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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 105 (1998), S. 263-275 
    ISSN: 1573-2932
    Keywords: chloride ; hydrograph separation ; Panola Mountain Research Watershed ; streamflow ; tracer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract An analysis of chloride (Cl-) concentrations and fluxes at the 41 ha Panola Mountain Research Watershed indicates that Cl- may be used effectively to differentiate "new" and "old" water flow through the hillslope and their respective contributions to streamwater. Rainfall and throughfall, the "new" water inputs, are marked by low Cl- concentrations (〈15 µeq L-1). Stormwater moves rapidly to depth along preferred pathways in a deciduous forest hillslope, as evidenced by low Cl- concentrations (〈20 µeq L-1) in mobile soil water from zero-tension stainless-steel pan lysimeters. "Old" waters, matrix soil waters and groundwater, typically have high Cl- concentrations (〉30 µeq L-1). Timing of soil water transport is not sufficiently rapid to suggest that soil water from this hillslope site (20 m from the stream) contributes to streamwater during individual rainstorms. The source of streamflow, therefore, must be a combination of channel interception, overland flow and soil water from near-channel areas, and runoff from a 3 ha bedrock outcrop in the headwaters. Groundwater contribution to streamflow was estimated using Cl- concentrations of throughfall and groundwater as the two end members for a two-component hydrograph separation. For the study period, groundwater contributed 79% of the streamflow and from 1985 to 1995, contributed 75% of the streamflow. Rainfall was the source of 45% of the Cl- flux from the watershed in the long term; the remaining Cl- is hypothesized to be derived from dry deposition, consistent with the enrichment noted for throughfall. At peak flow during individual rainstorms, "new" water can contribute 95% of the runoff.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 91 (1996), S. 283-298 
    ISSN: 1573-2932
    Keywords: dry deposition ; charge density ; chloride ; colorimetry ; ion balance ; ion chromatography ; recycling ; watershed budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Colorimetric Cl− data from natural solutions that contain dissolved organic carbon (DOC) may be biased high. We evaluated aquatic Cl- concentrations in ecosystem compartments at the Bear Brook Watershed, Maine, and from lakes in Maine, using ion chromatography and colorimetry. DOC imparts a positive interference on colorimetric Cl− results proportional to DOC concentrations at approximately 0.8 µeq Cl−/L per mg DOC/L. The interference is not a function of Cl− concentration. The resulting bias in concentrations of Cl− may be 50% or more of typical environmental values for Cl− in areas remote from atmospheric deposition of marine aerosols. Such biased data in the literature appear to have led to spurious conclusions about recycling of Cl− by forests, the usefulness of Cl− as a conservative tracer in watershed studies, and calculations of elemental budgets, ion balance, charge density of DOC, and dry deposition factors.
    Type of Medium: Electronic Resource
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