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  • 1
    Publication Date: 2020-02-06
    Description: High-Mg, low-Ti volcanic rocks from the Manihiki Plateau in the Western Pacific share many geochemical characteristics with subduction-related boninites such as high-Ca boninites from the Troodos ophiolite on Cyprus, which are believed to originate by hydrous re-melting of previously depleted mantle. In this paper we compare the Manihiki rocks and Troodos boninites using a new dataset on the major and trace element composition of whole rocks and glasses from these locations, and new high-precision, electron microprobe analyses of olivine and Cr-spinel in these rocks. Our results show that both low-Ti Manihiki rocks and Troodos boninites could originate by re-melting of a previously depleted lherzolite mantle source (20–25% of total melting with 8–10% melting during the first stage), as indicated by strong depletion of magmas in more to less incompatible elements (Sm/Yb 〈 0.8, Zr/Y 〈 2, Ti/V 〈 12) and high-Cr-spinel compositions (Cr# 〉 0.5). In comparison with Troodos boninites, the low-Ti Manihiki magmas had distinctively lower H2O contents (〈 0.2 vs. 〉 2 wt% in boninites), ~ 100 °C higher liquidus temperatures at a given olivine Fo-number, lower fO2 (ΔQFM 〈 + 0.2 vs. ΔQFM 〉 + 0.2) and originated from deeper and hotter mantle (1.4–1.7 GPa, ~ 1440 °C vs. 0.8–1.0 GPa, ~ 1300 °C for Troodos boninites). The data provide new evidence that re-melting of residual upper mantle is not only restricted to subduction zones, where it occurs under hydrous conditions, but can also take place due to interaction of previously depleted upper mantle with mantle plumes from the deep and hotter Earth interior.
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  • 2
    Publication Date: 2021-02-08
    Description: The paper presents data on plutonic and metamorphic rocks dredged during Cruise 249 of the German R/V Sonne to the Stalemate Ridge, Northwest Pacific Ocean and the Shirshov Rise, western Bering Sea. Dredges in the northwestern sector of the Stalemate Ridge and central portion of the Shirshov Rise show that the plutonic and metamorphic rocks obtained here are amazingly similar. Our petrologic and geochemical data led us to view the rocks as members of a mafic–ultramafic assemblage typical of cumulate portions of ophiolite complexes and backarc spreading centers. The plutonic complexes of the Shirshov Rise and Stalemate Ridge show similarities not only in the petrography and mineralogy of their protoliths but also in the character of their metamorphic transformations. Plutonic rocks from both areas display mineralogical evidence of metamorphism within a broad temperature range: from the high-temperature amphibolite facies to the greenschist facies. Relations between the index mineral assemblages indicate that the metamorphic history of plutonic complexes in the Stalemate Ridge and Shirshov Rise proceeded along a retrograde path. Hornblende schists accompanying the plutonic rocks of the Stalemate Ridge and Shirshov Rise are petrographically close to foliated amphibolites in subophiolitic metamorphic aureoles. Within the framework of geodynamic interpretations of our results, it is realistic to suggest that the examined plutonic complexes were exhumed from subduction zones of various age.
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  • 3
    Publication Date: 2019-10-24
    Description: Asymmetrically zoned hotspot tracks in the Pacific Ocean are interpreted to have formed from zoned plumes originating from the large-scale, lower-mantle, low-seismic-velocity anomaly (superplume?) beneath the southern Pacific, providing direct information about lowermantle compositional heterogeneity. New trace-element and Sr-Nd-Hf-Pb isotope data from the classic Tristan-Gough hotspot track in the South Atlantic also display a bilateral, asymmetric zonation with two distinct mantle source components, making it the first zoned plume to be recognized overlying the African superplume. The plume zonation can be traced for 70 m.y., four times longer than recognized for Pacific zoned hotspot tracks. These findings confirm that the proposed zonation of Pacific hotspots is not simply a geochemical oddity, but could be a major feature of plumes derived from lower-mantle superplumes. We propose that the enriched southern Gough subtrack source with elevated 207Pb/204Pb and 208Pb/204Pb at a given 206Pb/204Pb, but low 143Nd/144Nd and 176Hf/177Hf (DUPAL-like composition), may reflect the African superplume composition, whereas the more depleted northern Tristan subtrack source could represent a mixture of the superplume with the surrounding depleted mantle. Our results strengthen arguments that the enriched signature (DUPAL anomaly) in the South Atlantic could be derived from the lower mantle.
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  • 4
    Publication Date: 2019-10-24
    Description: Basalts from intraplate or hotspot ocean islands (e.g., the Hawaiian, Galápagos, and Canary Islands) are believed to be formed by mantle plumes, which emanate from mantle boundary layers such as the coremantle boundary. The long-term chemical structure of mantle plumes, however, remains poorly constrained. Spatial variation in the chemical composition has long been recognized in lavas from the Galápagos Islands: Enriched plume material forms a horseshoe-shaped region with depleted mantle, similar in composition to mid-ocean ridge basalt, in its inner part. The enriched horseshoe-shaped region can be subdivided into three distinct geochemical domains. We show that these same domains occur in the same relative positions with respect to morphology in a geochemical profile across the Galápagos hotspot track off the coast of Costa Rica, indicating that the asymmetrical spatial zonation of the Galápagos hotspot has existed for at least 14 m.y. Combined with published He isotope data, the results of this study imply that plume material can ascend from the lower mantle, possibly from the core-mantle boundary, with little stirring occurring during ascent, and that zonation in hotspot lavas may in some cases reflect spatial heterogeneity within the lower mantle source.
    Type: Article , PeerReviewed
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  • 5
    Publication Date: 2019-09-23
    Description: In this paper, we constrain the input and output fluxes of H2O, Cl and S into the southern-central Chilean subduction zone (31°S–46°S). We determine the input flux by calculating the amounts of water, chlorine and sulfur that are carried into the subduction zone in subducted sediments, igneous crust and hydrated lithospheric mantle. The applied models take into account that latitudinal variations in the subducting Nazca plate impact the crustal porosity and the degree of upper mantle serpentinization and thus water storage in the crust and mantle. In another step, we constrain the output fluxes of the subduction zone both to the subcontinental lithospheric mantle and to the atmosphere–geosphere–ocean by the combined use of gas flux determinations at the volcanic arc, volume calculations of volcanic rocks and the combination of mineralogical and geothermal models of the subduction zone. The calculations indicate that about 68 Tg/m/Ma of water enters the subduction zone, as averaged over its total length of 1,480 km. The volcanic output on the other hand accounts for 2 Tg/m/Ma or 3 % of that input. We presume that a large fraction of the volatiles that are captured within the subducting sediments (which accounts for roughly one-third of the input) are cycled back into the ocean through the forearc. This assumption is however questioned by the present lack of evidence for major venting systems of the submarine forearc. The largest part of the water that is carried into the subduction zone in the crust and hydrated mantle (accounting for two-thirds of the input) appears to be transported beyond the volcanic arc.
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  • 6
    Publication Date: 2019-10-24
    Description: Volcanic rocks were dredged from the Cocos and Fisher ridges and seamounts along a 250 km profile parallel to the Pacific coast of Costa Rica. The composition and laser 40Ar/39Ar ages of the Cocos Ridge and Seamounts are consistent with their formation above the Galápagos hotspot 13.0–14.5 Ma. The reconstructed paleoenvironment and chemistry of the Fisher Ridge are consistent with it having originated at a mid-oceanic ridge system. Laser 40Ar/39Ar dating of fresh basalt glass from the Fisher Ridge yielded isochron ages of 19.2 ± 0.3 Ma and 30.0 ± 0.5 Ma. The Fisher Ridge is along a lithospheric fault that may represent an extensional fracture formed when the oceanic floor rode over the Galápagos hotspot. Even though the younger structures are currently at water depths of 〉1000 m, volcanological, geochemical, and geophysical observations indicate that they once formed an emerged archipelago very similar in morphology to the Galápagos islands. The diversity of the biota on the isolated Galápagos islands, as first described by Charles Darwin, has had an important influence on the development of the theory of evolution. The existence of a now-drowned Galápagos archipelago 14.5 Ma considerably increases speciation times for the Galápagos biota and provides a complete solution to a long-standing controversy concerning the divergence of the Galápagos marine and land iguanas from a single ancestral species.
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  • 7
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    Springer
    In:  International Journal of Earth Sciences, 103 (8). pp. 2351-2357.
    Publication Date: 2017-05-23
    Description: This study presents laser step-heating 40Ar/39Ar age determinations of basaltic lava samples from Tamu Massif, the oldest and largest edifice of the submarine Shatsky Rise in the northwest Pacific and Earth’s proposed largest volcano. The rocks were recovered during Integrated Ocean Drilling Program Expedition 324, which cored 160 m into the igneous basement near the summit of Tamu Massif. The analyzed lavas cover all three major stratigraphic groups penetrated at this site and confirm a Late Jurassic/Early Cretaceous age for the onset of Shatsky Rise volcanism. Lavas analyzed from the lower and middle section of the hole yield plateau ages between 144.4 ± 1.0 and 143.1 ± 3.3 Ma with overlapping analytical errors (2σ), whereas a sample from the uppermost lava group produced a significantly younger age of 133.9 ± 2.3 Ma suggesting a late or rejuvenated phase of volcanism. The new geochronological data infer minimum (average) melt production rates of 0.63–0.84 km3/a over a time interval of 3–4 million years consistent with the presence of a mantle plume.
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  • 8
    Publication Date: 2019-10-24
    Description: At the present, the geochemical influence of the Galápagos hotspot (offshore South America) can be seen only along the Galápagos spreading center, north of the hotspot. It is possible, however, that Galápagos plume material also reached the East Pacific Rise in the past. Detecting such influence would be of particular importance for the interpretation of geochemical data from oceanic crust at Ocean Drilling Program (ODP) Site 1256, which formed ∼15 m.y. ago at the East Pacific Rise during a Miocene period of superfast spreading, and is considered to be a reference site for oceanic crust produced at fast-spreading ridges. Here we present geochemical data from Miocene basaltic crust (23–7 Ma) drilled at several Deep Sea Drilling Project (DSDP), ODP, and Integrated Ocean Drilling Program (IODP) sites that formed along the East Pacific Rise between 3°S and 7°N. Lavas formed between ca. 22.5 and ca. 11 Ma show enriched, Galápagos plume–like Pb and Nd isotope ratios (with a peak in enrichment between ≥18 and 12 Ma) compared to lavas created shortly before or after this time interval. Despite their enriched isotope composition, these samples generally show depletion in more-incompatible, relative to less-incompatible, trace elements. Derivation from an enriched Galápagos plume source that had experienced recent melt extraction before it melted further beneath the East Pacific Rise can explain the combined incompatible-trace-element depletion and isotopic enrichment of the 22.5–11 Ma lavas. The influence of plume material correlates with the interval of superfast spreading along the equatorial East Pacific Rise, suggesting a causal relationship. Enhanced ridge-plume interaction ("ridge suction") due to superfast spreading could have facilitated the flow of Galápagos plume material to the ridge. On the other hand, the arrival of Galápagos-type signatures took place immediately after formation of the Galápagos spreading center, which could have provided a pathway for hot plume material to spread into the main ridge network.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2019-09-23
    Description: Subduction zones of continental, transitional, and oceanic settings, relative to the nature of the overriding plate, are compared in terms of trace element compositions of mafic to intermediate arc rocks, in order to evaluate the relationship between subduction parameters and the presence of subduction fluids. The continental Chilean Southern Volcanic Zone (SVZ) and the transitional to oceanic Central American Volcanic Arc (CAVA) show increasing degrees of melting with increasing involvement of slab fluids, as is typical for hydrous flux melting beneath arc volcanoes. At the SVZ, the central segment with the thinnest continental crust/lithosphere erupted the highest-degree melts from the most depleted sources, similar to the oceanic-like Nicaraguan segment of the CAVA. The northern part of the SVZ, located on the thickest continental crust/lithosphere, exhibits features more similar to Costa Rica situated on the Caribbean Large Igneous Province, with lower degrees of melting from more enriched source materials. The composition of the slab fluids is characteristic for each arc system, with a particularly pronounced enrichment in Pb at the SVZ and in Ba at the CAVA. A direct compositional relationship between the arc rocks and the corresponding marine sediments that are subducted at the trenches clearly shows that the compositional signature of the lavas erupted in the different arcs carries an inherited signal from the subducted sediments.
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  • 10
    Publication Date: 2019-09-23
    Description: The broad belt of intraplate volcanism in the East Atlantic between 25° and 37° N is proposed to have formed by two adjacent hotspot tracks (the Madeira and Canary tracks) that possess systematically different isotopic signatures reflecting different mantle source compositions. To test this model, Hf isotope ratios from volcanic rocks from all individual islands and all major seamounts are presented in this study. In comparison with published Nd isotope variations (6 εNd units), 176Hf/177Hf ratios span a much larger range (14 εHf units). Samples from the proposed Madeira hotspot track have the most radiogenic Hf isotopic compositions (176Hf/177Hfm up to 0.283335), extending across the entire field for central Atlantic MORB. They form a relatively narrow, elongated trend on the Nd vs. Hf isotope diagram (stretching over 〉10 εHf units) between a depleted N-MORB-like endmember and a moderately enriched composition located on, or slightly below, the Nd–Hf mantle array, which overlaps the proposed "C" mantle component of Hanan and Graham (1996). In contrast, all samples from the Canary hotspot track plot below the mantle array (176Hf/177Hfm = 0.282943–0.283067) and form a much denser cluster with less compositional variation (~4 εHf units). The cluster falls between (1) a low Hf isotope HIMUlike endmember, (2) a more depleted composition, and (3) the moderately enriched end of the Madeira trend. The new Hf isotope data confirm the general geochemical distinction of the Canary and Madeira domains in the East Atlantic. Both domains, however, seem to share a common, moderately enriched endmember that has "C"-like isotope compositions and is believed to represent subducted, 〈1-Ga-old oceanic lithosphere (oceanic crust and possibly minor sediment addition). The lower 176Hf/177Hf ratio of the enriched, HIMU-like Canary domain endmember indicates the contribution of oceanic lithosphere with somewhat older recycling ages of 〉=1 Ga.
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