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  • 1
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    Unknown
    HWU
    In:  [Poster] In: 7. International Conference on Gas Hydrates (ICGH 2011), 17.-21.07.2011, Edinburgh, Scotland, United Kingdom . Proceedings of the 7th International Conference on Gas Hydrates (ICGH2011) ; 591/1-9 .
    Publication Date: 2012-03-16
    Description: The production of natural gas via injection of fossil-fuel derived CO2 into submarine gas hydrate reservoirs can be an example of tapping a hydrocarbon energy source in a CO2-neutral manner. However, the industrial application of this method is technically challenging. Thus, prior to feasibility testing in the field, multi-scale laboratory experiments and adapted reaction-modeling are needed. To this end, high-pressure flow-through reactors of 15 and 2000 mL sample volume were constructed and tested. Process parameters (P, T, Q, fluid composition) are defined by a fluid supply and conditioning unit to enable simulation of natural fluid-flow scenarios for a broad range of sedimentary settings. Additional Raman- and NMR-spectroscopy aid in identifying the most efficient pathway for CH4 extraction from hydrates via CO2 injection on both microscopic and macroscopic level. In this study we present experimental set-up and design of the highpressure flow-through reactors as well as CH4 yields from H4-hydrate decomposition experiments using CO2-rich brines and pure liquefied CO2.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 2
    facet.materialart.
    Unknown
    HWU
    In:  In: Proceedings of the 7th International Conference on Gas Hydrates (ICGH2011). HWU, Edinburgh, UK, 591/1-9.
    Publication Date: 2012-07-06
    Description: The production of natural gas via injection of fossil-fuel derived CO2 into submarine gas hydrate reservoirs can be an example of tapping a hydrocarbon energy source in a CO2-neutral manner. However, the industrial application of this method is technically challenging. Thus, prior to feasibility testing in the field, multi-scale laboratory experiments and adapted reaction-modeling are needed. To this end, high-pressure flow-through reactors of 15 and 2000 mL sample volume were constructed and tested. Process parameters (P, T, Q, fluid composition) are defined by a fluid supply and conditioning unit to enable simulation of natural fluid-flow scenarios for a broad range of sedimentary settings. Additional Raman- and NMR-spectroscopy aid in identifying the most efficient pathway for CH4 extraction from hydrates via CO2 injection on both microscopic and macroscopic level. In this study we present experimental set-up and design of the highpressure flow-through reactors as well as CH4 yields from H4-hydrate decomposition experiments using CO2-rich brines and pure liquefied CO2.
    Type: Book chapter , NonPeerReviewed
    Format: text
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  • 3
    Publication Date: 2023-02-08
    Description: The fate of plastic debris entering the oceans is largely unconstrained. Currently, intensified research is devoted to the abiotic and microbial degradation of plastic floating near the ocean surface for an extended period of time. In contrast, the impacts of environmental conditions in the deep sea on polymer properties and rigidity are virtually unknown. Here, we present unique results of plastic items identified to have been introduced into deep-sea sediments at a water depth of 4150 m in the eastern equatorial Pacific Ocean more than two decades ago. The results, including optical, spectroscopic, physical and microbial analyses, clearly demonstrate that the bulk polymer materials show no apparent sign of physical or chemical degradation. Solely the polymer surface layers showed reduced hydrophobicity, presumably caused by microbial colonization. The bacterial community present on the plastic items differed significantly (p 〈 0.1%) from those of the adjacent natural environment by a dominant presence of groups requiring steep redox gradients (Mesorhizobium, Sulfurimonas) and a remarkable decrease in diversity. The establishment of chemical gradients across the polymer surfaces presumably caused these conditions. Our findings suggest that plastic is stable over extended times under deep-sea conditions and that prolonged deposition of polymer items at the seafloor may induce local oxygen depletion at the sediment-water interface.
    Type: Article , PeerReviewed
    Format: text
    Format: text
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  • 4
    Publication Date: 2022-03-30
    Description: The coastal and open oceans represent a major, but yet unconstrained, sink for plastics. It is likely that plastic-biota interactions are a key driver for the fragmentation, aggregation, and vertical transport of plastic litter from surface waters to sedimentary sinks. Cruise SO279 conducted sampling to address core questions of microplastic distribution in the open ocean water column, biota, and sediments. Seven stations were sampled between the outer Bay of Biscay and the primary working area south of the Azores. Additional samples were collected from surface waters along the cruise track to link European coastal and shelf waters with the open ocean gyre. Microplastic samples coupled with geochemical tracer analyses will build a mechanistic understanding of MP transport and its biological impact reaching from coastal seas to the central gyre water column and sinks at the seabed. Furthermore, floating plastics were sampled for microbial community and genetic analyses to investigate potential enzymatic degradation pathways. Cruise SO279 served as the third cruise of a number of connected research cruises to build an understanding of the transport pathways of plastic and microplastic debris in the North Atlantic from the input through rivers and air across coastal seas into the accumulation spots in the North Atlantic gyre and the vertical export to its sink at the seabed. The cruise was an international effort as part of the JPI Oceans project HOTMIC (“HOrizontal and vertical oceanic distribution, Transport, and impact of MICroplastics”) and the BMBF funded project PLASTISEA (‘Harvesting the marine Plastisphere for novel cleaning concepts’), and formed a joint effort of HOTMIC and PLASTISEA researchers from a range of countries and institutes.
    Type: Report , NonPeerReviewed
    Format: text
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