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  • 1
    Publication Date: 2024-02-07
    Description: In this study, we used stable isotopes of oxygen (δ18O), deuterium (δD), and dissolved inorganic carbon (δ13CDIC) in combination with temperature, salinity, oxygen and nutrient concentrations to characterize the coastal (71-78 °W) and an oceanic (82-98 °W) water masses (SAAW-Subantarctic Surface Water; STW-Subtropical Water; ESSW-Equatorial Subsurface water; AAIW-Antarctic Intermediate Water; PDW-Pacific Deep Water) of the Southeast Pacific (SEP). The results show that δ18O and δD can be used to differentiate between SAAW-STW, SAAW-ESSW and ESSW-AAIW. δ13CDIC signatures can be used to differentiate between STW-ESSW (oceanic section), SAAW-ESSW, ESSW-AAIW and AAIW-PDW. Compared with the oceanic section, our new coastal section highlights differences in both the chemistry and geometry of water masses above 1000 m. Previous paleoceanographic studies using marine sediments from the SEP continental margin used the present-day hydrological oceanic transect to compare against, as the coastal section was not sufficiently characterized. We suggest that our new results of the coastal section should be used for past characterizations of the SEP water masses that are usually based on continental margin sediment samples.
    Type: Article , PeerReviewed
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 32 (2017): 1174–1194, doi:10.1002/2017PA003122.
    Description: Mg/Ca and stable oxygen isotope compositions (δ18O) of planktic foraminifera tests are commonly used as proxies to reconstruct past ocean conditions including variations in the vertical water column structure. Accurate proxy calibrations require thorough regional studies, since parameters such as calcification depth and temperature of planktic foraminifera depend on local environmental conditions. Here we present radiocarbon-dated, modern surface sediment samples and water column data (temperature, salinity, and seawater δ18O) from the Western Pacific Warm Pool. Seawater δ18O (δ18OSW) and salinity are used to calculate individual regressions for western Pacific surface and thermocline waters (δ18OSW = 0.37 × S-12.4 and δ18OSW = 0.33 × S-11.0). We combine shell δ18O and Mg/Ca with water column data to estimate calcification depths of several planktic foraminifera and establish regional Mg/Ca-temperature calibrations. Globigerinoides ruber, Globigerinoides elongatus, and Globigerinoides sacculifer reflect mixed layer conditions. Pulleniatina obliquiloculata and Neogloboquadrina dutertrei and Globorotalia tumida preserve upper and lower thermocline conditions, respectively. Our multispecies Mg/Ca-temperature calibration (Mg/Ca = 0.26exp0.097*T) matches published regressions. Assuming the same temperature sensitivity in all species, we propose species-specific calibrations that can be used to reconstruct upper water column temperatures. The Mg/Ca temperature dependencies of G. ruber, G. elongatus, and G. tumida are similar to published equations. However, our data imply that calcification temperatures of G. sacculifer, P. obliquiloculata, and N. dutertrei are exceptionally warm in the western tropical Pacific and thus underestimated by previously published calibrations. Regional Mg/Ca-temperature relations are best described by Mg/Ca = 0.24exp0.097*T for G. sacculifer and by Mg/Ca = 0.21exp0.097*T for P. obliquiloculata and N. dutertrei.
    Description: Bundesministerium für Bildung und Forschung (BMBF) Grant Number: 03G0228A; National Science Foundation (NSF) Grant Number: OCE1131371; DFG-Research Center/Cluster of Excellence “The Ocean in the Earth System”
    Description: 2018-05-09
    Keywords: Western Pacific Warm Pool ; Mg/Ca calibration ; Oxygen isotopes ; Planktic foraminifera ; Thermocline reconstruction
    Repository Name: Woods Hole Open Access Server
    Type: Article
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