Description: Highlights • Individual evolution of temporal and spatial co-existing magma suites • Determination of pre-eruptive magma chamber conditions of the Cão Grande Formation magma chambers • Cão Grande Formation phonolite magmas typically reach H2O-saturation prior to the eruption. Abstract The Cão Grande Formation (CGF) on the western plateau of Santo Antão is a sequence of four phonolitic tephras (Canudo Tephra, Cão Grande I Tephra, Cão Grande II Tephra and Furninha Tephra) produced by highly explosive eruptions that alternatingly originated from a basanitic - phonolitic and a nephelinitic - phonolitic magmatic system. Detailed stratigraphy and petrological investigations of each unit are used to demonstrate the unusual situation that two distinct highly evolved magmas differentiated contemporaneously in separate magmatic systems. Chemical thermobarometry suggests that both magmatic systems not only temporally co-existed, but also that their magma chambers resided close to each other at 7 to 16 km depth, beneath the western plateau of Santo Antão. However, the distinct melt and magma compositions indicate that both systems evolved independently. The only interaction between both magmatic systems was an injection of magma from the nephelinitic - phonolitic magmatic system into the Cão Grande II Tephra (CG II) phonolitic reservoir, which is associated to the basanitic - phonolitic magmatic system. Compositional zonations in the tephra deposits indicate that the eruptions of the CGF tapped stratified magma reservoirs that mainly resulted from crystal accumulation generating downward increasing magma density. However, the CG II tephras also show a significant gradient in melt (glass) compositions. Magmas of the Canudo Tephra (CT) and the Cão Grande I Tephra (CG I) were H2O-saturated and their eruptions were probably triggered by fluid overpressure in the magma chamber. On the other hand, the CG II magma was H2O-undersaturated; we therefore assume that the injection of the hot nephelinitic - phonolitic magma system-type melt/magma triggered the eruption. The zoned deposit of the Furninha Tephra (FT) indicates mafic magma replenishment into a phonolitic reservoir directly prior to the eruption, thus providing a probable triggering mechanism. The new magma chamber models and thermobarometric results for the four CGF units provide constraints for hazard assessments, because similar events may occur in the future considering the longevity of the CGF magma systems.

Description: A rigorous detection of Milankovitch periodicities in volcanic output across the Pleistocene-Holocene ice age has remained elusive. We report on a spectral analysis of a large number of well-preserved ash plume deposits recorded in marine sediments along the Pacific Ring of Fire. Our analysis yields a statistically significant detection of a spectral peak at the obliquity period. We propose that this variability in volcanic activity results from crustal stress changes associated with ice age mass redistribution. In particular, increased volcanism lags behind the highest rate of increasing eustatic sea level (decreasing global ice volume) by 4.0 ± 3.6 k.y. and correlates with numerical predictions of stress changes at volcanically active sites. These results support the presence of a causal link between variations in ice age climate, continental stress field, and volcanism.

Description: During IODP NanTroSEIZE Expedition 322, four packages of tuffaceous sandstones (TST 1, 2, 3a, 3b) were recovered within a moderately lithified and bioturbated silty claystone succession in the Late Miocene (〉 7.6 to ~ 9.1 Ma) upper part of the middle Shikoku Basin deposits. To assess the emplacement processes of the tuffaceous sandstones we investigate modal and geochemical compositions of 24 thin sections that reveal systematic vertical changes within each bed. TST 1, 2 and 3b are single beds whereas TST 3a is composed of at least two beds suggesting several rapidly succeeding sedimentation events. The beds are density-graded such that low-density pyroclasts including pumice lapilli are enriched at the top whereas dense lithic components and minerals are enriched at the bottom. The volcanic glass particles (pumice and shards) that are the dominant modal constituents of each sandstone bed have homogeneous geochemical compositions in each bed. Moreover, TST 1, 2, and 3a glass compositions overlap completely but TST 3b glass has a different composition, as is analogously observed for the mineral compositions. This unique multistage approach of sedimentological and geochemical methods facilitated the detailed investigation of distal volcano-derived, probably tsunamogenic, turbidites in order to contribute to the distinction between primary and secondary induced mass flows. We interpret that all tuffaceous sandstones were emplaced by turbidity currents that were formed during major explosive volcanic eruptions. However, while TST 1, 2, and 3a turbidity currents formed by the entry into the ocean of voluminous pyroclastic flows erupted at a volcano on mainland Japan, TST 3b was emplaced by a turbidity current formed by a shallow submarine or subaerial volcanic eruption at the Izu–Bonin arc where it collided with Japan. These results regarding distal turbidites encourage the revisiting of older marine deposits in the scope of hazard evaluation through past events, especially in regions near to volcanic sources.

Description: Highlights • Subplinian to Plinian eruptions from Cocos Island • Tectonically controlled melt ascent • Ocean island evolution without passing typical growth stages Abstract We report a series of fourteen marine tephra layers that are the products of large explosive eruptions of Subplinian to Plinian intensities and magnitudes (VEI 〉 4) from Cocos Island, Costa Rica. Cocos Island is a volcanic island in the eastern Central Pacific Ocean ~ 500 km offshore Costa Rica, and is situated on the northwestern flank of the aseismic Cocos Ridge. Geochemical fingerprinting of Pleistocene (~ 2.4–1.4 Ma) marine tephra layers from Ocean Drilling Project (ODP) Leg 202 Site 1241 using major and trace element compositions of volcanic glass shards demonstrates unequivocally their origin from Cocos Island rather than the Galápagos Archipelago or the Central American Volcanic Arc (CAVA). Cocos Island and the adjacent seamounts of the Cocos Island Province have alkalic compositions and formed on young (≤ 3 Ma) oceanic crust from an extinct spreading ridge bounded by a transform fault against the older and thicker crust of the aseismic Cocos Ridge. Cocos Island has six times the average volume of the adjacent seamounts although all appear to have formed during the 3–1.4 Ma time period. Cocos Island lies closest to the transform fault and we explain its excessive growth by melts rising from garnet-bearing mantle being deflected from the thick Cocos Ridge lithosphere toward the thinner lithosphere on the other side of the transform, thus enlarging the melt catchment area for Cocos Island compared to the seamounts farther away from the transform. This special setting favored growth above sea level and subaerial explosive eruptions even though the absence of appropriate compositions suggests that the entirely alkalic Cocos Island (and seamounts) never evolved through the productive tholeiitic shield stage typical of other Pacific Ocean islands, possibly because melt production rates remained too small. Conditions of magma generation and ascent resembled Hawaiian pre-shield volcanoes but persisted for much longer (〈 1 m.y.) and formed evolved, trachytic magmas. Therefore Cocos Island may be a unique example for a volcanic ocean island that did not pass through the typical growth stages.

Description: The upper Quaternary pyroclastic flow deposits of Laacher See volcano show compositional and structural facies variations on four different scales: (1) eruptive units of pyroclastic flows, composed of many flow units; (2) depositional cycles of as many as five flow units; flow units containing (3) regional intraflow-unit facies; and (4) local intraflow-unit subfacies. These facies can be explained by successively overlapping processes beginning in the magma column and ending with final deposition. The pyroclastic flow deposits thus reflect major aspects of the eruptive history of Laacher See volcano: (a) drastic changes in eruptive mechanism due to increasing access of water to the magma chamber and (b) change in chemical composition and crystal and gas content as evacuation of a compositionally zoned magma column progressed. The four scales of facies result from four successive sets of processes: (1) differentiation in the magma column and external factors governing the mechanism of eruption; (2) temporal variations of factors inducing eruption column collapse; (3) physical conditions in the eruption column and the way in which its collapse proceeds; and (4) interplay of flow-inherent and morphology-induced transport mechanics.

Description: Small-volume (ca. 0.6 km3) pyroclastic flow deposits at Laacher See contain lithic breccias and two types of ground layers that differ significantly in their structure and composition from the main body of flow units. Lithic breccia bodies, up to 3.5 m thick, containing up to 85 weight% lithic blocks, occur locally at various distances from the vent. The deposition of these breccias was apparently governed by the strong influence of paleomorphology on the dynamics of the pyroclastic flows. The breccias were deposited at three main changes in bottom gradient along the path of the pyroclastic flows. The accumulation of large lithics is explained: (a) by compression of flows on the rising bottom close to the vent; (b) by thinning of flows accelerating over a steep incline; (c) by deceleration of the pre-concentrated lower part of flows in hydraulic jumps; and (d) possibly by a stationary vortex at the inner bend of a valley curvature. Poorly sorted lithic-rich ground layers, laterally highly variable in internal structure and composition, are restricted to marginal regions of the pyroclastic flow deposits within deep and narrow valleys. They are interpreted as having formed due to the extreme roughness of the valley walls, enforcing irregular turbulent flow and intense fluidization of the flow head, in which density-dominated segregation of lithics occurred. Wellsorted lapilli-rich ground layers of constant lateral thickness were probably generated by a more regularly moving, less intensely fluidized head of pyroclastic flows in which size-dominated segregation was effective but density-segregation was minor. A model of the temporal and longitudinal evolution of a flow head is proposed. Close to the vent, the head is exclusively erosive. With increasing distance, erosive power declines and erosion is paralleled by ground layer formation under strong fluidization. Further from the vent, the head ceases to erode while fluidization is still sufficient for ground layer formation. When fluidization declines to a level ineffective for segregation, ground layers terminate while the head advances and only terminates when plug-flow dominates.

Description: Lahars, debris flows, and sediment-rich floods are frequent and deadly hazards at all mountain-forming volcanoes. Their hazard potential is traditionally assessed through mass-conserving closed-system models, where peak conversion rates of potential energy to mechanical energy and hence maximum destruction potential are predicted to occur on the steepest volcano flanks. This belies evidence of extremely high-energy and deadly catastrophes caused by such flows at large distances from volcanoes. Here we use the first high-resolution record of a moving lahar to develop a new model of the temporally and spatially variable mass-flow structure. We show that bulk flow energy can grow dramatically in such systems over tens to hundreds of kilometers via momentum transfers from the lahar into water and particles along its path. We also demonstrate that dynamic transformations of such flows and their ultimate runout are primarily controlled by the mass flow front.

Description: The dacite to andesite zoned Mateare Tephra is the fallout of a predominantly plinian eruption from Chiltepe peninsula at the western shore of Lake Managua that occurred 3000–6000 years ago. It comprises four units: Unit A of high-silica dacite is stratified, ash-rich lapilli fallout generated by unsteady subplinian eruption pulses affected by minor water access to the conduit and conduit blocking by degassed magma. Unit B of less silicic dacite is well sorted, massive pumice lapilli fallout from the main, steady plinian phase of the eruption. Unit C is andesitic fallout that is continuous from unit B except for the rapid change in chemical composition, which had little influence on the ongoing eruption except for a minor transient reduction of the discharge rate and access of water to the conduit. After this, discharge rate re-established to a strong plinian eruption that emplaced the main part of unit C. This was again followed by water access to the conduit which increased through upper unit C. The lithic-rich lapilli to wet ash fallout of unit D is the product of the fully phreatomagmatic terminal phase of the eruption. A massive well-sorted sand layer, the Mateare Sand, replaces laterally variable parts of unit A and lowermost part of unit B in outcrops up to 32 m above present lake level. The corresponding interval missing in the primary fallout can be identified by comparing the composition of pumice entrained in the sand, and pumice from the local base of unit B on top of the sand, with the compositional gradient in undisturbed fallout. The amount of fallout entrained in the sand decreases with distance to the lake. The Mateare Sand occurs at elevations well above beach levels and its widespread continuous distribution defies a fluviatile origin. Instead, it was produced by lake tsunamis triggered by eruption pulses during the initial unsteady phase of activity. Such tsunamis could threaten areas not affected by fallout, and represent a hazard of particular importance in Nicaragua where two large lakes host several explosive volcanoes.

Description: Highlights: • Two new phonolitic tephra units complementing the two previously known. • First radiometric ages of the CGF. • Contemporaneously evolution of the CGF and the Tope de Coroa. • Marine correlations improve tephra volume estimations for CG I and II. Abstract: The Cão Grande Formation (CGF) on the western plateau of Santo Antão Island is part of the younger volcanic sequence that originated from both, basanitic and nephelinitic magmatic suites, respectively called COVA and COROA suites. Based on our detailed revised stratigraphy of the CGF, including two yet unknown tephra units, we can show that both suites produced multiple, highly differentiated eruptions over a contemporaneous period. Correlations of CGF tephras with marine ash layers provide distal dispersal data for Cão Grande I (CG I) and also identify two highly explosive, phonolitic eruptions that pre-date the CGF tephra deposits known on land. Within the CGF, the lowermost, 220±7 ka old unit Canudo Tephra (CT; COVA suite) comprises phonolitic fall deposits and ignimbrites; it is partly eroded and overlain by debris flow deposits marking a hiatus in highly differentiated eruptions. The phonolitic CG I Tephra (COROA suite) consists of an initial major plinian fall deposit and associated ignimbrite and terminal surge deposits. This is immediately overlain by the phonolitic to phono-tephritic Cão Grande II (CG II; COVA suite), a complex succession of numerous fallout layers and density-current deposits. CG I and CG II have radiometric ages of 106±3 ka and 107±15 ka, respectively, that are identical within their error limits. The youngest CGF unit, the Furninha Tephra (FT; COROA suite), consists of three foidic-phonolitic fall deposits interbedded with proximal scoria deposits from a different vent. The phonolitic eruptions switched to and fro between both magmatic suites, in each case with a stronger first followed by a weaker second eruption. Each eruption evolved from stable to unstable eruption columns. During their terminal phases, both magma systems also leaked evolved dome-forming lavas next to the tephras. Distal ashes increase the CG I tephra volume to ~ 10 km3, about twice the previously published estimate. The tephra volume of CG II is ~ 3 km3; CT and FT are too poorly exposed for volume estimation. The characteristics of the CGF tephra units outline hazard conditions that may be expected from future evolved explosive eruptions on the western plateau of Santo Antão.