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  • Center for Marine Environmental Sciences; MARUM  (3)
  • Mg/Ca  (2)
  • 0048BC; 0051BC; 0052BC; 0069BC; BC; Box corer; Bulimina cf. aculeata, Magnesium/Calcium ratio; Bulimina cf. mexicana, Magnesium/Calcium ratio; Cibicidoides kullenbergi, Magnesium/Calcium ratio; Cibicidoides pachyderma, Magnesium/Calcium ratio; Cibicidoides robertsonianus, Magnesium/Calcium ratio; Cibicidoides wuellerstorfi, Magnesium/Calcium ratio; DEPTH, sediment/rock; Elevation of event; Event label; Gyroidinoides cf. mediceus, Magnesium/Calcium ratio; Gyroidinoides cf. soldanii, Magnesium/Calcium ratio; Inductively coupled plasma - mass spectrometry (ICP-MS); Latitude of event; Longitude of event; Melonis barleeanus, Magnesium/Calcium ratio; OC205-02; OC205-02_0048BC; OC205-02_0051BC; OC205-02_0052BC; OC205-02_0057BC; OC205-02_0060BC; OC205-02_0061BC; OC205-02_0069BC; OC205-02_0076BC; OC205-02_0077BC; OC205-02_0079BC; Oceanus; Oceanus205-02; Oridorsalis umbonatus, Magnesium/Calcium ratio; Providence Channel; Pullenia bulloides, Magnesium/Calcium ratio; Siphonina sp., Magnesium/Calcium ratio; Uvigerina spp., Magnesium/Calcium ratio  (1)
  • 130-806B; AGE; Benthic foraminifera; Bottom water temperature; Calculated from Mg/Ca ratios; Cibicidoides mundulus, Magnesium/Calcium ratio; Cibicidoides wuellerstorfi, Magnesium/Calcium ratio; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Joides Resolution; Leg130; Mg/Ca; North Atlantic Deep Water; North Pacific Ocean; ocean drilling program; Ocean Drilling Program; ocean gateway; ODP; Oridorsalis umbonatus, Magnesium/Calcium ratio; Sample code/label  (1)
Document type
Keywords
  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2013. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 121 (2013):196-213, doi:10.1016/j.gca.2013.07.028.
    Description: The Mg/Ca ratio in foraminiferal calcite is one of the principal proxies used for paleoceanographic temperature reconstructions, but recent core-top sediment observations suggest that salinity may exert a significant secondary control on planktic foraminifers. This study compiles new and published laboratory culture experiment data from the planktic foraminifers Orbulina universa, Globigerinoides sacculifer and Globigerinoides ruber, in which salinity was varied but temperature, pH and light were held constant. Combining new data with results from previous culture studies yields a Mg/Ca-sensitivity to salinity of 4.4±2.3%, 4.7±1.2%, and 3.3±1.7% per salinity unit (95% confidence), respectively, for the three foraminifer species studied here. Comparison of these sensitivities with core-top data suggests that the much larger sensitivity (27±4% per salinity unit) derived from Atlantic core-top sediments in previous studies is not a direct effect of salinity. Rather, we suggest that the dissolution correction often applied to Mg/Ca data can lead to significant overestimation of temperatures. We are able to reconcile culture calibrations with core-top observations by combining evidence for seasonal occurrence and latitude-specific habitat depth preferences with corresponding variations in physico-chemical environmental parameters. Although both Mg/Ca and δ18O yield temperature estimates that fall within the bounds of hydrographic observations, discrepancies between the two proxies highlight unresolved challenges with the use of paired Mg/Ca and δ18O analyses to reconstruct paleo-salinity patterns across ocean basins. The first step towards resolving these challenges requires a better spatially and seasonally resolved δ18Osw archive than is currently available. Nonetheless, site-specific reconstructions of salinity change through time may be valid.
    Description: This research was supported by NSF OCE 07-51764 (BH), OCE 05-50703 (HJS), ARC DP 8800010 (SE), OCE 07-52649 (PdeM), ERC 2010-NEWLOG ADG-267931 (HE) and a Columbia Climate Center Grant (KA and BH).
    Keywords: Sea surface temperatures ; Mg/Ca ; δ18O ; Planktic foraminifers ; Salinity
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
    Format: application/vnd.ms-excel
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 12 (2011): Q04003, doi:10.1029/2010GC003333.
    Description: Core top samples from Indonesian and northeast Atlantic depth transects were used to calibrate Mg/Ca and δ18O in tests of the calcitic benthic foraminifer Hyalinea balthica to bottom water temperature between 4°C and 13°C. This shallow infaunal species is primarily abundant in neritic to upper bathyal sediments (〈600 m). Both linear and exponential calibrations suggest a temperature sensitivity of ~12% per °C that is ~4 times higher than observed in other species of deep-sea benthic foraminifera. Culture experiments support the core top calibration. We find no discernible effect of salinity and saturation on Mg/Ca. Comparison between the measured benthic foraminiferal δ18O and predicted equilibrium values suggests that on average H. balthica δ18O is 0.64‰ ± 0.13‰ lower than predicted from the equilibrium composition. To test the reliability of using paired H. balthica Mg/Ca and δ18O measurements for reconstructing seawater δ18Osw and salinity, we apply this calibration to another depth transect from Cape Ghir off NW Africa, which was not included in the calibration. Based on error analysis of the calibration data and this validation test, we show that the uncertainty of reconstructing bottom water temperature and salinity from paired Mg/Ca and δ18O measurements of H. balthica is better than ±0.7°C and ±0.69 practical salinity scale, respectively. The small uncertainties allow for the reconstruction of seawater density to better than 0.3σθ units, which is precise enough for the identification of specific water masses and reconstruction of changes in their properties. We propose that the relatively high Mg content and temperature sensitivity of H. balthica might be due to minor, biologically mediated contribution of high-Mg calcite to the primarily low Mg calcite test, which is influenced by the ambient temperature. This hypothesis, if correct, suggests that benthic species with relatively high Mg/Ca may be better suited for deepwater temperature reconstructions than species that have thus far been more commonly used.
    Description: This project was funded by NSF Awards OCE 02‐20922 and 09‐02977 to YR, OCE 09‐28607 to MK, OCE02‐20776 to DWO, and DFG priority program INTERDYNAMIK to AM.
    Keywords: Mg/Ca ; Benthic foraminifera ; Temperature calibration ; Isotope
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Limitation Availability
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  • 3
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    PANGAEA
    In:  Supplement to: Hollstein, Martina; Mohtadi, Mahyar; Rosenthal, Yair; Moffa-Sanchez, Paola; Oppo, Delia W; Martínez Méndez, Gema; Steinke, Stephan; Hebbeln, Dierk (2017): Stable Oxygen Isotopes and Mg/Ca in Planktic Foraminifera From Modern Surface Sediments of the Western Pacific Warm Pool: Implications for Thermocline Reconstructions. Paleoceanography, 32(11), 1174-1194, https://doi.org/10.1002/2017PA003122
    Publication Date: 2023-03-03
    Description: Mg/Ca and stable oxygen isotope compositions (d18O) of planktic foraminifera tests are commonly used as proxies to reconstruct past ocean conditions including variations in the vertical water column structure. Accurate proxy calibrations require thorough regional studies, since parameters such as calcification depth and temperature of planktic foraminifera depend on local environmental conditions. Here we present radiocarbon-dated, modern surface sediment samples and water column data (temperature, salinity, and seawater d18O) from the Western Pacific Warm Pool. Seawater d18O (d18OSW) and salinity are used to calculate individual regressions for western Pacific surface and thermocline waters (d18OSW = 0.37 × S-12.4 and d18OSW = 0.33 × S-11.0). We combine shell d18O and Mg/Ca with water column data to estimate calcification depths of several planktic foraminifera and establish regional Mg/Ca-temperature calibrations. Globigerinoides ruber, Globigerinoides elongatus, and Globigerinoides sacculifer reflect mixed layer conditions. Pulleniatina obliquiloculata and Neogloboquadrina dutertrei and Globorotalia tumida preserve upper and lower thermocline conditions, respectively. Our multispecies Mg/Ca-temperature calibration (Mg/Ca = 0.26exp0.097*T) matches published regressions. Assuming the same temperature sensitivity in all species, we propose species-specific calibrations that can be used to reconstruct upper water column temperatures. The Mg/Ca temperature dependencies of G. ruber, G. elongatus, and G. tumida are similar to published equations. However, our data imply that calcification temperatures of G. sacculifer, P. obliquiloculata, and N. dutertrei are exceptionally warm in the western tropical Pacific and thus underestimated by previously published calibrations. Regional Mg/Ca-temperature relations are best described by Mg/Ca = 0.24exp0.097*T for G. sacculifer and by Mg/Ca = 0.21exp0.097*T for P. obliquiloculata and N. dutertrei.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 3 datasets
    Location Call Number Limitation Availability
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  • 4
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    PANGAEA
    In:  Supplement to: Hollstein, Martina; Mohtadi, Mahyar; Rosenthal, Yair; Prange, Matthias; Oppo, Delia W; Martínez Méndez, Gema; Tachikawa, Kazuyo; Moffa-Sanchez, Paola; Steinke, Stephan; Hebbeln, Dierk (2018): Variations in Western Pacific Warm Pool surface and thermocline conditions over the past 110,000 years: Forcing mechanisms and implications for the glacial Walker circulation. Quaternary Science Reviews, 201, 429-445, https://doi.org/10.1016/j.quascirev.2018.10.030
    Publication Date: 2023-03-03
    Description: Surface and thermocline conditions of the Western Pacific Warm Pool (WPWP) reflect changes in regional and basin scale ocean and atmosphere circulations and in turn may affect climate globally. Previous studies suggest that a range of factors influences the WPWP on different timescales, however the precise forcings and mechanisms are unclear. Combining surface and thermocline records from sediment cores offshore Papua New Guinea we explore the influence of local and remote processes on the WPWP in response to astronomical forcing and changing glacial-interglacial boundary conditions over the past 110 kyr. We find that thermocline temperatures change with variations in Earth's obliquity with higher temperatures coinciding with high obliquity, which is attributed to variations in subduction and advection of the South Pacific Tropical Water. In contrast, rainfall variations associated with meridional migrations of the Intertropical Convergence Zone are primarily driven by changes in insolation due to precession. Records of bulk sedimentary Ti/Ca and foraminiferal Nd/Ca indicate an additional influence of obliquity, which, however, cannot unambiguously be related to changes in precipitation. Finally, our results suggest a thermocline deepening during the Last Glacial Maximum (LGM). A compilation of available proxy records illustrates a dipole-like pattern of LGM thermocline depth anomalies with a shoaling (deepening) in the northern (southern) WPWP. A comparison of the proxy compilation with an ensemble of Paleoclimate Model Intercomparison Project (PMIP) climate model simulations reveals that the spatial pattern of LGM thermocline depth anomalies is mainly attributable to a contraction of the Pacific Walker circulation on its western side.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 4 datasets
    Location Call Number Limitation Availability
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  • 5
    Publication Date: 2023-11-21
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 2 datasets
    Location Call Number Limitation Availability
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  • 6
    Publication Date: 2024-01-09
    Keywords: 130-806B; AGE; Benthic foraminifera; Bottom water temperature; Calculated from Mg/Ca ratios; Cibicidoides mundulus, Magnesium/Calcium ratio; Cibicidoides wuellerstorfi, Magnesium/Calcium ratio; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Joides Resolution; Leg130; Mg/Ca; North Atlantic Deep Water; North Pacific Ocean; ocean drilling program; Ocean Drilling Program; ocean gateway; ODP; Oridorsalis umbonatus, Magnesium/Calcium ratio; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 574 data points
    Location Call Number Limitation Availability
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  • 7
    Publication Date: 2024-03-09
    Keywords: 0048BC; 0051BC; 0052BC; 0069BC; BC; Box corer; Bulimina cf. aculeata, Magnesium/Calcium ratio; Bulimina cf. mexicana, Magnesium/Calcium ratio; Cibicidoides kullenbergi, Magnesium/Calcium ratio; Cibicidoides pachyderma, Magnesium/Calcium ratio; Cibicidoides robertsonianus, Magnesium/Calcium ratio; Cibicidoides wuellerstorfi, Magnesium/Calcium ratio; DEPTH, sediment/rock; Elevation of event; Event label; Gyroidinoides cf. mediceus, Magnesium/Calcium ratio; Gyroidinoides cf. soldanii, Magnesium/Calcium ratio; Inductively coupled plasma - mass spectrometry (ICP-MS); Latitude of event; Longitude of event; Melonis barleeanus, Magnesium/Calcium ratio; OC205-02; OC205-02_0048BC; OC205-02_0051BC; OC205-02_0052BC; OC205-02_0057BC; OC205-02_0060BC; OC205-02_0061BC; OC205-02_0069BC; OC205-02_0076BC; OC205-02_0077BC; OC205-02_0079BC; Oceanus; Oceanus205-02; Oridorsalis umbonatus, Magnesium/Calcium ratio; Providence Channel; Pullenia bulloides, Magnesium/Calcium ratio; Siphonina sp., Magnesium/Calcium ratio; Uvigerina spp., Magnesium/Calcium ratio
    Type: Dataset
    Format: text/tab-separated-values, 66 data points
    Location Call Number Limitation Availability
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