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  • thermodynamic modelling  (2)
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  • 1
    Publication Date: 2023-10-26
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉In the Penninic nappe stack of the Western Alps, high‐ to ultrahigh‐pressure metamorphic ophiolites of the Zermatt‐Saas Zone are associated with slivers of continental crust. In one of these slivers, Monte Emilius, the overprinting of pre‐Alpine granulite‐facies rocks by subduction‐related, Alpine eclogite‐facies metamorphism can be studied. Mafic granulites were initially transformed into blueschists. In a second step, shear zones were developed in which the blueschists recrystallized to fine‐grained, foliated glaucophane eclogites, and eclogite veins. The combination of petrographic and field observations as well as whole‐rock compositions suggests that the eclogite assemblage formed only in shear zones where Ca‐metasomatism induced a change in major element composition. These substantial differences in bulk rock composition demonstrate how spatially limited eclogitization may be controlled by chemical redistribution, the degree of fabric development, and associated metamorphic reactions along fluid pathways. Thermodynamic modelling of selected bulk rock compositions yielded only slightly different conditions of 1.8 ± 0.1 GPa/550 ± 50°C for blueschist and 1.9–2.3 GPa/550 ± 50°C for eclogite, constraining Ca‐rich fluid infiltration and transformation to a depth of ~60–70 km. Eclogitization occurred in the Early Eocene at 52.96 ± 0.91 Ma, as indicated by a well‐defined Lu–Hf garnet isochron.〈/p〉
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:552.4 ; eclogite ; Lu–Hf garnet geochronology ; Monte Emilius ; subduction ; thermodynamic modelling ; Zermatt–Saas zone
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-12-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉High‐ and ultrahigh‐pressure rocks occur in the Austroalpine Nappes in a ~400 km long belt from the Texel Complex in the west to the Sieggraben Unit in the east. Garnet growth during pressure increase was dated using Lu‐Hf chronometry. The results range between c. 100 and 90 Ma, indicating a short‐lived period of subduction. Combined with already published data, our estimates of metamorphic conditions indicate a field gradient with increasing pressure and temperature from the northwest to the southeast, where the rocks experienced ultrahigh‐pressure metamorphism. The P‐T conditions of the eclogites generally lie on the ‘warm’ side of the global range of subduction‐zone metamorphic conditions. The oldest Cretaceous eclogites (c. 100 Ma) are found in the Saualpe‐Koralpe area derived from widespread gabbros formed during Permian to Triassic rifting. In the Texel Complex garnets showing two growth phases yielded a Variscan‐Eoalpine mixed age indicating re‐subduction of Variscan eclogite‐bearing continental crust during the Eoalpine orogeny. Jurassic blueschist‐facies metamorphism at Meliata in the Western Carpathians and Cretaceous eclogite‐facies metamorphism in the Austroalpine are separated by a time gap of c. 50 Ma and therefore do not represent a transition from oceanic to continental subduction but rather separate events. Thus, we propose that subduction initiation was intracontinental at the site of a Permian rift.〈/p〉
    Description: German Science Foundation (DFG)
    Description: Slovak Research and Development Agency http://dx.doi.org/10.13039/501100005357
    Keywords: ddc:552.4 ; Eastern Alps ; Eoalpine (Cretaceous) event ; high‐pressure metamorphism ; thermodynamic modelling ; Lu‐Hf geochronology
    Language: English
    Type: doc-type:article
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