPI reference template. Published RPI data at ODP Site 1101, located on Drift 4, can be adequately correlated to contemporary RPI templates, probably as a result of disappearance (dissolution) of maghemite at sediment depths 〉~10m.

Description: The Miocene Climatic Optimum (MCO; ~16.9 to 14.7 Ma) provides an outstanding opportunity to investigate climate-carbon cycle dynamics during a geologically recent interval of global warmth. We present benthic stable oxygen (d18O) and carbon (d13C) isotope records (5-12 kyr time resolution) spanning the late early to middle Miocene interval (18 to 13 Ma) at Integrated Ocean Drilling Program (IODP) Site U1335 (eastern equatorial Pacific Ocean). The U1335 stable isotope series track the onset and development of the MCO as well as the transitional climatic phase culminating with global cooling and expansion of the East Antarctic ice-sheet at ~13.8 Ma. We integrate these new data with published stable isotope, geomagnetic polarity and X-ray fluorescence (XRF) scanner-derived carbonate records from IODP Sites U1335, U1336, U1337 and U1338 on a consistent, astronomically-tuned timescale. Benthic isotope and XRF scanner-derived CaCO3 records depict prominent 100 kyr variability with 400 kyr cyclicity additionally imprinted on d13C and CaCO3 records, pointing to a tight coupling between the marine carbon cycle and climate variations. Our inter-site comparison further indicates that the lysocline behaved in highly dynamic manner throughout the MCO, with 〉75% carbonate loss occurring at paleo-depths ranging from ~3.4 to ~4 km in the eastern equatorial Pacific Ocean. Carbonate dissolution maxima coincide with warm phases (d18O minima) and d13C decreases, implying that climate-carbon cycle feedbacks fundamentally differed from the late Pleistocene glacial-interglacial pattern, where dissolution maxima correspond to d13C maxima and d18O minima. Carbonate dissolution cycles during the MCO were, thus, more similar to Paleogene hyperthermal patterns.

Description: Episodes of ice-sheet disintegration and meltwater release over glacial-interglacial cycles are recorded by discrete layers of detrital sediment in the Labrador Sea. The most prominent layers reflect the release of iceberg armadas associated with cold Heinrich events, but the detrital sediment carried by glacial outburst floods from the melting Laurentide Ice Sheet is also preserved. Here we report an extensive layer of red detrital material in the Labrador Sea that was deposited during the early last interglacial period. We trace the layer through sediment cores collected along the Labrador and Greenland margins of the Labrador Sea. Biomarker data, Ca/Sr ratios and d18O measurements link the carbonate contained in the red layer to the Palaeozoic bedrock of the Hudson Bay. We conclude that the debris was carried to the Labrador Sea during a glacial outburst flood through the Hudson Strait, analogous to the final Lake Agassiz outburst flood about 8,400 years ago, probably around the time of a last interglacial cold event in the North Atlantic. We suggest that outburst floods associated with the final collapse of the Laurentide Ice Sheet may have been pervasive features during the early stages of Late Quaternary interglacial periods.

Description: Integrated Ocean Drilling Program (IODP) Expedition 303 to the North Atlantic provided 16 records of the Matuyama-Brunhes polarity transition (MBT), based on u-channel and discrete samples, from holes drilled at three sites (Sites U1304, U1305 and U1306) that have mean Brunhes sedimentation rates of 16-18 cm/kyr. The MBT occurs during the transition from marine isotope stage (MIS) 19c to MIS 18e, with mid-point at ~773 ka, and a transition duration of ~8 kyr. Combining the new MBT records, including one new record for the top Jaramillo, with previously published North Atlantic MBT records (ODP Sites 983, 984 and 1063) yields a total of more than 20 high-sedimentation-rate polarity transition records. The MBT yields a repetitive pattern of transitional field states as virtual geomagnetic poles (VGPs) move from high southern latitudes to loop over the Pacific, group in NE Asia, and transit into the mid-latitude South Atlantic before reaching high latitudes in the Northern Hemisphere. The VGPs for the top Jaramillo transition feature a loop over the Pacific, then a NE Asia group before transit over the Indian Ocean to high southerly latitudes. The North Atlantic MBT records described here contrast with longitudinally-constrained VGP paths for the MBT, indicating that relatively low sedimentation rate (~4 cm/kyr) records of the MBT are heavily smoothed by the remanence acquisition process and do not adequately represent the MBT field. The VGPs at the MBT and top Jaramillo, as measured in the North Atlantic, have similarities with excursion (Iceland Basin) VGP paths, and were apparently guided by maxima in downward vertical flux similar to those seen in the modern non-dipole (ND) field, implying longevity in ND features through time.

Description: The long-term rate of racemization for amino acids preserved in planktonic foraminifera was determined by using independently dated sediment cores from the Arctic Ocean. The racemization rates for aspartic acid (Asp) and glutamic acid (Glu) in the common taxon, Neogloboquadrina pachyderma, were calibrated for the last 150 ka using 14C ages and the emerging Quaternary chronostratigraphy of Arctic Ocean sediments. An analysis of errors indicates realistic age uncertainties of about ±12% for Asp and ±17% for Glu. Fifty individual tests are sufficient to analyze multiple subsamples, identify outliers, and derive robust sample mean values. The new age equation can be applied to verify and refine age models for sediment cores elsewhere in the Arctic Ocean, a critical region for understanding the dynamics of global climate change.

Description: Heinrich events are well documented for the last glaciation, but little is known about their occurrence in older glacial periods of the Pleistocene. Here we report scanning XRF and bulk carbonate d18O results from Integrated Ocean Drilling Program Site U1308 (reoccupation of Deep Sea Drilling Project Site 609) that are used to develop proxy records of ice-rafted detritus (IRD) for the last ~1.4 Ma. Ca/Sr is used as an indicator of IRD layers that are rich in detrital carbonate (i.e., Heinrich layers), whereas Si/Sr reflects layers that are poor in biogenic carbonate and relatively rich in detrital silicate minerals. A pronounced change occurred in the composition and frequency of IRD at ~640 ka during marine isotope stage (MIS) 16, coinciding with the end of the middle Pleistocene transition. At this time, "Hudson Strait" Heinrich layers suddenly appeared in the sedimentary record of Site U1308, and the dominant period of the Si/Sr proxy shifted from 41 ka prior to 640 ka to 100 ka afterward. The onset of Heinrich layers during MIS 16 represents either the initiation of surging of the Laurentide Ice Sheet (LIS) off Hudson Strait or the first time icebergs produced by this process survived the transport to Site U1308. We speculate that ice volume (i.e., thickness) and duration surpassed a critical threshold during MIS 16 and activated the dynamical processes responsible for LIS instability in the region of Hudson Strait. We also observe a strong coupling between IRD proxies and benthic d13C variation at Site U1308 throughout the Pleistocene, supporting a link between iceberg discharge and weakening of thermohaline circulation in the North Atlantic.