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  • (Ketiminophosphane)gold(I) complexes  (1)
  • AGE; Aluminium; Aluminium oxide; Antimony; Arsenic; Barium; Beryllium; Bismuth; Boron; Cadmium; Caesium; Calcium; Calcium oxide; Carbon, organic, total; Carbon, total; Carbon dioxide; Cerium; Chlorine; Chromium; Cobalt; Copper; Dysprosium; environmental change; Erbium; Europium; Gadolinium; Gallium; Germanium; Gold; Hafnium; Holmium; Indium; inorganic geochemistry; Iodine; Iron; Iron oxide, Fe2O3; Iron oxide, FeO; Lanthanum; Lead; Lithium; Loss on ignition; Lutetium; Magnesium; Magnesium oxide; Manganese; Manganese oxide; Median values; Mercury; Molybdenum; MULT; Multiple investigations; Neodymium; Nickel; Niobium; Nitrogen, total; Number of analyses; Palladium; Phosphorus; Phosphorus pentoxide; Platinum; Potassium; Potassium oxide; Praseodymium; provenance study; proxies; Recalculated; Rhenium; Rubidium; Saale; Saale catchment; Samarium; Scandium; Selenium; Silicon; Silicon dioxide; Silver; Sodium; Sodium oxide; Stratigraphy; Strontium; Sulfur, total; Sulfur trioxide; Tantalum; Tellurium; Terbium; Thallium; Thorium; Thulium; Tin; Titanium; Titanium dioxide; Tungsten; Uranium; Vanadium; Water in rock; Ytterbium; Yttrium; Zinc; Zirconium  (1)
  • ConA-labelling  (1)
Document type
Keywords
Publisher
Years
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1423-1426 
    ISSN: 0009-2940
    Keywords: Gold ; Gold(I) complexes ; (Imine)gold(I)complexes ; Ketiminophosphanes ; (Ketiminophosphane)gold(I) complexes ; Ketiminophosphane sulfides ; (Ketiminophosphanesulfide)gold(I) complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reactions of chloro(dimethyl sulfide)gold(I) with equivalent quantities of the ketiminophosphane diphenyl(diphenylmethyleneamino)phosphane (1a) or its sulfide (1aS) lead to high yields of stable, crystalline 1 : 1 complexes with AuCl units attached to the phosphorus and sulfur atom, respectively. Tris(diphenylmethyleneamino)phosphane (1c) gives the related complex (Ph2C=N)3PAuCl with the gold atom also selectively P-bound. Bis(diphenylmethyleneamino)phenyl-phosphane (1b) could not be used because of its limited stability. Single-crystal X-ray diffraction studies have shown that there is no auxiliary coordination of the metal center by the imino functions of the ligands. The geometry of the P/S—Au—Cl moieties deviates only very slightly from linearity. The angle at the sulfur atom in (Ph2C=N)Ph2PSAuCl is very small [94.30(3)°], but despite of the resulting rather open coordination there are no discernible intra- or intermolecular contacts in the lattice. Such contacts are also absent with (Ph2C=N)Ph2PAuCl and (Ph2C=N)3PAuCl owing to the bulk of the ligands. The 1 : 1 complexes do not react with an excess of (Me2S)AuCl. This finding, and the molecular structures of the 1 : 1 complexes, show very consistently that both phosphane and sulfide donors are far superior as ligands for gold(I) as compared to ketimine donor molecules.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Yeast 12 (1996), S. 965-975 
    ISSN: 0749-503X
    Keywords: act1-1 ; SAC3 ; ConA-labelling ; Life Sciences ; Life Sciences (general)
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Notes: A temperature-sensitive mutation (act1-1) in the essential actin gene of Saccharomyces cerevisiae can be suppressed by mutations in the SAC3 gene. A DNA fragment containing the SAC3 gene was sequenced. SAC3 codes for a 150 kDa hydrophillic protein which does not show any significant similarities with other proteins in the databases. Sac3 therefore is a novel yeast protein. A nuclear localization of Sac3 is suggested by the presence of a putative nuclear localization signal in the Sac3 sequence. A SAC3 disruption mutation was constructed. SAC3 disruption mutants were viable but grew more slowly and were larger than wild-type cells. In contrast to the sac3-1 mutation, the SAC3 disruption was not able to suppress the temperature sensitivity and the osmosensitivity of the act1-1 mutant. This demonstrates that act1-1 suppression by sac3-1 is not the result of a simple loss of SAC3 function. Furthermore, we examined the act1-1 and the sac3 mutants for defects in polarized cell growth by FITC-Concanavalin A (Con A)-labelling. The sac3 mutants showed a normal ConA-labelling pattern. In the act1-1 mutant, however, upon shift to non-permissive temperature, newly synthesized cell wall material, instead of being directed towards the bud, was deposited at discrete spots in the mother cell.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2024-06-17
    Description: A literature retrieval was performed for whole rock geochemical analyses of sedimentary, magmatic and metamorphic rocks in the catchment of River Thuringian Saale for the past 600 Ma. Considering availability and coincidence with paleontological an facies data the following indicators seem suitable to detect environmental and climatic changes: biogenic P for Paleoproductivity, STI Index for weathering intensity, Ni/Co-ratio for redox conditions, relative enrichments of Co, Ba and Rb versus crustal values for volcanic activity at varying differentiation. The Mg/Ca-ratio as proxy for salinity is applicable in evaporites. The binary plot Nb/Y versus Zr/TiO2 indicates a presently eroded volcanic level of the Bohemian Massif as catchment area for the Middle Bunter, whereas higly differentiated volcanics provided source material for Neoproterozoic greywackes. A positive Eu-anomaly is limited to the Lower Bunter and implies mafic source rocks perhaps formerly located in the Bohemian Massif.
    Keywords: AGE; Aluminium; Aluminium oxide; Antimony; Arsenic; Barium; Beryllium; Bismuth; Boron; Cadmium; Caesium; Calcium; Calcium oxide; Carbon, organic, total; Carbon, total; Carbon dioxide; Cerium; Chlorine; Chromium; Cobalt; Copper; Dysprosium; environmental change; Erbium; Europium; Gadolinium; Gallium; Germanium; Gold; Hafnium; Holmium; Indium; inorganic geochemistry; Iodine; Iron; Iron oxide, Fe2O3; Iron oxide, FeO; Lanthanum; Lead; Lithium; Loss on ignition; Lutetium; Magnesium; Magnesium oxide; Manganese; Manganese oxide; Median values; Mercury; Molybdenum; MULT; Multiple investigations; Neodymium; Nickel; Niobium; Nitrogen, total; Number of analyses; Palladium; Phosphorus; Phosphorus pentoxide; Platinum; Potassium; Potassium oxide; Praseodymium; provenance study; proxies; Recalculated; Rhenium; Rubidium; Saale; Saale catchment; Samarium; Scandium; Selenium; Silicon; Silicon dioxide; Silver; Sodium; Sodium oxide; Stratigraphy; Strontium; Sulfur, total; Sulfur trioxide; Tantalum; Tellurium; Terbium; Thallium; Thorium; Thulium; Tin; Titanium; Titanium dioxide; Tungsten; Uranium; Vanadium; Water in rock; Ytterbium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 2994 data points
    Location Call Number Limitation Availability
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