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  • Wiley-Blackwell  (27)
  • Hindawi  (12)
  • Institut für Geowissenschaften, Christian-Albrechts-Universität Kiel  (1)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 2139-2144 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP-DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 93-97 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of chloride ions on surface enhanced Raman scattering (SERS) and the time dependence of the SERS intensity of p-aminobenzoic acid (PABA) and pyridine in silver sol were studied. The addition of chloride ions can destroy the equilibrium between the gas-like and the solid-like phase adsorption of PABA on the silver surface and causes a transformation of the molecular adsorption state and a reduction in the SERS intensity. The influence of chloride ions on SERS and the time dependence of SERS intensity in PABA - silver sol and pyridine - silver sol mixtures were studied. It was found that, in the same environment, the SERS' intensity of pyridine increases and that of PABA decreases on addition of KCl. The results show that the chemical effect of chloride ions on SERS of PABA and pyridine in silver sol is overwhelming. The results of light absorption of PABA and pyridine in silver sol are consistent with this conclusion.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 319-323 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Using a new method, the Raman and hyper-Raman tensors for the point groups 8 (C8), 8 (S8), 8/m (C8h), 8mm (C8ν), 822 (D8) and 8/mmm (D8h) have been tabulated.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2013-05-22
    Description: The yield of rice ( Oryza sativa L.) has increased substantially with the development of new cultivars, but the role of potassium (K) requirement for the increase in grain yield and the genotypic advance is still unclear. In order to investigate this relationship a database of 1199 on-farm measurements (harvest index 0.4) comprising 〉 400 modern rice cultivars was collected during 2005–2010 across major irrigated lowland rice–production regions of China. This was used to evaluate the relationships among K requirement, grain yield, and genetic improvement. Across all the sites and seasons, mean reciprocal internal efficiency of K (RIE-K, kg K [t grain produced] –1 ) was 19.8 kg K (t grain) –1 and rice yield averaged 8.7 t ha –1 . Considering four levels of grain yield (〈 7.5, 7.5–9, 9–10.5, and 〉 10.5 t ha –1 ), the respective RIEs were 18.7, 19.4, 20.5, and 21.7 kg K (t grain) –1 . The gradual increase in the RIE-K with yield was attributed mainly to the increase in straw and grain K concentration and the decrease in the K harvest index. The RIE-K values for ordinary inbred, ordinary hybrid, and “super rice” were 18.5, 20.1, and 19.9 kg K (t grain) –1 , respectively. Examining the historical development of rice cultivars, the RIE-K decreased from 40.9 (Nanjing1, early tall, inbred) in the 1950s to 19.8 (IR24, semi-dwarf, ordinary inbred) in the 1970s, and then increased to 20.9 (Shanyou63, modern ordinary hybrid) in the 1980s and 20.6 kg K (t grain) –1 (II-you084, “super” rice) in the 2000s. This variation in RIE-K among grain-yield levels and cultivars highlights the importance of information on rice K requirement in calculating K balance and optimal K-fertilizer rate for rice production.
    Print ISSN: 1436-8730
    Electronic ISSN: 1522-2624
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley-Blackwell
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  • 5
    Publication Date: 2013-05-01
    Description: In hepatocellular carcinomas (HCCs), the levels of histone H3 dimethylation at lysine 9 (H3K9me2) and its corresponding histone methyltransferase G9a are significantly elevated. Recently, G9a was reported to form a complex with the H3K9 methylation effector protein CDYL, but little is known about the expression of CDYL in HCC patients. The human CDYL gene produces two transcripts, a long form ( CDYLa ) and a short form ( CDYLb) , but it is unclear whether the protein products have different functions. The aim of this study was to investigate the distinctions between CDYLa and CDYLb and their expression levels in HCC tissues. We first examined binding abilities of the different CDYL forms with methylated H3 peptides by a pull-down assay. Human CDYLb (h-CDYLb) specifically recognized H3Kc9me2 and H3Kc9me3 modifications, whereas human CDYLa (h-CDYLa) did not interact with any methylated H3 peptides. Similarly, mouse CDYLb (m-CDYLb) specifically bound with di- and tri-methylated H3Kc9 peptides, while mouse CDYLa (m-CDYLa) lacked that ability. Affinity purification also was used to identify the distinct composition of the h-CDYLa or h-CDYLb protein complex. h-CDYLb was found in a multiprotein complex with G9a and GLP, while the h-CDYLa complex did not contain these two enzymes. Consistent with the protein complex composition, h-CDYLb and G9a were both upregulated in HCC tissues, compared with adjacent non-cancerous liver tissues. Furthermore, the positive correlation between expression levels of h-CDYLb and G9a was statistically significant. In contrast, h-CDYLa showed no enrichment in HCC tissues. These findings suggest that h-CDYLb and G9a are cooperatively involved in HCC. © 2013 Wiley Periodicals, Inc.
    Print ISSN: 1045-2257
    Electronic ISSN: 1098-2264
    Topics: Biology , Medicine
    Published by Wiley-Blackwell
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  • 6
  • 7
    Publication Date: 2015-02-26
    Description: This paper examines the local container drayage problem under a special operation mode in which tractors and trailers can be separated; that is, tractors can be assigned to a new task at another location while trailers with containers are waiting for packing or unpacking. Meanwhile, the strategy of sharing empty containers between different customers is also considered to improve the efficiency and lower the operation cost. The problem is formulated as a vehicle routing and scheduling problem with temporal constraints. We adopt combinatorial benders’ cuts algorithm to solve this problem. Numerical experiments are performed on a group of randomly generated instances to test the performance of the proposed algorithm.
    Print ISSN: 1024-123X
    Electronic ISSN: 1563-5147
    Topics: Mathematics , Technology
    Published by Hindawi
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  • 8
    Publication Date: 2015-02-23
    Description: Foot-and-mouth disease virus (FMDV) serotype Asia 1 was mostly endemic in Asia and then was responsible for economically important viral disease of cloven-hoofed animals, but the study on its selection and evolutionary process is comparatively rare. In this study, we characterized 377 isolates from Asia collected up until 2012, including four vaccine strains. Maximum likelihood analysis suggested that the strains circulating in Asia were classified into 8 different groups (groups I–VIII) or were unclassified (viruses collected before 2000). On the basis of divergence time analyses, we infer that the TMRCA of Asia 1 virus existed approximately 86.29 years ago. The result suggested that the virus had a high mutation rate (5.745 × 10−3 substitutions/site/year) in comparison to the other serotypes of FMDV VP1 gene. Furthermore, the structural protein VP1 was under lower selection pressure and the positive selection occurred at many sites, and four codons (positions 141, 146, 151, and 169) were located in known critical antigenic residues. The remaining sites were not located in known functional regions and were moderately conserved, and the reason for supporting all sites under positive selection remains to be elucidated because the power of these analyses was largely unknown.
    Electronic ISSN: 1537-744X
    Topics: Natural Sciences in General
    Published by Hindawi
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  • 9
    Publication Date: 2015-04-08
    Description: With the development of the public transportation, bus network becomes complicated and hard to evaluate. Transfer time is a vital indicator to evaluate bus network. This paper proposed a method to calculate transfer times using Space P. Four bus networks in China have been studied in this paper. Some static properties based on graph theory and complex theory are used to evaluate bus topological structure. Moreover, a bus network evolution model to reduce transfer time is proposed by adding lines. The adding method includes four types among nodes with random choice, large transfer time, degree, and small degree. The results show that adding lines with nodes of small degree is most effective comparing with the other three types.
    Print ISSN: 1026-0226
    Electronic ISSN: 1607-887X
    Topics: Mathematics
    Published by Hindawi
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  • 10
    Publication Date: 2015-05-04
    Description: For practical purposes, the curtain grouting method is an effective method to treat geological disasters and can be used to improve the strength and permeability resistance of surrounding rock. Selection of the optimal parameters of grouting reinforcement cycle especially reinforcement cycle thickness is one of the most interesting areas of research in curtain grouting designs. Based on the fluid-structure interaction theory and orthogonal analysis method, the influence of reinforcement cycle thickness, elastic modulus, and permeability on water inflow of tunnel after grouting and stability of surrounding rock was analyzed. As to the water inflow of tunnel after grouting used as performance evaluation index of grouting reinforcement cycle, it can be concluded that the permeability was the most important factor followed by reinforcement cycle thickness and elastic modulus. Furthermore, pore water pressure field, stress field, and plastic zone of surrounding rock were calculated by using COMSOL software under different conditions of reinforcement cycle thickness. It also can be concluded that the optimal thickness of reinforcement cycle and permeability can be adopted as 8 m and 1/100 of the surrounding rock permeability in the curtain grouting reinforcement cycle. The engineering case provides a reference for similar engineering.
    Print ISSN: 1024-123X
    Electronic ISSN: 1563-5147
    Topics: Mathematics , Technology
    Published by Hindawi
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