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  • (Ketiminophosphane)gold(I) complexes  (1)
  • AGE; Aluminium; Aluminium oxide; Antimony; Arsenic; Barium; Beryllium; Bismuth; Boron; Cadmium; Caesium; Calcium; Calcium oxide; Carbon, organic, total; Carbon, total; Carbon dioxide; Cerium; Chlorine; Chromium; Cobalt; Copper; Dysprosium; environmental change; Erbium; Europium; Gadolinium; Gallium; Germanium; Gold; Hafnium; Holmium; Indium; inorganic geochemistry; Iodine; Iron; Iron oxide, Fe2O3; Iron oxide, FeO; Lanthanum; Lead; Lithium; Loss on ignition; Lutetium; Magnesium; Magnesium oxide; Manganese; Manganese oxide; Median values; Mercury; Molybdenum; MULT; Multiple investigations; Neodymium; Nickel; Niobium; Nitrogen, total; Number of analyses; Palladium; Phosphorus; Phosphorus pentoxide; Platinum; Potassium; Potassium oxide; Praseodymium; provenance study; proxies; Recalculated; Rhenium; Rubidium; Saale; Saale catchment; Samarium; Scandium; Selenium; Silicon; Silicon dioxide; Silver; Sodium; Sodium oxide; Stratigraphy; Strontium; Sulfur, total; Sulfur trioxide; Tantalum; Tellurium; Terbium; Thallium; Thorium; Thulium; Tin; Titanium; Titanium dioxide; Tungsten; Uranium; Vanadium; Water in rock; Ytterbium; Yttrium; Zinc; Zirconium  (1)
Document type
Keywords
Publisher
Years
  • 1
    Electronic Resource
    Electronic Resource
    Gold(1) Complexes of Ketiminophosphanes and -phosphane Sulfides (1997)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1423-1426 
    Details
    ISSN: 0009-2940
    Keywords: Gold ; Gold(I) complexes ; (Imine)gold(I)complexes ; Ketiminophosphanes ; (Ketiminophosphane)gold(I) complexes ; Ketiminophosphane sulfides ; (Ketiminophosphanesulfide)gold(I) complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reactions of chloro(dimethyl sulfide)gold(I) with equivalent quantities of the ketiminophosphane diphenyl(diphenylmethyleneamino)phosphane (1a) or its sulfide (1aS) lead to high yields of stable, crystalline 1 : 1 complexes with AuCl units attached to the phosphorus and sulfur atom, respectively. Tris(diphenylmethyleneamino)phosphane (1c) gives the related complex (Ph2C=N)3PAuCl with the gold atom also selectively P-bound. Bis(diphenylmethyleneamino)phenyl-phosphane (1b) could not be used because of its limited stability. Single-crystal X-ray diffraction studies have shown that there is no auxiliary coordination of the metal center by the imino functions of the ligands. The geometry of the P/S—Au—Cl moieties deviates only very slightly from linearity. The angle at the sulfur atom in (Ph2C=N)Ph2PSAuCl is very small [94.30(3)°], but despite of the resulting rather open coordination there are no discernible intra- or intermolecular contacts in the lattice. Such contacts are also absent with (Ph2C=N)Ph2PAuCl and (Ph2C=N)3PAuCl owing to the bulk of the ligands. The 1 : 1 complexes do not react with an excess of (Me2S)AuCl. This finding, and the molecular structures of the 1 : 1 complexes, show very consistently that both phosphane and sulfide donors are far superior as ligands for gold(I) as compared to ketimine donor molecules.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19971301011
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    Paper (German National Licenses)
    Fulltext
  • 2
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    Unknown
    Inorganic geochemistry of sedimentary rocks in the catchment of river Thuringian Saale during the last 600 Ma (2021)
    PANGAEA
    Details
    Publication Date: 2023-07-14
    Description: A literature retrieval was performed for whole rock geochemical analyses of sedimentary, magmatic and metamorphic rocks in the catchment of River Thuringian Saale for the past 600 Ma. Considering availability and coincidence with paleontological an facies data the following indicators seem suitable to detect environmental and climatic changes: biogenic P for Paleoproductivity, STI Index for weathering intensity, Ni/Co-ratio for redox conditions, relative enrichments of Co, Ba and Rb versus crustal values for volcanic activity at varying differentiation. The Mg/Ca-ratio as proxy for salinity is applicable in evaporites. The binary plot Nb/Y versus Zr/TiO2 indicates a presently eroded volcanic level of the Bohemian Massif as catchment area for the Middle Bunter, whereas higly differentiated volcanics provided source material for Neoproterozoic greywackes. A positive Eu-anomaly is limited to the Lower Bunter and implies mafic source rocks perhaps formerly located in the Bohemian Massif.
    Keywords: AGE; Aluminium; Aluminium oxide; Antimony; Arsenic; Barium; Beryllium; Bismuth; Boron; Cadmium; Caesium; Calcium; Calcium oxide; Carbon, organic, total; Carbon, total; Carbon dioxide; Cerium; Chlorine; Chromium; Cobalt; Copper; Dysprosium; environmental change; Erbium; Europium; Gadolinium; Gallium; Germanium; Gold; Hafnium; Holmium; Indium; inorganic geochemistry; Iodine; Iron; Iron oxide, Fe2O3; Iron oxide, FeO; Lanthanum; Lead; Lithium; Loss on ignition; Lutetium; Magnesium; Magnesium oxide; Manganese; Manganese oxide; Median values; Mercury; Molybdenum; MULT; Multiple investigations; Neodymium; Nickel; Niobium; Nitrogen, total; Number of analyses; Palladium; Phosphorus; Phosphorus pentoxide; Platinum; Potassium; Potassium oxide; Praseodymium; provenance study; proxies; Recalculated; Rhenium; Rubidium; Saale; Saale catchment; Samarium; Scandium; Selenium; Silicon; Silicon dioxide; Silver; Sodium; Sodium oxide; Stratigraphy; Strontium; Sulfur, total; Sulfur trioxide; Tantalum; Tellurium; Terbium; Thallium; Thorium; Thulium; Tin; Titanium; Titanium dioxide; Tungsten; Uranium; Vanadium; Water in rock; Ytterbium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 2994 data points
    Location Call Number Limitation Availability
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    DATA PANGAEA
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