ISSN:
0044-2313
Keywords:
Alkylisocyanide iron complexes
;
Mitsunobu reaction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Pseudohalogeno Metal Compounds. LXXIV. Preparation of Alkyl Isocyanide Iron Complexes from Isocyano Acid Iron Complexes and primary Alcohols via Redox CondensationIsocyano acid iron complexes Fe(CN)2(CNH)4 · 4Et2O and Fe(bpy)(CN)2(CNH)2 · 2H2O are esterificated with methanol and ethanol in the presence of triphenylphosphine and diethyl azodicarboxylate (Mitsunobu conditions) to give the isocyanide complexes Fe(CN)2(CNR)4 and Fe(bpy)(CN)2(CNR)2 · 2H2O (R = Me, Et) which are characterized by their spectroscopic data.
Notes:
Die Isoblausäure-Komplexe Fe(CN)2(CNH)4 · 4Et2O und Fe(bpy)(CN)2(CNH)2 · 2H2O setzen sich mit Methanol und Ethanol in Anwesenheit von Triphenylphosphan und Azodicarbonsäurediethylester (Mitsunobu-Bedingungen) zu den Isocyanid-komplexen Fe(CN)2(CNR)4 und Fe(bpy)(CN)2(CNR)2 · 2H2O (R = Me, Et) um. Die Isocyanid-Verbindungen werden durch ihre spektroskopischen Daten charakterisiert.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19916000131
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