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  • Wiley-Blackwell  (27)
  • Institut für Geowissenschaften, Christian-Albrechts-Universität Kiel  (1)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 2139-2144 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP-DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 93-97 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of chloride ions on surface enhanced Raman scattering (SERS) and the time dependence of the SERS intensity of p-aminobenzoic acid (PABA) and pyridine in silver sol were studied. The addition of chloride ions can destroy the equilibrium between the gas-like and the solid-like phase adsorption of PABA on the silver surface and causes a transformation of the molecular adsorption state and a reduction in the SERS intensity. The influence of chloride ions on SERS and the time dependence of SERS intensity in PABA - silver sol and pyridine - silver sol mixtures were studied. It was found that, in the same environment, the SERS' intensity of pyridine increases and that of PABA decreases on addition of KCl. The results show that the chemical effect of chloride ions on SERS of PABA and pyridine in silver sol is overwhelming. The results of light absorption of PABA and pyridine in silver sol are consistent with this conclusion.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 319-323 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Using a new method, the Raman and hyper-Raman tensors for the point groups 8 (C8), 8 (S8), 8/m (C8h), 8mm (C8ν), 822 (D8) and 8/mmm (D8h) have been tabulated.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2013-05-22
    Description: The yield of rice ( Oryza sativa L.) has increased substantially with the development of new cultivars, but the role of potassium (K) requirement for the increase in grain yield and the genotypic advance is still unclear. In order to investigate this relationship a database of 1199 on-farm measurements (harvest index 0.4) comprising 〉 400 modern rice cultivars was collected during 2005–2010 across major irrigated lowland rice–production regions of China. This was used to evaluate the relationships among K requirement, grain yield, and genetic improvement. Across all the sites and seasons, mean reciprocal internal efficiency of K (RIE-K, kg K [t grain produced] –1 ) was 19.8 kg K (t grain) –1 and rice yield averaged 8.7 t ha –1 . Considering four levels of grain yield (〈 7.5, 7.5–9, 9–10.5, and 〉 10.5 t ha –1 ), the respective RIEs were 18.7, 19.4, 20.5, and 21.7 kg K (t grain) –1 . The gradual increase in the RIE-K with yield was attributed mainly to the increase in straw and grain K concentration and the decrease in the K harvest index. The RIE-K values for ordinary inbred, ordinary hybrid, and “super rice” were 18.5, 20.1, and 19.9 kg K (t grain) –1 , respectively. Examining the historical development of rice cultivars, the RIE-K decreased from 40.9 (Nanjing1, early tall, inbred) in the 1950s to 19.8 (IR24, semi-dwarf, ordinary inbred) in the 1970s, and then increased to 20.9 (Shanyou63, modern ordinary hybrid) in the 1980s and 20.6 kg K (t grain) –1 (II-you084, “super” rice) in the 2000s. This variation in RIE-K among grain-yield levels and cultivars highlights the importance of information on rice K requirement in calculating K balance and optimal K-fertilizer rate for rice production.
    Print ISSN: 1436-8730
    Electronic ISSN: 1522-2624
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley-Blackwell
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  • 5
    Publication Date: 2013-05-01
    Description: In hepatocellular carcinomas (HCCs), the levels of histone H3 dimethylation at lysine 9 (H3K9me2) and its corresponding histone methyltransferase G9a are significantly elevated. Recently, G9a was reported to form a complex with the H3K9 methylation effector protein CDYL, but little is known about the expression of CDYL in HCC patients. The human CDYL gene produces two transcripts, a long form ( CDYLa ) and a short form ( CDYLb) , but it is unclear whether the protein products have different functions. The aim of this study was to investigate the distinctions between CDYLa and CDYLb and their expression levels in HCC tissues. We first examined binding abilities of the different CDYL forms with methylated H3 peptides by a pull-down assay. Human CDYLb (h-CDYLb) specifically recognized H3Kc9me2 and H3Kc9me3 modifications, whereas human CDYLa (h-CDYLa) did not interact with any methylated H3 peptides. Similarly, mouse CDYLb (m-CDYLb) specifically bound with di- and tri-methylated H3Kc9 peptides, while mouse CDYLa (m-CDYLa) lacked that ability. Affinity purification also was used to identify the distinct composition of the h-CDYLa or h-CDYLb protein complex. h-CDYLb was found in a multiprotein complex with G9a and GLP, while the h-CDYLa complex did not contain these two enzymes. Consistent with the protein complex composition, h-CDYLb and G9a were both upregulated in HCC tissues, compared with adjacent non-cancerous liver tissues. Furthermore, the positive correlation between expression levels of h-CDYLb and G9a was statistically significant. In contrast, h-CDYLa showed no enrichment in HCC tissues. These findings suggest that h-CDYLb and G9a are cooperatively involved in HCC. © 2013 Wiley Periodicals, Inc.
    Print ISSN: 1045-2257
    Electronic ISSN: 1098-2264
    Topics: Biology , Medicine
    Published by Wiley-Blackwell
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  • 6
  • 7
    Publication Date: 2016-05-05
    Description: It is important to clarify the quantity and composition of hydrologic N export from terrestrial ecosystem and its primary controlling factors, because it affected N availability, productivity and C storage in natural ecosystems. The most previous investigations were focused on the effects of N deposition and human disturbance on the composition of hydrologic N export. However, few studies were aware of whether there were significant differences in the concentrations and composition of hydrologic N export from natural ecosystems in different climate zones, and what is the primary controlling factor. In the present study, three natural forest ecosystems and one natural grassland ecosystem that were located in different climate zones and with different soil pH range were selected. The concentrations of total dissolved N, DON, NH 4 + , NO 3 − in soil solution and stream water, soil properties, and soil gross N transformation rates were measured to answer above questions. Our results showed that NO 3 - concentrations and the composition pattern of hydrologic N export from natural ecosystems varied greatly in the different climate zones. The NO 3 - concentrations in stream water varied largely, ranging from 0.1 mg N L -1 to 1.6 mg N L -1 . While, DON concentration in stream water, ranging from 0.1 to 0.9 mg N L -1 , did not differ significantly and the concentrations of NH 4 + were uniformly low (average 0.1 mg N L -1 ) in all studied sites. There was a trade-off relationship between the proportions of NO 3 - and DON to total dissolved N in stream water. In subtropical strongly acidic forests soil site, DON was the dominance in total dissolved N in stream water. While, NO 3 - -N became dominance in temperate acidic forests soil site, subtropical alkaline forests soil region, and the alpine meadow sites on the Tibetan Plateau. The proportions of NO 3 - to total dissolved N in both soil solution and stream water significantly increased with the increasing of the gross autotrophic nitrification rates (p 〈 0.01). Our results indicated that the characteristics of soil N transformations were the most primary factor regulating the composition of hydrologic N losses from ecosystems. The nitrification was the central soil N transformation processes regulating N composition in soil solution and hydrologic N losses. These results provided important information on understanding easily the composition of hydrologic N export from terrestrial ecosystem.
    Print ISSN: 0148-0227
    Topics: Biology , Geosciences
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  • 8
    Publication Date: 2016-06-04
    Description: Computational studies on the mechanism and diastereoselectivity of base catalyzed synthesis of bicyclo[3.3.1]nonanes by Robinson annulation are reported. Three possible mechanisms were considered, and only the methanol assisted H-shift process could be the favorable pathway. We have discovered a rare Curtin–Hammet scenario: rate determining steps for the two diastereomeric products formed are completely different reactions, and a correction factor should be considered when gauging the ratio of products from competing pathways. The pathway leading to the anti product is kinetically preferred, which is consistent with experimental results. Finally, the ratio of the two products was rationalized. Copyright © 2016 John Wiley & Sons, Ltd. The results of an investigation into the detailed mechanism and kinetics of base catalyzed Robinson annulations leading to bicyclo[3.3.1]nonanes give an insight into the origin of diastereoselectivity and will prompt chemists to rethink Curtin–Hammet principle in the elucidation of isomeric products in organic reactions. Selectivity among competitive pathways may be determined by dissimilar transition states or divergent rate limiting steps. When predicting the outcome of different products, a correction factor should be considered in calculation of the isomeric products ratio.
    Print ISSN: 0894-3230
    Electronic ISSN: 1099-1395
    Topics: Chemistry and Pharmacology , Physics
    Published by Wiley-Blackwell
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  • 9
    Publication Date: 2013-11-29
    Description: [1]  Recent advances in computing technologies have renewed interest in the intelligent systems for automatic interpretation of ionograms, images obtained by remote sensing of the ionospheric plasma. The ionogram " autoscaling" techniques based on the template matching method, previously rendered unrealistic for their computing complexity, have now become feasible. This work presents an automatic scaling technique for extracting the main features of the F1 and F2 layers of the ionosphere, such as critical frequency and virtual height, from vertical incidence (VI) ionograms that do not the distinguish O/X polarization of the echoes. The proposed technique uses the Quasi-Parabolic Segments (QPS) to model the electron density profile shapes that are used to synthesize a pool of candidate traces. Moreover, the empirical orthogonal functions (EOF) and image technique are applied to reduce the size of the candidate traces so that the auto-scaling algorithm can run in realistic time. With the template matching algorithm, the technique will provide the initial parameters of the QPS model for the F1 and F2 layers, which are then fine-tuned to obtain the better fitting parameters. In order to evaluate the performance of this technique, a large data set of ionograms recorded in Wuhan at daytime and nighttime in winter, summer, equinoctial months, are analyzed and investigated. The automatic scaling results are compared with manually scaling results. Our results indicate that the proposed technique described in this paper is reliable and efficient and will facilitate the statistical study of temporal and spatial ionospheric characteristics over Wuhan.
    Print ISSN: 0048-6604
    Electronic ISSN: 1944-799X
    Topics: Geosciences , Physics
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  • 10
    Publication Date: 2014-02-12
    Description: We can apply both fixed and random effects models to multi-regional clinical trial (MRCT) design and data analysis. Thoroughly, understanding the features of these models in an MRCT setting will help assessing their applicability to an MRCT. In this paper, we discuss the interpretations of trial results from these models. We also evaluate the impact of the number of regions and the sample size configuration across the regions on the required total sample size for the overall treatment effect assessment. For quantifying treatment effects of individual regions, the empirical shrinkage estimator and the James–Stein type shrinkage estimator associate with smaller variability compared with the regular sample estimator. We conduct computation and simulation to compare the performance of these estimators when they are applied to assess consistency of treatment effects across regions. We use a multinational trial example to illustrate the application of these methods. Copyright © 2014 John Wiley & Sons, Ltd.
    Print ISSN: 0277-6715
    Electronic ISSN: 1097-0258
    Topics: Mathematics , Medicine
    Published by Wiley-Blackwell
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