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  • Polymer and Materials Science  (2)
  • Capsulorhexis  (1)
  • 1
    ISSN: 1573-2622
    Keywords: Anterior capsular cataract ; Capsulorhexis ; Silicone oil ; Vitrectomy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract To clarify the mechanical difficulties experienced when performing anterior capsulorhexis in vitrectomized eyes filled with silicone oil. Five anterior lens capsules removed from eyes with a silicone oil history were submitted to light and electron microscopic analysis and then compared to two capsules from eyes with trauma history and seven capsules from eyes without silicone oil or trauma history. Comparable abnormalities of the inner and outer surface of the anterior lens capsule were consistently observed after silicone oil fill of the vitreous cavity or after traumatic impact to the lens: patches of multilayer epithelial cells with interspersed capsule material and connective tissue were observed on the posterior surface of the anterior lens capsule. The development of this anterior subcapsular tissue plaque is obviously influenced not only by the PVR process or by side effects of the surgical procedure but also by the silicone oil tamponade or a trauma history. The plaque can be considered primarily responsible for the increased mechanical resistance of the lens capsule in all eyes with silicone oil/trauma history examined in this study.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Stable aminoplast dispersions can be obtained by new, commercially interesting syntheses. Nature and quantity of the catalysts used - the concentration of hydrogen ions and salts  - , the presence and quantity of water, and the temperature profile have an effect on the storage stability, setting, particle size, and particle size distribution of the condensation products dispersed in the polyether polyols and, in correlation, on the ultimate viscosity of the aminoplast dispersions. The aminoplast dispersion can be manufactured on conventional foaming equipment according to cold curing PUR-foam formulations with toluylene diisocyanate (® Desmodur T 80).Besides acceptable values for the physical properties such as rigidity, elasticity, and tensile strength, the resultant cold cured foams give a striking result in the flammabil-ity test acc. to DIN 4102 inasmuch as they reach Flammability Classification B 1. Yet there are no definitive results about a thinkable emanation of formaldehyde out of such dispersions under the conditions of use.
    Notes: Stabile Aminoplastdispersionen lassen sich nach neuen, technisch interessanten Synthesewegen herstellen. Die Lagerstabilität, Aushörtung, Teilchengrößie und Teilchengrößeverteilung der in den Polyetherpolyolen dispergierten Kondensationsprodukte und damit korrelierend die Endviskosität der Aminoplastdispersionen werden durch die Art und Menge der venvendeten Katalysatoren - die Wasserstoffionen und Salzkonzentration  - , die Anwesenheit und Menge von Wasser und durch die Temperaturführung beeinflußt. Die Aminoplastdispersion ist auf herkömmlichen Verschäumungsanlagen nach PUR-Kaltschaumrezepturen mit Toluylendiisocyanat (®Desmodur T 80) verarbeitbar. Die resultierenden Kaltschaumstoffe erreichen  -  neben guten Werten fur die mechanischen Eigenschaften wie Härte, Elastizität und Reififestigkeit - im Brandtest nach DIN 4102 iiberraschenderweise die Brandklasse B 1 . Uber die denkbare Abspaltung von Formaldehyd unter den Bedingungen der Anwendung solcher Dispersionen liegen noch keine abschliefienden Ergebnisse vor.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Theory and Simulations 3 (1994), S. 855-883 
    ISSN: 1022-1344
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: With the help of a simple reaction-diffusion model with constant striation thickness the influence of micromixing on free-radical polymerization was investigated for several test reactions with discontinuous prepolymerization and jerky addition of selected reactants. Monomer conversion or mean values of molar mass and chemical composition cannot be expected to be very sensitive to micromixing effects. If molar mass distributions are to be used, problems will arise from the fact that the distribution of the polymer accumulated during prepolymerization covers mixing influences occurring after reactant feed. The instantaneous molar mass distribution would be more suitable. Time-integral distributions of chemical composition or sequence length in combination with appropriate test reactions proved to be feasible indicators for the effects of micromixing as it becomes possible to separate the distribution of the prepolymer from that of the polymer which is formed after addition when micromixing is to be investigated.
    Additional Material: 31 Ill.
    Type of Medium: Electronic Resource
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