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  • Cell & Developmental Biology  (4)
  • Dendrochronology  (1)
  • Pyramidal inversion  (1)
  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2014. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Quaternary Science Reviews 121 (2015): 89-97, doi:10.1016/j.quascirev.2015.05.020.
    Description: Warming over Mongolia and adjacent Central Asia has been unusually rapid over the past few decades, particularly in the summer, with surface temperature anomalies higher than for much of the globe. With few temperature station records available in this remote region prior to the 1950s, paleoclimatic data must be used to understand annual-to-centennial scale climate variability, to local response to large-scale forcing mechanisms, and the significance of major features of the past millennium such as the Medieval Climate Anomaly (MCA) and Little Ice Age (LIA) both of which can vary globally. Here we use an extensive collection of living and subfossil wood samples from temperature-sensitive trees to produce a millennial-length, validated reconstruction of summer temperatures for Mongolia and Central Asia from 931 to 2005 CE. This tree-ring reconstruction shows general agreement with the MCA (warming) and LIA (cooling) trends, a significant volcanic signature, and warming in the 20th and 21st Century. Recent warming (2000-2005) exceeds that from any other time and is concurrent with, and likely exacerbated, the impact of extreme drought (1999-2002) that resulted in massive livestock loss across Mongolia.
    Description: This research was supported by the National Science Foundation under grants AGS-PRF #1137729, ATM0117442, and AGS0402474.
    Keywords: Mongolia ; Temperature ; Tree-ring ; Dendrochronology ; Reconstruction ; Global warming
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 2
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: Vascularization of subcutaneous (ear) and mesenteric adrenal autografts, homografts, and x-irradiated autografts was studied microscopically through visualization of small blood vessels by intravascular precipitation of lead chromate. Vascularization of autografts in both sites begins on the third day after transplantation with a surface network of small vessels. Vascular buds penetrate the graft on the fourth day. On the seventh vascularization is complete. Vessels penetrate along regenerated adrenocortical fasciculi. Later, large vessels supplying the network around the graft are prominent and venous sinuses exist near the surface. Vascularization of subcutaneous homotransplants follows the same qualitative course but is chronologically irregular, delayed one or more days in most cases. On the second day an inflammatory vascular reaction occurs around the wound in the ear. Generally, vessels are finer, less well injected than in autografts. Mesenteric homografts, however, are vascularized like mesenteric autografts. X-irradiation of adrenals in vitro with 2,000 r prior to autografting also produces chronological irregularity and retardation of vascularization, up to 28 days after subcutaneous transplantation, but only during the first 12 days in mesenteric transplants. Except for reduction in size, from the thirteenth day on, x-irradiated mesenteric transplants are like non-irradiated controls.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    The @Anatomical Record 125 (1956), S. 17-39 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 9 (1970), S. 400-414 
    ISSN: 0570-0833
    Keywords: Pyramidal inversion ; Inversion barriers ; Stereochemistry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Pyramidal inversion is discussed from the point of view of recent theoretical and experimental investigations in an attempt to provide a unified description of this process. Quantum mechanical studies of pyramidal molecules indicate that the origin of the inversion barrier may be dependent on the degree of angular constraint. Effects due to the electronegativity of substituents on the inversion center, to the presence of adjacent lone pairs, and to inclusion of d-type functions in the basis set are discussed. The utility and limitations of molecular orbital calculations, vibrational spectroscopy, microwave spectroscopy, direct kinetic measurements, and dynamic nuclear magnetic resonance (DNMR) spectroscopy as means for determining barriers to pyramidal inversion are discussed in context with a review of the highlights of experimental observations on the subject. Ambiguities that arise in the interpretation of barriers determined by DNMR are explored in detail. Factors that affect the magnitude of inversion barriers are discussed separately in four broad categories: steric effects; effects of conjugation (including (p-d)π conjugation) and hyperconjugation; effects of angular constraint; and effects of heteroatomic substitution. In the last category, critical reference is made to the question of electronegativity vs. lone pair-lone pair repulsions, the problem of rotation vs. inversion, and the role of d orbitals.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0095-9898
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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