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  • Newark :John Wiley & Sons, Incorporated,  (6)
  • Millersville, PA :Materials Research Forum LLC,  (3)
  • Milton :Taylor & Francis Group,  (3)
  • Cham :Springer International Publishing AG,  (2)
Document type
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  • 1
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Green chemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (299 pages)
    Edition: 1st ed.
    ISBN: 9783030678845
    Series Statement: Advances in Science, Technology and Innovation Series
    DDC: 660.0286
    Language: English
    Note: Intro -- Contents -- 1 Biomass-Derived Polyurethanes for Sustainable Future -- Abstract -- 1 Introduction -- 1.1 Chemicals for Preparation of Polyurethanes -- 1.2 Importance of Green Chemicals and Synthesis Methods -- 1.3 Characteristics of Biomaterials for Polyurethanes -- 2 Bio-Oils as a Renewable Resource for Polyurethanes -- 2.1 Epoxidation and Ring-Opening Reactions -- 2.2 Hydroformation and Hydrogenation Reactions -- 2.3 Ozonolysis -- 2.4 Thiol-Ene Reaction -- 2.5 Transesterification Reaction -- 3 Terpenes as Green Starting Chemicals for Polyurethanes -- 4 Lignin for Green Polymers -- 5 Conclusion -- References -- 2 Mechanochemistry: A Power Tool for Green Synthesis -- Abstract -- 1 Introduction -- 2 History of Mechanochemistry -- 3 Principles of Mechanochemistry -- 3.1 Mechanisms and Kinetics of Mechanochemistry -- 3.2 Effects of Reaction Parameters -- 4 Mechanochemical Synthesis of Materials -- 4.1 Mechanochemical Synthesis of Co-crystals -- 4.2 Mechanochemistry in Inorganic Synthesis -- 4.3 Mechanochemistry in Organic Synthesis -- 4.4 Mechanochemistry in Metal-Organic Frameworks (MOFs) -- 4.5 Mechanochemistry in Porous Organic Materials (POMs) -- 4.6 Mechanochemical Synthesis of Polymers -- 5 Conclusions -- References -- 3 Future Trends in Green Synthesis -- Abstract -- 1 Introduction -- 2 Green Chemistry Metrics -- 2.1 Atom Economy (AE) -- 2.2 Environmental Factor (E Factor) -- 2.3 Process Mass Intensity (PMI) -- 2.4 Reaction Mass Efficiency (RME) -- 3 Application of Green Concept in Synthesis -- 3.1 Solvent-Based Organic Synthesis -- 3.2 Aqueous Medium -- 3.2.1 Micellar Media -- 3.2.2 Different Non-Aqueous Media -- Ionic Liquids -- Fluorous Media -- Supercritical Fluid -- Solvent-Free Synthesis -- 4 Future Trends -- References -- 4 Plant-Mediated Green Synthesis of Nanoparticles -- Abstract -- 1 Introduction. , 2 Methods for Metallic Nanoparticle Biosynthesis -- 3 Green Biosynthesis of Metallic NPs -- 3.1 Gold Nanoparticles -- 3.2 Platinum Nanoparticles -- 3.3 Silver Nanoparticles -- 3.4 Zinc Oxide Nanoparticles -- 3.5 Titanium Dioxide Nanoparticles -- 4 Different Parts Used for the Synthesis of Metallic Nanoparticles -- 4.1 Fruit -- 4.2 Stem -- 4.3 Seeds -- 4.4 Flowers -- 4.5 Leaves -- 5 Conclusions -- References -- 5 Green Synthesis of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- Abstract -- 1 Introduction -- 2 Advantages of Green Synthesis Methods -- 3 Green Synthesis Methods for Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 3.1 Biological Methods -- 3.1.1 Using Microorganism -- Microorganisms as Reactant -- Microorganism as Template -- 3.1.2 Using Plant -- Plant as Reactant -- Plant as Template -- 3.1.3 Using Other Green Templates -- 3.2 Physical and Chemical Methods -- 3.2.1 Green Techniques -- 3.2.2 Green Reagents -- 3.2.3 Green Solvents -- 4 Growth Mechanism of Metal and Metal Oxide HSNs -- 4.1 Biological Method -- 4.1.1 Biomolecules as Reagents -- 4.1.2 Biomolecules as Templates -- 4.2 Physical and Chemical Methods -- 5 Applications of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 5.1 Biomedical Application -- 5.2 Environmental Remediation -- 5.2.1 Wastewater Treatment -- 5.2.2 Energy Storage -- 5.2.3 Sensing -- 6 Present Challenges and Future Prospect -- Acknowledgements -- References -- 6 Bioprivileged Molecules -- Abstract -- 1 Introduction -- 2 Four Carbon 1,4-Diacids -- 2.1 Succinic Acid -- 2.2 Fumaric Acid -- 2.3 Malic Acid -- 3 Furan 2,5-Dicarboxylic Acid (FDCA) -- 4 3-Hydroxypropionic Acid (3-HPA) -- 5 Glucaric Acid -- 6 Glycerol -- 7 Aspartic Acid -- 8 Itaconic Acid -- 9 3-Hydroxybutyrolactone -- 10 Sorbitol -- 11 Xylitol -- 12 Glutamic Acid -- 13 Levulinic Acid. , 14 Emerging Molecules -- 15 Conclusion -- References -- 7 Membrane Reactors for Green Synthesis -- Abstract -- 1 Introduction -- 2 Chemical Reaction Enzymatic MR Using Supercritical CO2-IL -- 2.1 Ionic Liquid Media Effect on Free CLAB -- 2.2 Butyl Propionate Synthesis Using Active Membranes SC-CO2 and SC-CO2/IL -- 2.3 Butyl Propionate Synthesis Using Active Membranes in Hexane/IL -- 3 Mixed Ionic Electronic MR -- 3.1 Methane Flow Rate and Concentration Effects on Side II of Membrane -- 3.2 Steam Flow Effect on Side I of Membrane -- 3.3 Temperature Effect -- 4 Green Synthesis of Methanol in a Membrane Reactor -- 5 Green Fuel Energy -- 5.1 Green H2 Energy -- 5.2 Biofuel Energy -- 5.3 Green Fuel Additive -- 6 Biocatalyst Membrane Reactors -- 7 Photocatalytic Membrane Reactors -- 8 Conclusions -- References -- 8 Application of Membrane in Reaction Engineering for Green Synthesis -- Abstract -- 1 Introduction -- 2 Applications of Membrane Reactors in Reaction Engineering -- 2.1 Syngas Production -- 2.2 Hydrogen Production -- 2.3 CO2 Thermal Decomposition -- 2.4 Higher Hydrocarbon Production -- 2.5 Methane Production -- 2.6 Ammonia Production -- 3 Environmental Impacts -- 4 Conclusions and Future Recommendations -- Acknowledgements -- References -- 9 Photo-Enzymatic Green Synthesis: The Potential of Combining Photo-Catalysis and Enzymes -- Abstract -- 1 Introduction -- 2 Principle -- 3 Enzymes Involved in Light-Driven Catalysis -- 3.1 Heme-Containing Enzymes -- 3.1.1 Cytochrome P450 -- 3.1.2 Peroxidases -- 3.2 Flavin-Based Enzyme -- 3.2.1 Baeyer-Villiger Monooxygenases -- 3.2.2 Old Yellow Enzymes -- 3.3 Metal Cluster-Centered Enzyme -- 3.3.1 Hydrogenases -- 3.3.2 Carbon Monoxide Dehydrogenases -- 4 Nanoparticle-Based Activation of Enzyme -- 5 Applications in Photo-Biocatalysis -- 5.1 Isolated Enzymes/Cell Lysates -- 6 Summary and Future Scope -- References. , 10 Biomass-Derived Carbons and Their Energy Applications -- Abstract -- 1 Introduction -- 2 Types of Biomass Materials -- 2.1 Plant-Based Carbons -- 2.2 Fruit-Based Carbons -- 2.3 Animal-Based Carbons -- 2.4 Microorganism-Based Carbons -- 3 Activation of Biomass-Derived Carbons -- 3.1 Activation of Carbons -- 3.1.1 Chemical Activation of Carbons -- 3.1.2 Carbon Activation Through Physical Method -- 3.1.3 Self-activation of Carbons -- 3.2 Pyrolysis Techniques -- 3.2.1 Effect of Temperature -- 3.2.2 Effect of Residence Time -- 3.2.3 Heating Rate Effect -- 3.2.4 Size of the Particle -- 3.3 Microwave-Assisted Technique -- 3.4 Carbonization by Hydrothermal -- 3.5 Ionothermal Carbonization -- 3.6 Template Method -- 4 Energy Storage Applications of Biomass Carbons -- 4.1 Supercapacitors -- 4.2 Li/Na-Ion Batteries -- 5 Conclusion -- Acknowledgements -- References -- 11 Green Synthesis of Nanomaterials via Electrochemical Method -- Abstract -- 1 Introduction -- 2 Green Synthesis -- 2.1 Application of Biology in Green Synthesis -- 2.2 Green Synthesis Based on the Application of Solvent -- 3 Computational Data and Analysis -- 4 Electrochemical Method -- 5 Electrodeposition Method -- 5.1 Experimental Setup for Electrodeposition -- 6 Research Work: Using Green Electrochemical Methods for Nanomaterials Synthesis -- 7 Conclusion -- References -- 12 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridine Class of Bio-heterocycles: Green Avenues and Sustainable Developments -- Abstract -- 1 Introduction -- 2 Microwave-Assisted Synthesis of 2-arylimidazo[1,2-a]pyridines [Abbreviated as 2-Aryl-IPs]. -- 2.1 Synthesis of Fused Bicyclic Heteroaryl Boronates and Imidazopyridine-Quinazoline Hybrids Under MW-irradiations -- 2.2 MW-Irradiated Synthesis of IPs Using Multi-Component Strategy Under Neat Conditions. , 2.3 One-Pot, Three-Component Synthesis of 2-Phenyl-H-Imidazo[1,2-α]pyridine Under MW-Irradiations -- 2.4 Microwave-Assisted Amine-Triggered Benzannulation Strategy for the Preparation of 2,8-Diaryl-6-Aminoimidazo-[1,2-a]pyridines -- 2.5 MW-Assisted NaHCO3-catalyzed Synthesis of Imidazo[1,2-a]pyridines in PEG400 Media and Its Practical Application in the Synthesis of 2,3-Diaryl-IP Class of Bio-Heterocycles -- 2.6 MW-Irradiated, Ligand-Free, Palladium-Catalyzed, One-Pot 3-component Reaction for an Efficient Preparation of 2,3-Diarylimidazo[1,2-a]pyridines -- 2.7 MW-Assisted Water-PEG400-mediated Synthesis of 2-Phenyl-IP via Multi-Component Reaction (MCR) -- 2.8 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridines Under Neat, Catalyst-Free Conditions -- 2.9 Green Synthesis of Imidazo[1,2-a]pyridines in H2O -- 2.10 Microwave-Assisted Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]Pyridines -- 2.11 Microwave-Assisted Nano SiO2 Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]pyridines -- 2.12 Microwave-Assisted NaHCO3-Catalyzed Synthesis of 2-phenyl-IPs -- 3 Microwave-Assisted Synthesis of 3-amino-2-arylimidazo[1,2-a]pyridines [3-amino-2-aryl-IPs] -- 3.1 Microwave-Irradiated Synthesis of 3-aminoimidazo[1,2-a]pyridines via Fluorous Multi-component Pathway -- 3.2 MW-Irradiated Synthetic Protocol for 3-aminoimidazo[1,2-a]pyridines via MCR Pathway -- 3.3 MW-Assisted Sequential Ugi/Strecker Reactions Involving 3-Center-4-Component and 3-Center-5-Component MCR Strategy -- 3.4 One-Pot, 4-component Cyclization/Suzuki Coupling Leading to the Rapid Formation of 2,6-Disubstituted-3-Amino-IPs Under Microwave Irradiations -- 3.5 ZnCl2-catalyzed MCR of 3-aminoimidazo[1,2-a]pyridines Using MW Conditions -- 3.6 Microwave-Promoted Preparation of N-(3-arylmethyl-2-oxo-2,3-dihydroimidazo[1,2-a]pyridin-3-Yl)Benzamides. , 3.7 MW-Assisted Multi-component Neat Synthesis of Benzimidazolyl-Imidazo[1,2-a]pyridines.
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  • 2
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Renewable energy sources. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (354 pages)
    Edition: 1st ed.
    ISBN: 9783030728779
    Series Statement: Advances in Science, Technology and Innovation Series
    DDC: 628.532
    Language: English
    Note: Intro -- Contents -- 1 Chemical Valorization of CO2 -- Abstract -- 1 Introduction -- 2 CO2-Derived Fuels and Chemicals -- 2.1 Methane -- 2.2 Methanol -- 2.3 Dimethyl Ether -- 2.4 Formic Acid -- 2.5 Ethanol -- 2.6 CO2-Fischer-Tropsch Liquid Fuels -- 2.7 Carbon Monoxide-Syngas -- 3 CO2 Chemically Derived Materials -- 3.1 Polymers -- 3.2 CO2-Derived Building Materials -- 4 Conclusions -- References -- 2 Progress in Catalysts for CO2 Reforming -- Abstract -- 1 Introduction -- 2 Technologies for Capturing and Storing Carbon Dioxide -- 3 Technologies for Using Carbon Dioxide -- 4 Methane Dry Reforming Process -- 4.1 Progress in Catalysts for Methane Dry Reforming (1928-1989) -- 4.2 Progress in Catalysts for Methane Dry Reforming (1990-1999) -- 4.3 Progress in Catalysts for Methane Dry Reforming (2000-2009) -- 4.4 Progress in Catalysts for Methane Dry Reforming (2010-2019) -- 4.5 Current Status in the Catalysts for Methane Dry Reforming -- 5 Dry Reforming of Other Compounds -- 6 Use of Steam or Oxygen in Dry Reforming of Methane and Other Compounds -- 7 Solid Oxide Fuel Cells Fueled with Biogas -- 8 Commercialization of Dry Reforming Process -- 9 Conclusions -- References -- 3 Fuel Generation from CO2 -- Abstract -- 1 Introduction -- 2 Approaches for Directly Converting CO2 to Fuels -- 2.1 Pure CO2 Decomposition Technology -- 2.2 Reagent-Based CO2 Conversion Technology -- 2.2.1 Dry Deformation of Methane Technology -- 2.2.2 Catalytic Hydrogenation of CO2 -- 3 Biological CO2 Fixation for Fuels -- 3.1 Thermochemical Conversion -- 3.1.1 Torrefaction -- 3.1.2 Pyrolysis -- 3.1.3 Thermochemical Liquefaction -- 3.1.4 Gasification -- 3.1.5 Direct Combustion -- 3.2 Biochemical Conversion -- 3.2.1 Biodiesel -- 3.2.2 Bioethanol -- 3.2.3 Biomethane -- 3.2.4 Biohydrogen -- 3.2.5 Bioelectricity -- 3.2.6 Volatile Organic Compounds. , 4 Conclusion and Future Perspectives -- References -- 4 Thermodynamics of CO2 Conversion -- Abstract -- 1 Introduction -- 2 Carbon Dioxide Capture -- 3 Carbon Dioxide Utilisations -- 4 Thermodynamic Considerations -- 5 Thermodynamics of CO2 -- 5.1 The Thermodynamic Attainable Region (AR) -- 5.2 Using Hess's Law to Transform the Extents to G-H AR @ 25˚C -- 5.3 Increasing Temperature on G-H AR -- 6 Conclusion -- Acknowledgements -- References -- 5 Enzymatic CO2 Conversion -- Abstract -- 1 Introduction -- 1.1 CO2 as a Greenhouse Gas -- 1.2 Carbon Capture, Storage, and Utilization -- 1.3 CO2 as a Chemical Feedstock -- 1.4 CO2 Conversion with Enzymes -- 2 Natural Conversion of CO2 in Cells -- 3 Enzymatic Conversion of CO2 in Cells -- 3.1 Conversion of CO2 by a Single Enzyme (in vitro) -- 3.1.1 Formate Dehydrogenase -- 3.1.2 Carbonic Anhydrase -- 3.1.3 Carbon Monoxide Dehydrogenase -- 3.1.4 Ribulose-1,5-bisphosphate Carboxylase/Oxygenase (RuBisCO) -- 3.2 Conversion of CO2 by a Multi-Enzyme Cascade in vitro -- 3.3 Other Ways (Photocatalytic CO2 Methanation) -- 4 Industrial Applications -- 4.1 Alcohols -- 4.2 Organic Acids -- 4.3 Terpenoids -- 4.4 Fatty Acids -- 4.5 Polyhydroxyalkanoates -- 4.6 Calcium Carbonate -- 5 Summary and Future Prospects -- References -- 6 Electrochemical CO2 Conversion -- Abstract -- 1 Introduction -- 2 Electrochemical CO2 Conversion -- 2.1 Fundamentals of the Process -- 2.2 Variants of Electrochemical Conversion of CO2 -- 2.2.1 Aqueous Electrolytes -- 2.2.2 Non-Aqueous Electrolytes -- 2.2.3 Solid Oxide Electrolytes -- 2.2.4 Molten Salt Electrolytes -- 3 Electrochemical CO2 Conversion from Molten Salts -- 3.1 Present State of Electrochemical Reduction of CO2in Molten Salts for the Production of Solid-Phase Carbonaceous Nanomaterials -- 3.2 Direct Electrochemical Reduction of CO2 in Chloride Melts. , 3.3 Indirect Electrochemical Reduction of CO2 in Molten Salts -- 3.4 The Mechanisms of Electrode Reactions Occurring at the Cathode and Anode -- 3.5 Prospects for CO2 Conversion in Molten Salts -- 4 Conclusions -- References -- 7 Supercritical Carbon Dioxide Mediated Organic Transformations -- Abstract -- 1 Introduction -- 2 Applications of Supercritical Carbon Dioxide -- 2.1 Hydrogenation Reactions -- 2.2 Asymmetric Hydrogenation Reactions -- 2.3 Diels-Alder Reaction -- 2.4 Coupling Reaction -- 2.5 Oxidation Reaction -- 2.6 Baeyer-Villiger Oxidation Reaction -- 2.7 Iodination Reaction -- 2.8 Polymerization Reaction -- 2.9 Carbonylation Reaction -- 2.9.1 Acetalization Reaction -- 2.9.2 Olefin Metathesis Reaction -- 2.9.3 Synthesis of heterocycles -- Synthesis of α-alkylidene Cyclic Carbonates -- Synthesis of 4-Methyleneoxazolidin-2-Ones -- Synthesis of 5-Alkylidene-1, 3-Oxazolidin-2-Ones -- Synthesis of 6-Phenyl-3a, 4-Dihydro-1H-Cyclopenta[C]furan-5(3H)-One -- Synthesis of 3, 4, 5, 6-Tetraethyl-2H-Pyran-2-One -- 3 Conclusions -- Acknowledgements -- References -- 8 Theoretical Approaches to CO2 Transformations -- Abstract -- 1 Carbon Dioxide Properties -- 2 CO2 Transformation as an Undeniable Necessity -- 3 CO2 Activation -- 3.1 Methodologies of CO2 Activation -- 4 Theoretical Insight of CO2 Transformation -- 4.1 The Theoretical Approach in CO2 Conversion to Value-Added Chemicals -- 4.1.1 Carbon Monoxide -- 4.1.2 Methane -- 4.1.3 Methanol -- 4.1.4 Formic Acid -- 4.1.5 Heterocycles -- Cyclic Carbonates -- Cyclic Carbamate -- Quiznazoline-2,4(1H,3H)-Dione -- 4.1.6 Summary and Outlook -- 5 Theoretical Designing of Novel Catalysts Based on DFT Studies -- 5.1 Theoretical Designing: Problems and Opportunities -- 6 Conclusion -- References -- 9 Carbon Dioxide Conversion Methods -- Abstract -- 1 Introduction -- 2 Molecular Structure of CO2. , 3 Thermo-Kinetics of CO2 Conversion -- 4 CO2 Conversion Methods and Products -- 4.1 Fischer-Tropsch Gas-to-Liquid (GTL) -- 4.2 Mineralization -- 4.3 Chemical Looping Dry Reforming -- 4.4 Enzymatic Conversion -- 4.5 Photocatalytic and Photo-Electrochemical Conversion -- 4.6 Thermo-Chemical Conversion -- 4.7 Hydrogenation -- 4.8 Reforming -- 5 Economic Assessment of CO2Alteration to Valuable Products -- 5.1 Syngas -- 5.2 Methanol -- 5.3 Formic Acid -- 5.4 Urea -- 5.5 Dimethyl Carbonate (DMC) -- 6 Conclusions and Future Perspective -- Acknowledgements -- References -- 10 Closing the Carbon Cycle -- Abstract -- 1 Introduction -- 2 Methods to Capture CO2 -- 3 CO2 Capture Technologies -- 4 CO2 Capture from the Air -- 5 Biomass and Waste-Based Chemicals -- 6 Advantages of Biomass-Based Chemicals -- 7 Replacement of Carbon-Based Energy Resources -- 8 Biomass Energy -- 9 Wind Energy -- 10 Solar Energy -- 11 Ocean Energy -- 12 Geothermal Energy -- 13 Hydrothermal Energy -- 14 Conclusions -- References -- 11 Carbon Dioxide Utilization to Energy and Fuel: Hydrothermal CO2 Conversion -- Abstract -- 1 Introduction -- 2 Hydrothermal CO2 Conversion -- 2.1 Metals and Catalysts as Reductant -- 2.2 Organic Wastes as Reductant -- 2.3 Inorganic Wastes as Reductant -- 2.4 Biomass as Reductant -- 3 Conclusion -- References -- 12 Ethylenediamine-Carbonic Anhydrase Complex for CO2 Sequestration -- 1 Introduction -- 2 An Overview of Carbonic Anhydrase (CA) -- 3 Mechanism of Action for Biocarbonate Formation -- 4 Historical Background of Carbonic Anhydrase -- 5 Sources of Carbonic Anhydrase -- 6 Carbonic Anhydrase in Microorganism -- 6.1 Micrococcus Lylae, Micrococcus Luteus, and Pseudomonas Fragi -- 6.2 Bacillus Subtilis and Citrobacter Freundii -- 6.3 Neisseria Gonorrhoeae -- 6.4 Helicobacter Pylori -- 7 Plant Carbonic Anhydrase -- 8 Overview of CO2. , 9 Sources of Carbon Dioxide (CO2) -- 10 Effect of Carbon Dioxide (CO2) -- 11 Carbon Dioxide Capturing -- 12 Carbon Dioxide (CO2) Sequestration -- 13 Carbon Dioxide (CO2) Sequestration by Carbonic Anhydrase -- 14 Separation System for CO2 Sequestration -- 15 Cryogenic Separation -- 16 Membrane Separation -- 17 Absorption -- 18 Adsorption -- 19 Bioreactors for CO2 Sequestration -- 20 Carbonic Anhydrase Immobilization -- 21 Ethylenediamine for Carbon Dioxide (CO2) Capturing -- 22 CO2 Capturing and Sequestration with Ethylenediamine-Carbonic Anhydrase Complex -- 23 CO2 Capturing and Sequestration Design and Optimization: Challenges and Future Prospects -- 24 Conclusion -- References -- 13 Green Pathway of CO2 Capture -- Abstract -- 1 Introduction -- 2 Molecular Structure of Carbon Dioxide -- 3 CO2 Capture System -- 3.1 Post-Combustion System -- 3.2 Pre-Combustion System -- 3.3 Oxy-Fuel Combustion System -- 4 Absorption Technology -- 4.1 Green Absorption with Ionic Liquids -- 4.1.1 Properties and Uses of Ionic Liquids -- 4.1.2 CO2 Solubility in PILs -- 4.1.3 CO2 Absorption in PILs with Carboxylate Anion -- 4.2 Reaction Mechanism Involved in CO2-Absorption -- 5 Adsorption Technology -- 5.1 Organic Adsorbents -- 5.1.1 Activated Charcoal -- 5.1.2 Biochar -- 5.1.3 Metal-Organic Frameworks (MOFs) -- 5.2 Other CO2 Adsorbents -- 5.2.1 Metal Oxide-Based Absorbents -- 5.2.2 Zeolites -- 5.3 Biological Processes of CO2Sequestration -- 5.3.1 Carbon Utilization by Forest and Agricultural Management -- 5.3.2 Ocean Fertilization -- 5.3.3 CO2 Capture by Microalgae -- 5.4 Electrochemical Ways for CO2 Capture -- 6 Conclusion -- References -- 14 Carbon Derivatives from CO2 -- Abstract -- 1 Introduction -- 2 Artificial Photoreduction -- 3 Electrochemical Reduction -- 4 Hydrogenation -- 5 Synthesis of Organic Carbonates -- 6 Reforming. , 7 Photocatalytic Reduction of CO2 with Water.
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  • 3
    Online Resource
    Online Resource
    Newark :John Wiley & Sons, Incorporated,
    Keywords: Nanostructured materials. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (491 pages)
    Edition: 1st ed.
    ISBN: 9781119651161
    Language: English
    Note: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Application of MOFs and Their Derived Materials in Sensors -- 1.1 Introduction -- 1.2 Application of MOFs and Their Derived Materials in Sensors -- 1.2.1 Optical Sensor -- 1.2.1.1 Colorimetric Sensor -- 1.2.1.2 Fluorescence Sensor -- 1.2.1.3 Chemiluminescent Sensor -- 1.2.2 Electrochemical Sensor -- 1.2.2.1 Amperometric Sensor -- 1.2.2.2 Impedimetric, Electrochemiluminescence, and Photoelectrochemical Sensor -- 1.2.3 Field-Effect Transistor Sensor -- 1.2.4 Mass-Sensitive Sensor -- 1.3 Conclusion -- Acknowledgments -- References -- Chapter 2 Applications of Metal-Organic Frameworks (MOFs) and Their Derivatives in Piezo/Ferroelectrics -- 2.1 Introduction -- 2.1.1 Brief Introduction to Piezo/Ferroelectricity -- 2.2 Fundamentals of Piezo/Ferroelectricity -- 2.3 Metal-Organic Frameworks for Piezo/ Ferroelectricity -- 2.4 Ferro/Piezoelectric Behavior of Various MOFs -- 2.5 Conclusion -- References -- Chapter 3 Fabrication and Functionalization Strategies of MOFs and Their Derived Materials "MOF Architecture" -- 3.1 Introduction -- 3.2 Fabrication and Functionalization of MOFs -- 3.2.1 Metal Nodes -- 3.2.2 Organic Linkers -- 3.2.3 Secondary Building Units -- 3.2.4 Synthesis Methods -- 3.2.4.1 Hydrothermal and Solvothermal Method -- 3.2.4.2 Microwave Synthesis -- 3.2.4.3 Electrochemical Method -- 3.2.4.4 Mechanochemical Synthesis -- 3.2.4.5 Sonochemical (Ultrasonic Assisted) Method -- 3.2.4.6 Diffusion Method -- 3.2.4.7 Template Method -- 3.2.5 Synthesis Strategies -- 3.3 MOF Derived Materials -- 3.4 Conclusion -- References -- Chapter 4 Application of MOFs and Their Derived Materials in Molecular Transport -- 4.1 Introduction -- 4.2 MOFs as Nanocarriers for Membrane Transport -- 4.2.1 MIL-89 -- 4.2.2 MIL-88A -- 4.2.3 MIL-100 -- 4.2.4 MIL-101 -- 4.2.5 MIL-53 -- 4.2.6 ZIF-8. , 4.2.7 Zn-TATAT -- 4.2.8 BioMOF-1 (Zn) -- 4.2.9 UiO (Zr) -- 4.3 Conclusion -- References -- Chapter 5 Role of MOFs as Electro/-Organic Catalysts -- 5.1 What Is MOFs -- 5.2 MOFs as Electrocatalyst in Sensing Applications -- 5.3 MOFs as Organic Catalysts in Organic Transformations -- 5.4 Conclusion and Future Prospects -- References -- Chapter 6 Application of MOFs and Their Derived Materials in Batteries -- 6.1 Introduction -- 6.2 Metal-Organic Frameworks -- 6.2.1 Classification and Properties of Metal-Organic Frameworks -- 6.2.2 Potential Applications of MOFs -- 6.2.3 Synthesis of MOFs -- 6.3 Polymer Electrolytes -- 6.3.1 Historical Perspectives and Classification of Polymer Electrolytes -- 6.3.2 MOF Based Polymer Electrolytes -- 6.4 Ionic Liquids -- 6.4.1 Properties of Ionic Liquids -- 6.4.2 Ionic Liquid Incorporated MOF -- 6.5 Ion Transport in Polymer Electrolytes -- 6.5.1 General Description of Ionic Conductivity -- 6.5.2 Models for Ionic Transport in Polymer Electrolytes -- 6.5.3 Impedance Spectroscopy and Ionic Conductivity Measurements -- 6.5.4 Concept of Mismatch and Relaxation -- 6.5.5 Scaling of ac Conductivity -- 6.6 IL Incorporated MOF Based Composite Polymer Electrolytes -- 6.7 Conclusion and Perspectives -- References -- Chapter 7 Fine Chemical Synthesis Using Metal-Organic Frameworks as Catalysts -- 7.1 Introduction -- 7.2 Oxidation Reaction -- 7.2.1 Epoxidation -- 7.2.2 Sulfoxidation -- 7.2.3 Aerobic Oxidation of Alcohols -- 7.3 1,3-Dipolar Cycloaddition Reaction -- 7.4 Transesterification Reaction -- 7.5 C-C Bond Formation Reactions -- 7.5.1 Heck Reactions -- 7.5.2 Sonogashira Coupling -- 7.5.3 Suzuki Coupling -- 7.6 Conclusion -- References -- Chapter 8 Application of Metal Organic Framework and Derived Material in Hydrogenation Catalysis -- 8.1 Introduction -- 8.1.1 The Active Centers in Parent MOF Materials. , 8.1.2 The Active Centers in MOF Catalyst -- 8.1.3 Metal Nodes -- 8.2 Hydrogenation Reactions -- 8.2.1 Hydrogenation of Alpha-Beta Unsaturated Aldehyde -- 8.2.2 Hydrogenation of Cinnamaldehyde -- 8.2.3 Hydrogenation of Nitroarene -- 8.2.4 Hydrogenation of Nitro Compounds -- 8.2.5 Hydrogenation of Benzene -- 8.2.6 Hydrogenation of Quinoline -- 8.2.7 Hydrogenation of Carbon Dioxide -- 8.2.8 Hydrogenation of Aromatics -- 8.2.9 Hydrogenation of Levulinic Acid -- 8.2.10 Hydrogenation of Alkenes and Alkynes -- 8.2.11 Hydrogenation of Phenol -- 8.3 Conclusion -- References -- Chapter 9 Application of MOFs and Their Derived Materials in Solid-Phase Extraction -- 9.1 Solid-Phase Extraction -- 9.1.1 Materials in SPE -- 9.2 MOFs and COFs in Miniaturized Solid-Phase Extraction (µSPE) -- 9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-µSPE) -- 9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-µSPE) -- 9.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 10 Anticancer and Antimicrobial MOFs and Their Derived Materials -- 10.1 Introduction -- 10.2 Anticancer MOFs -- 10.2.1 MOFs as Drug Carriers -- 10.2.2 MOFs in Phototherapy -- 10.3 Antibacterial MOFs -- 10.4 Antifungal MOFs -- References -- Chapter 11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Pe -- 11.1 Introduction -- 11.2 General Synthesis Routes -- 11.2.1 Hydrothermal Synthesis -- 11.2.2 Solvothermal Synthesis of MOFs -- 11.2.3 Room Temperature Synthesis -- 11.2.4 Microwave Assisted Synthesis -- 11.2.5 Mechanochemical Synthesis -- 11.2.6 Electrochemical Synthesis -- 11.3 Postsynthetic Modification in MOF -- 11.4 Computational Method -- 11.5 Results and Discussion. , 11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone) -- 11.6 Conclusion -- References -- Chapter 12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds -- 12.1 Introduction -- 12.2 VOCs and Their Potential Hazards -- 12.2.1 Other Sources of VOCs -- 12.3 VOCs Removal Techniques -- 12.4 Fabricated MOF for VOC Removal -- 12.4.1 MIL Series MOFs -- 12.4.2 Isoreticular MOFs -- 12.4.2.1 Adsorption Comparison of the Isoreticular MOFs -- 12.4.3 NENU Series MOFs -- 12.4.4 MOF-5, Eu-MOF, and MOF-199 -- 12.4.5 Amine-Impregnated MIL-100 -- 12.4.6 Biodegradable MOFs MIL-88 Series -- 12.4.7 Catalytic MOFs -- 12.4.8 Photo-Degradating MOFs -- 12.4.9 Some Other Studied MOFs -- 12.5 MOF Composites -- 12.5.1 MIL-101 Composite With Graphene Oxide -- 12.5.2 MIL-101 Composite With Graphite Oxide -- 12.6 Generalization Adsorptive Removal of VOCs by MOFs -- 12.7 Simple Modeling the Adsorption -- 12.7.1 Thermodynamic Parameters -- 12.7.2 Dynamic Sorption Methods -- 12.8 Factor Affecting VOCs Adsorption -- 12.8.1 Breathing Phenomena -- 12.8.2 Activation of MOFs -- 12.8.3 Applied Pressure -- 12.8.4 Relative Humidity -- 12.8.5 Breakthrough Conditions -- 12.8.6 Functional Group of MOFs -- 12.8.7 Concentration, Molecular Size, and Type of VOCs -- 12.9 Future Perspective -- References -- Chapter 13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis -- List of Abbreviations -- 13.1 Introduction -- 13.2 Perspective Synthesis of MOF and Their Derived Materials -- 13.3 MOF for Hydrogen Evolution Reaction -- 13.4 MOF for Oxygen Evolution Reaction -- 13.5 MOF for Oxygen Reduction Reaction -- 13.6 MOF for CO2 Electrochemical Reduction Reaction -- 13.6.1 Electrosynthesis of MOF for CO2 Reduction -- 13.6.2 Composite Electrodes as MOF for CO2 Reduction. , 13.6.3 Continuous Flow Reduction of CO2 -- 13.6.4 CO2 Electrochemical Reduction in Ionic Liquid -- 13.7 MOF for Electrocatalytic Sensing -- 13.8 Electrocatalytic Features of MOF -- 13.9 Conclusion -- Acknowledgment -- References -- Chapter 14 Applications of MOFs and Their Composite Materials in LightDriven Redox Reactions -- 14.1 Introduction -- 14.1.1 MOFs as Photocatalysts -- 14.1.2 Charge Transfer Mechanisms -- 14.1.3 Methods of Synthesis -- 14.2 Pristine MOFs and Their Application in Photocatalysis -- 14.2.1 Group 4 Metallic Clusters -- 14.2.2 Groups 8, 9, and 10 Metallic Clusters -- 14.2.3 Group 11 Metallic Clusters -- 14.2.4 Group 12 Metallic Clusters -- 14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis -- 14.3.1 Ag-MOF Composites -- 14.3.2 Au-MOF Composites -- 14.3.3 Cu-MOF Composites -- 14.3.4 Pd-MOF Composites -- 14.3.5 Pt-MOF Composites -- 14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis -- 14.4.1 TiO2-MOF Composites -- 14.4.2 Graphitic Carbon Nitride-MOF Composites -- 14.4.3 Bismuth-Based Semiconductors -- 14.4.4 Reduced Graphene Oxide-MOF Composites -- 14.4.5 Silver-Based Semiconductors -- 14.4.6 Other Semiconductors -- 14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis -- 14.5.1 Semiconductor-Semiconductor-MOF Composites -- 14.5.2 Semiconductor-Metal-MOF Composites -- 14.6 Conclusions -- References -- Index -- Also of Interest -- Check out these other forthcoming and published titles from Scrivener Publishing -- EULA.
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    Online Resource
    Online Resource
    Newark :John Wiley & Sons, Incorporated,
    Keywords: Adhesives-Environmental aspects. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (300 pages)
    Edition: 1st ed.
    ISBN: 9781119655084
    Language: English
    Note: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Anti-Adhesive Coatings: A Technique for Prevention of Bacterial Surface Fouling -- 1.1 Bacterial Surface Fouling (Biofouling) -- 1.2 Negative Effects of Biofouling by Bacteria on Practical Applications -- 1.3 Anti-Adhesive Coatings for Preventing Bacterial Surface Fouling -- 1.3.1 Hydrophilic Polymers -- 1.3.2 Zwitterionic Polymers -- 1.3.3 Super-Hydrophobic Polymers -- 1.3.4 Slippery Liquid Infused Porous Surfaces (SLIPS) -- 1.3.5 Protein and Glycoprotein-Based Coatings -- 1.4 Bifunctional Coatings With Anti-Adhesive and Antibacterial Properties -- 1.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 2 Lignin-Based Adhesives -- 2.1 Introduction -- 2.2 Native Lignin and Source of Technical Lignin -- 2.2.1 Native Lignin -- 2.2.2 Technical Lignins -- 2.3 Limitations of Technical Lignins -- 2.3.1 Heterogeneity of Technical Lignins -- 2.3.2 Reactivity of Technical Lignins -- 2.4 Lignin Pre-Treatment/Modification for Adhesive Application -- 2.4.1 Physical Pre-Treatment -- 2.4.2 Chemical Modification -- 2.5 Challenges and Prospects -- 2.6 Conclusions -- References -- Chapter 3 Green Adhesive for Industrial Applications -- 3.1 Introduction -- 3.2 Advanced Green Adhesives Categories- Industrial Applications -- 3.2.1 Keta Spire Poly Etherether Ketone Powder Coating -- 3.2.2 Bio-Inspired Adhesive in Robotics Field Application -- 3.2.3 Bio-Inspired Synthetic Adhesive in Space Application -- 3.2.3.1 Micro Structured Dry Adhesive Fabrication for Space Application -- 3.2.4 Natural Polymer Adhesive for Wood Panel Industry -- 3.2.5 Tannin Based Bio-Adhesive for Leather Tanning Industry -- 3.2.6 Conductive Adhesives in Microelectronics Industry -- 3.2.7 Bio-Resin Adhesive in Dental Industry -- 3.2.8 Green Adhesive in Fiberboard Industry -- 3.3 Conclusions and Future Scope. , References -- Chapter 4 Green Adhesives for Biomedical Applications -- 4.1 Introduction -- 4.2 Main Raw Materials of Green Adhesives: Structure, Composition, and Properties -- 4.2.1 Chitosan -- 4.2.2 Alginate -- 4.2.3 Lignin -- 4.2.4 Lactic Acid PLA -- 4.3 Properties Characterization of Green Adhesives for Biomedical Applications -- 4.3.1 Diffraction X-Rays (DRX) -- 4.3.2 Atomic Force Microscopy (AFM) -- 4.3.3 Scanning Electron Microscope (SEM Images) -- 4.3.4 Wettability or Contact Angle (CA) -- 4.3.5 Fourier Transform Infrared Spectroscopy (FTIR) -- 4.3.6 Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES) -- 4.3.7 Thermal Analysis (TG/DTG/DTA and DSC Curves) -- 4.3.8 Surface Area and Porosimetry Analyzer (ASAP) -- 4.3.9 Mechanical Properties of Green Adhesives -- 4.4 Biomedical Applications of Natural Polymers -- 4.4.1 Alginate -- 4.4.1.1 Biomedical Applications of Alginate -- 4.4.2 Chitosan -- 4.4.2.1 Biomedical Applications of Chitosan -- 4.4.3 Lignin -- 4.4.3.1 Biomedical Applications of Lignin -- 4.4.4 Polylactide (PLA) -- 4.4.4.1 Biomedical Applications of PLA -- 4.5 Final Considerations -- Acknowledgements -- References -- Chapter 5 Waterborne Adhesives -- 5.1 Introduction -- 5.1.1 Motivation for the Use of Waterborne Adhesives -- 5.1.1.1 Sustainability and Environment Regulations -- 5.1.1.2 Circular Economy -- 5.1.1.3 Avoid Harmful Emissions -- 5.1.1.4 Development of Novel and Sustainable End Products -- 5.1.2 Environmental Effects and Mankind Toxicity Analysis -- 5.2 Performance of Waterborne Adhesives: An Overview -- 5.2.1 Waterborne Polyurethane (WBPU) Adhesives -- 5.2.1.1 Chemical Structure of Waterborne PU -- 5.2.1.2 Performances of WBPU Adhesives -- 5.2.2 Waterborne Epoxy Adhesive -- 5.3 Conclusions -- References -- Chapter 6 Using Polyfurfuryl Alcohol as Thermoset Adhesive/Sealant -- 6.1 Introduction. , 6.2 Furfuryl Alcohol as Adhesives -- 6.3 Polyfurfuryl Alcohol as Sealants -- 6.3.1 Effect of Different Parameters on the Curing of PFA-Based Sealants -- 6.4 Applications -- 6.5 Conclusions -- Acknowledgement -- References -- Chapter 7 Bioadhesives -- 7.1 Introduction -- 7.2 History of Bioadhesives -- 7.3 Classification of Bioadhesives -- 7.4 Mechanism of Bioadhesion -- 7.4.1 Mechanical Interlocking -- 7.4.2 Chain Entanglement -- 7.4.3 Intermolecular Bonding -- 7.4.4 Electrostatic Bonding -- 7.5 Testing of Bioadhesives -- 7.5.1 In Vitro Methods -- 7.5.1.1 Shear Stress Measurements -- 7.5.1.2 Peel Strength Evaluation -- 7.5.1.3 Flow Through Experiment and Plate Method -- 7.5.2 Ex Vitro Methods -- 7.5.2.1 Adhesion Weight Method -- 7.5.2.2 Fluorescent Probe Methods -- 7.5.2.3 Falling Liquid Film Method -- 7.6 Application of Bioadhesives -- 7.6.1 Bioadhesives as Drug Delivery Systems -- 7.6.2 Bioadhesives as Fibrin Sealants -- 7.6.3 Bioadhesives as Protein-Based Adhesives -- 7.6.4 Bioadhesives in Tissue Engineering -- 7.7 Conclusion -- References -- Chapter 8 Polysaccharide-Based Adhesives -- 8.1 Introduction -- 8.2 Cellulose-Derived Adhesive -- 8.2.1 Esterification -- 8.2.1.1 Cellulose Nitrate -- 8.2.1.2 Cellulose Acetate -- 8.2.1.3 Cellulose Acetate Butyrate -- 8.2.2 Etherification -- 8.2.2.1 Methyl Cellulose -- 8.2.2.2 Ethyl Cellulose -- 8.2.2.3 Carboxymethyl Cellulose -- 8.3 Starch-Derived Adhesives -- 8.3.1 Alkali Treatment -- 8.3.2 Acid Treatment -- 8.3.3 Heating -- 8.3.4 Oxidation -- 8.4 Natural Gums Derived-Adhesives -- 8.5 Fermentation-Based Adhesives -- 8.6 Enzyme Cross-Linked-Based Adhesives -- 8.7 Micro-Biopolysaccharide-Based Adhesives -- 8.8 Mechanism of Adhesion -- 8.9 Tests for Adhesion Strength -- 8.10 Applications -- 8.10.1 Biomedical Applications -- 8.10.2 Food Stuffs Applications -- 8.10.3 Pharmaceutical Applications. , 8.10.4 Agricultural Applications -- 8.10.5 Cigarette Manufacturing -- 8.10.6 Skin Cleansing Applications -- 8.11 Conclusion -- References -- Chapter 9 Wound Healing Adhesives -- 9.1 Introduction -- 9.2 Wound -- 9.2.1 Types of Wounds -- 9.2.1.1 Acute Wounds -- 9.2.1.2 Chronic Wounds -- 9.3 Structure and Function of the Skin -- 9.4 Mechanism of Wound Healing -- 9.5 Wound Closing Techniques -- 9.6 Wound Healing Adhesives -- 9.7 Types of Wound Healing Adhesives Based Upon Site of Application -- 9.7.1 External Use Wound Adhesives -- 9.7.1.1 Steps for Applying External Wound Healing Adhesives on Skin [30] -- 9.7.2 Internal Use Wound Adhesives -- 9.8 Types of Wound Healing Adhesives Based Upon Chemistry -- 9.8.1 Natural Wound Healing Adhesives -- 9.8.1.1 Fibrin Sealants/Fibrin-Based Tissue Adhesives -- 9.8.1.2 Albumin-Based Adhesives -- 9.8.1.3 Collagen and Gelatin-Based Wound Healing Adhesives -- 9.8.1.4 Starch -- 9.8.1.5 Chitosan -- 9.8.1.6 Dextran -- 9.8.2 Synthetic Wound Healing Adhesives -- 9.8.2.1 Cyanoacrylate -- 9.8.2.2 Poly Ethylene Glycol-Based Wound Adhesives (PEG) -- 9.8.2.3 Hydrogels -- 9.8.2.4 Polyurethane -- 9.9 Summary -- References -- Chapter 10 Green-Wood Flooring Adhesives -- 10.1 Introduction -- 10.2 Wood Flooring -- 10.2.1 Softwood Flooring -- 10.2.2 Hardwood Flooring -- 10.2.3 Engineered Wood Flooring -- 10.2.4 Laminate Flooring -- 10.2.5 Vinyl Flooring -- 10.2.6 Agricultural Residue Wood Flooring Panels -- 10.3 Recent Advances About Green Wood-Flooring Adhesives -- 10.3.1 Xylan -- 10.3.2 Modified Cassava Starch Bioadhesives -- 10.3.3 High-Efficiency Bioadhesive -- 10.3.4 Bioadhesive Made From Soy Protein and Polysaccharide -- 10.3.5 Green Cross-Linked Soy Protein Wood Flooring Adhesive -- 10.3.6 "Green" Bio-Thermoset Resins Derived From Soy Protein Isolate and Condensed Tannins. , 10.3.7 Development of Green Adhesives Using Tannins and Lignin for Fiberboard Manufacturing -- 10.3.8 Cottonseed Protein as Wood Adhesives -- 10.3.9 Chitosan as an Adhesive -- 10.3.10 PE-cg-MAH Green Wood Flooring Adhesive -- References -- Chapter 11 Synthetic Binders for Polymer Division -- List of Abbreviations -- 11.1 Introduction -- 11.2 Classification of Adhesives Based on Its Chemical Properties -- 11.2.1 Thermoset Adhesives -- 11.2.2 Thermoplastic Adhesives -- 11.2.3 Adhesive Blends -- 11.3 Adhesives Characteristics -- 11.4 Adhesives Classification Based on Its Function -- 11.4.1 Permanent Adhesives -- 11.4.2 Removable Adhesives -- 11.4.3 Repositionable Adhesives -- 11.4.4 Blended Adhesives -- 11.4.5 Anaerobic Adhesives -- 11.4.6 Aromatic Polymer Adhesives -- 11.4.7 Asphalt -- 11.4.8 Adhesives Based on Butyl Rubber -- 11.4.9 Cellulose Ester Adhesives -- 11.4.10 Adhesives Based on Cellulose Ether -- 11.4.11 Conductive Adhesives -- 11.4.12 Electrically Conductive Adhesive Materials -- 11.4.13 Thermally Conductive Adhesives -- 11.5 Resin -- 11.5.1 Unsaturated Polyester Resin -- 11.5.2 Monomers -- 11.5.2.1 Unsaturated Polyester -- 11.5.2.2 Alcohol Constituents -- 11.5.2.3 Constituents Like Anhydride and Acid -- 11.5.3 Vinyl Monomers of Unsaturated Polyester Resins -- 11.5.4 Styrenes -- 11.5.5 Acrylates and Methacrylates -- 11.5.6 Vinyl Ethers -- 11.5.7 Fillers -- 11.6 Polyurethanes -- 11.6.1 Monomers -- 11.6.1.1 Diisocyanates -- 11.6.1.2 Phosgene Route -- 11.6.1.3 Phosgene-Free Route -- 11.6.1.4 Polyols -- 11.6.1.5 Vinyl Functionalized Polyols -- 11.6.1.6 Polyols Based on Modified Polyurea -- 11.6.1.7 Polyols Based on Polyester -- 11.6.1.8 Acid and Alcohols-Based Polyesters -- 11.6.2 Rectorite Nanocomposites -- 11.6.3 Zeolite -- 11.7 Epoxy Resins -- 11.7.1 Monomers -- 11.7.1.1 Epoxides -- 11.7.1.2 Hyper Branched Polymers. , 11.7.2 Epoxide Resins Based on Liquid Crystalline Structure.
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    Online Resource
    Online Resource
    Millersville, PA :Materials Research Forum LLC,
    Keywords: Electronic books.
    Description / Table of Contents: The book presents new cutting-edge research findings in this field. Subjects covered include fabrication and characteristics of various electrode materials, cell design and strategies for enhancing the properties of PEC electrode materials.
    Type of Medium: Online Resource
    Pages: 1 online resource (224 pages)
    Edition: 1st ed.
    ISBN: 9781644900734
    Series Statement: Materials Research Foundations Series ; v.71
    Language: English
    Note: Intro -- front-matter -- Table of Contents -- Preface -- 1 -- Transition Metal Chalcogenides for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Typical structures of transition metal chalcogenides -- 3. Binary chalcogenides applied to photoelectrochemical water splitting -- 4. Transition metal-based ternary and multinary chalcogenides for photoelectrochemical water splitting -- 4.1 P-type copper-based chalcogenides -- 4.2. Silver-based chalcogenides for water splitting -- Conclusions -- References -- 2 -- Selection of Materials and Cell Design for Photoelectrochemical Decomposition of Water -- 1. Introduction -- 2. Principle and theory of water decomposition -- 3. Challenges in designing of a photoelectrochemical cell -- 4. Design configurations of PEC -- 4.1 Type 1 photo anodes -- 4.2 Type II heterojunction photomaterials -- 4.3 Type III wired type PEC tandem cells -- 4.4 Type IV wireless type PEC -- 4.5 Type V PV−EC systems -- Conclusions -- References -- 3 -- Interfacial Layer/Overlayer Effects in Photoelectrochemical Water Splitting -- 1. Introduction -- 2. PEC cell photoelectrode: Required characteristics and recent trends -- 3. Interface layering/over-layering: An effective strategy -- 4. Interface layering/over-layering of metal oxide semiconductors -- 4.1 Interface layering with BiVO4 -- 4.2 Interface layering with CuO/Cu2O -- 4.3 Interface layering with hematite (α-Fe2O3) -- 4.4 Interface layering with WO3 -- 4.5 Interface layering with TiO2 -- 5. Interface layering with carbon materials -- 6. Interface layering with low-cost non-metallic semiconductors -- 7. Interface layering/integration with metal nanoparticles -- Conclusion and future directions -- Acknowledgements -- References -- 4 -- Narrow Bandgap Semiconductors for Photoelectrochemical Water Splitting -- 1. Introduction. , 2. Narrow band gap materials as a strategy to improve photoresponse of the material -- 2.1 Bismuth sulfide (Bi2S3) -- 2.2 CuO -- 2.3 Fe2O3 -- 2.4 BiOI -- Spray Pyrolysis -- BiOI/BiOBr -- BiOI/TiO2 -- Conclusion -- References -- 5 -- Ti-based Materials for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Basic principle of PEC water splitting -- 3. Material selection for PEC water splitting -- 4. TiO2 photocatalyst for PEC water splitting -- 5. Tuning the photocatalytic of TiO2 into the visible light region -- Conclusion -- Acknowledgements -- References -- 6 -- BiVO4 Photoanodes for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Crystal and electronic band structure of BiVO4 -- 3. The band gap of monoclinic BiVO4 -- 3.1 BiVO4 photoanode band alignment at a liquid interface -- 4. Influence of crystal facet -- 5. Carrier dynamics in BiVO4 -- 6. Intrinsic defects/Oxygen vacancies in BiVO4 -- 7. Polarons in BiVO4 -- 8. Doping BiVO4 -- 8.1 W doping into BiVO4 -- 8.2 Mo doping into BiVO4 -- 8.3 Other dopants in BiVO4 -- 8.4 Lanthanide ion doping into BiVO4 -- 8.5 Codoping in BiVO4 (multiple ion doping) -- 9. The side of illumination on BiVO4 photoanode -- 10. Photo-charged BiVO4 -- 11. Hole blocking layer for BiVO4 -- 12. Catalyst coatings on BiVO4 photoanode -- 13. Plasmon-induced resonant energy transfer -- Conclusions and future perspective -- References -- 7 -- Noble Materials for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Fundamental properties of noble metals for photocatalytic activity -- 2.1 Fundamentals of the Localized Surface Plasmon Resonance (LSPR) -- 2.2 Schottky junction -- 3. Photoelectrodes materials -- 3.1 Titania (TiO2) -- 3.2 Haematite (Fe2O3) -- 3.3 Zinc oxide (ZnO) -- 4. Fundamental role of noble materials in PEC water splitting -- 4.1 Platinum (Pt) -- 4.2 Gold (Au) -- 4.3 Silver (Ag). , 4.4 Palladium (Pd) -- 4.5 Copper (Cu) -- 5. Noble bimetallic nanocomposites for PEC water splitting -- 5.1 Au-Pt bimetallic nanocomposites -- 5.2 Au-Pd bimetallic nanocomposites -- 5.3 Au-Ag bimetallic nanocomposites -- 5.4 Ag-Cu bimetallic nanocomposites -- 6. A brief note on bimetallic non-noble NPs for photoelectrochemical (PEC) water splitting -- Conclusion -- References -- back-matter -- Keyword Index -- About the Editors.
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  • 6
    Online Resource
    Online Resource
    Newark :John Wiley & Sons, Incorporated,
    Keywords: Layer structure (Solids). ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (403 pages)
    Edition: 1st ed.
    ISBN: 9781119655206
    DDC: 620.11
    Language: English
    Note: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 2D Metal-Organic Frameworks -- 1.1 Introduction -- 1.2 Synthesis Approaches -- 1.2.1 Selection of Synthetic Raw Materials -- 1.2.2 Solvent Volatility Method -- 1.2.3 Diffusion Method -- 1.2.3.1 Gas Phase Diffusion -- 1.2.3.2 Liquid Phase Diffusion -- 1.2.4 Sol-Gel Method -- 1.2.5 Hydrothermal/Solvothermal Synthesis Method -- 1.2.6 Stripping Method -- 1.2.7 Microwave Synthesis Method -- 1.2.8 Self-Assembly -- 1.2.9 Special Interface Synthesis Method -- 1.2.10 Surfactant-Assisted Synthesis Method -- 1.2.11 Ultrasonic Synthesis -- 1.3 Structures, Properties, and Applications -- 1.3.1 Structure and Properties of MOFs -- 1.3.2 Application in Biomedicine -- 1.3.3 Application in Gas Storage -- 1.3.4 Application in Sensors -- 1.3.5 Application in Chemical Separation -- 1.3.6 Application in Catalysis -- 1.3.7 Application in Gas Adsorption -- 1.4 Summary and Outlook -- Acknowledgements -- References -- Chapter 2 2D Black Phosphorus -- 2.1 Introduction -- 2.2 The Research on Black Phosphorus -- 2.2.1 The Structure and Properties -- 2.2.1.1 The Structure of Black Phosphorus -- 2.2.1.2 The Properties of Black Phosphorus -- 2.2.2 Preparation Methods -- 2.2.2.1 Mechanical Exfoliation -- 2.2.2.2 Liquid-Phase Exfoliation -- 2.2.3 Antioxidant -- 2.2.3.1 Degradation Mechanism -- 2.2.3.2 Adding Protective Layer -- 2.2.3.3 Chemical Modification -- 2.2.3.4 Doping -- 2.3 Applications of Black Phosphorus -- 2.3.1 Electronic and Optoelectronic -- 2.3.1.1 Field-Effect Transistors -- 2.3.1.2 Photodetector -- 2.3.2 Energy Storage and Conversion -- 2.3.2.1 Catalysis -- 2.3.2.2 Batteries -- 2.3.2.3 Supercapacitor -- 2.3.3 Biomedical -- 2.4 Conclusion and Outlook -- Acknowledgements -- References -- Chapter 3 2D Metal Carbides -- 3.1 Introduction -- 3.2 Synthesis Approaches -- 3.2.1 Ti3C2 Synthesis. , 3.2.2 V2C Synthesis -- 3.2.3 Ti2C Synthesis -- 3.2.4 Mo2C Synthesis -- 3.3 Structures, Properties, and Applications -- 3.3.1 Structures and Properties of 2D Metal Carbides -- 3.3.1.1 Structures and Properties of Ti3C2 -- 3.3.1.2 Structural Properties of Ti2C -- 3.3.1.3 Structural Properties of Mo2C -- 3.3.1.4 Structural Properties of V2C -- 3.3.2 Carbide Materials in Energy Storage Applications -- 3.3.2.1 Ti3C2 -- 3.3.2.2 Ti2C -- 3.3.2.3 V2C -- 3.3.2.4 Mo2C -- 3.3.3 Metal Carbide Materials in Catalysis Applications -- 3.3.3.1 Ti3C2 -- 3.3.3.2 V2C -- 3.3.3.3 Mo2C -- 3.3.4 Metal Carbide Materials in Environmental Management Applications -- 3.3.4.1 Ti3C2 in Environmental Management Applications -- 3.3.4.2 Ti2C in Environmental Management Applications -- 3.3.4.3 V2C in Environmental Management Applications -- 3.3.4.4 Mo2C in Environmental Management Applications -- 3.3.5 Carbide Materials in Biomedicine Applications -- 3.3.5.1 Ti3C2 in Biomedicine Applications -- 3.3.5.2 Ti2C in Biomedicine Applications -- 3.3.5.3 V2C in Biomedicine Applications -- 3.3.5.4 Mo2C in Biomedicine Applications -- 3.3.6 Carbide Materials in Gas Sensing Applications -- 3.3.6.1 Ti3C2 in Gas Sensing Applications -- 3.3.6.2 Ti2C in Gas Sensing Applications -- 3.3.6.3 V2C in Gas Sensing Applications -- 3.3.6.4 Mo2C in Gas Sensing Applications -- 3.4 Summary and Outlook -- Acknowledgements -- References -- Chapter 4 2D Carbon Materials as Photocatalysts -- 4.1 Introduction -- 4.2 Carbon Nanostructured-Based Materials -- 4.2.1 Forms of Carbon -- 4.2.2 Synthesis of Carbon Nanostructured-Based Materials -- 4.3 Photo-Degradation of Organic Pollutants -- 4.3.1 Graphene, Graphene Oxide, Graphene Nitride (g-C3N4) -- 4.3.1.1 Graphene-Based Materials -- 4.3.1.2 Graphene Nitride (g-C3N4) -- 4.3.2 Carbon Dots (CDs) -- 4.3.3 Carbon Spheres (CSs). , 4.4 Carbon-Based Materials for Hydrogen Production -- 4.5 Carbon-Based Materials for CO2 Reduction -- References -- Chapter 5 Sensitivity Analysis of Surface Plasmon Resonance Biosensor Based on Heterostructure of 2D BlueP/MoS2 and MXene -- 5.1 Introduction -- 5.2 Proposed SPR Sensor, Design Considerations, and Modeling -- 5.2.1 SPR Sensor and Its Sensing Principle -- 5.2.2 Design Consideration -- 5.2.2.1 Layer 1: Prism for Light Coupling -- 5.2.2.2 Layer 2: Metal Layer -- 5.2.2.3 Layer 3: BlueP/MoS2 Layer -- 5.2.2.4 Layer 4: MXene (Ti3C2Tx) Layer as BRE for Biosensing -- 5.2.2.5 Layer 5: Sensing Medium (RI-1.33-1.335) -- 5.2.3 Proposed Sensor Modeling -- 5.3 Results Discussion -- 5.3.1 Role of Monolayer BlueP/MoS2 and MXene (Ti3C2Tx) and Its Comparison With Conventional SPR -- 5.3.2 Influence of Varying Heterostructure Layers for Proposed Design -- 5.3.3 Effect of Changing Prism Material and Metal on Performance of Proposed Design -- 5.4 Conclusion -- References -- Chapter 6 2D Perovskite Materials and Their Device Applications -- 6.1 Introduction -- 6.2 Structure -- 6.2.1 Crystal Structure -- 6.2.2 Electronic Structure of 2D Perovskites -- 6.2.3 Structure of Photovoltaic Cell -- 6.3 Discussion and Applications -- 6.4 Conclusion -- References -- Chapter 7 Introduction and Significant Parameters for Layered Materials -- 7.1 Graphene -- 7.2 Phosphorene -- orthorhombic rhombohedral Simple cubic -- semiconductor semimetal metal -- 7.3 Silicene -- 7.4 ZnO -- 7.5 Transition Metal Dichalcogenides (TMDCs) -- 7.6 Germanene and Stanene -- 7.7 Heterostructures -- References -- Chapter 8 Increment in Photocatalytic Activity of g-C3N4 Coupled Sulphides and Oxides for Environmental Remediation -- 8.1 Introduction -- 8.2 GCN Coupled Metal Sulphide Heterojunctions for Environment Remediation -- 8.2.1 GCN and MoS2-Based Photocatalysts. , 8.2.2 GCN and CdS-Based Heterojunctions -- 8.2.3 Some Other GCN Coupled Metal Sulphide Photocatalysts -- 8.3 GCN Coupled Metal Oxide Heterojunctions for Environment Remediation -- 8.3.1 GCN and MoO3-Based Heterojunctions -- 8.3.2 GCN and Fe2O3-Based Heterojunctions -- 8.3.3 Some Other GCN Coupled Metal Oxide Photocatalysts -- 8.4 Conclusions and Outlook -- References -- Chapter 9 2D Zeolites -- 9.1 Introduction -- 9.1.1 What is 2D Zeolite? -- 9.1.2 Advancement in Zeolites to 2D Zeolite -- 9.2 Synthetic Method -- 9.2.1 Bottom-Up Method -- 9.2.2 Top-Down Method -- 9.2.3 Support-Assisted Method -- 9.2.4 Post-Synthesis Modification of 2D Zeolites -- 9.3 Properties -- 9.4 Applications -- 9.4.1 Petro-Chemistry -- 9.4.2 Biomass Conversion -- 9.4.2.1 Pyrolysis of Solid Biomass -- 9.4.2.2 Condensation Reactions -- 9.4.2.3 Isomerization -- 9.4.2.4 Dehydration Reactions -- 9.4.3 Oxidation Reactions -- 9.4.4 Fine Chemical Synthesis -- 9.4.5 Organometallics -- 9.5 Conclusion -- References -- Chapter 10 2D Hollow Nanomaterials -- 10.1 Introduction -- 10.2 Structural Aspects of HNMs -- 10.3 Synthetic Approaches -- 10.3.1 Template-Based Strategies -- 10.3.1.1 Hard Templating -- 10.3.1.2 Soft Templating -- 10.3.2 Self-Templating Strategies -- 10.3.2.1 Surface Protected Etching -- 10.3.2.2 Ostwald Ripening -- 10.3.2.3 Kirkendall Effect -- 10.3.2.4 Galvanic Replacement -- 10.4 Medical Applications of HNMs -- 10.4.1 Imaging and Diagnosis Applications -- 10.4.2 Applications of Nanotube Arrays -- 10.4.2.1 Pharmacy and Medicine -- 10.4.2.2 Cancer Therapy -- 10.4.2.3 Immuno and Hyperthermia Therapy -- 10.4.2.4 Infection Therapy and Gene Therapy -- 10.4.3 Hollow Nanomaterials in Diagnostics and Therapeutics -- 10.4.4 Applications in Regenerative Medicine -- 10.4.5 Anti-Neurodegenerative Applications -- 10.4.6 Photothermal Therapy -- 10.4.7 Biosensors. , 10.5 Non-Medical Applications of HNMs -- 10.5.1 Catalytic Micro or Nanoreactors -- 10.5.2 Energy Storage -- 10.5.2.1 Lithium Ion Battery -- 10.5.2.2 Supercapacitor -- 10.5.3 Nanosensors -- 10.5.4 Wastewater Treatment -- 10.6 Toxicity of 2D HNMs -- 10.7 Future Challenges -- 10.8 Conclusion -- Acknowledgement -- References -- Chapter 11 2D Layered Double Hydroxides -- 11.1 Introduction -- 11.2 Structural Aspects -- 11.3 Synthesis of LDHs -- 11.3.1 Co-Precipitation Method -- 11.3.2 Urea Hydrolysis -- 11.3.3 Ion-Exchange Method -- 11.3.4 Reconstruction Method -- 11.3.5 Hydrothermal Method -- 11.3.6 Sol-Gel Method -- 11.4 Nonmedical Applications of LDH -- 11.4.1 Adsorbent -- 11.4.2 Catalyst -- 11.4.3 Sensors -- 11.4.4 Electrode -- 11.4.5 Polymer Additive -- 11.4.6 Anion Scavenger -- 11.4.7 Flame Retardant -- 11.5 Biomedical Applications -- 11.5.1 Biosensors -- 11.5.2 Scaffolds -- 11.5.3 Anti-Microbial Agents -- 11.5.4 Drug Delivery -- 11.5.5 Imaging -- 11.5.6 Protein Purification -- 11.5.7 Gene Delivery -- 11.6 Toxicity -- 11.7 Conclusion -- Acknowledgement -- References -- Chapter 12 Experimental Techniques for Layered Materials -- 12.1 Introduction -- 12.2 Methods for Synthesis of Graphene Layered Materials -- 12.3 Selection of a Suitable Metallic Substrate -- 12.4 Graphene Synthesis by HFTCVD -- 12.5 Graphene Transfer -- 12.6 Characterization Techniques -- 12.6.1 X-Ray Diffraction Technique -- d D k -- 12.6.2 Field Emission Scanning Electron Microscopy (FESEM) -- 12.6.3 Transmission Electron Microscopy (TEM) -- 12.6.4 Fourier Transform Infrared Radiation (FTIR) -- 12.6.5 UV-Visible Spectroscopy -- 12.6.6 Raman Spectroscopy -- 12.6.7 Low Energy Electron Microscopy (LEEM) -- 12.7 Potential Applications of Graphene and Derived Materials -- 12.8 Conclusion -- Acknowledgement -- References -- Chapter 13 Two-Dimensional Hexagonal Boron Nitride and Borophenes. , 13.1 Two-Dimensional Hexagonal Boron Nitride (2D h-BN): An Introduction.
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  • 7
    Online Resource
    Online Resource
    Milton :Taylor & Francis Group,
    Keywords: Electronic books.
    Description / Table of Contents: Surveys recent advances in conducting polymers and their composites. Chapters address synthetic approaches, and applications in all types of electrochemical energy storage devices and next-generation devices. Evaluates the execution of these materials as electrodes in electrochemical power sources.
    Type of Medium: Online Resource
    Pages: 1 online resource (353 pages)
    Edition: 1st ed.
    ISBN: 9780429510885
    Language: English
    Note: Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- Contributors -- Editors -- Chapter 1. Polythiophene-Based Battery Applications -- 1.1 Introduction -- 1.2 Synthesis -- 1.2.1 Electrochemical Polymerization -- 1.2.2 Chemical Synthesis -- 1.3 Battery Applications of PTs -- 1.3.1 PTs as Cathodic Materials -- 1.3.1.1 PTs as Active Materials -- 1.3.1.2 PTs as Binder -- 1.3.1.3 PTs as Conduction-Promoting Agents -- 1.3.2 PTs as Air Cathode -- 1.3.2.1 Li-Air Batteries -- 1.3.2.2 Aluminum-Air Battery -- 1.3.2.3 Zinc-Air Battery -- 1.3.3 PTs as Anodic Materials -- 1.3.3.1 PTs as Active Materials for Anode -- 1.3.3.2 PTs as Binders -- 1.3.3.3 PTs as Conduction Promoting Agents (CPAs) -- 1.3.4 PTs as Battery Separators -- 1.3.4.1 Li-Ion Batteries -- 1.3.4.2 Li-S Batteries -- 1.3.4.3 Li-O2 Batteries -- 1.3.5 PTs as Electrolytes -- 1.3.6 PTs as Coin-cell Cases -- 1.3.7 PTs as Li-O2 Catalyst -- 1.4 Conclusion -- References -- Chapter 2. Synthetic Strategies and Significant Issues for Pristine Conducting Polymers -- 2.1 Introduction -- 2.2 Conduction Mechanism -- 2.3 Synthesis of Conducting Polymers -- 2.3.1 Synthesis through Polymerization -- 2.3.1.1 Chain-Growth Polymerization -- 2.3.1.2 Step-Growth Polymerization -- 2.3.2 Synthesis by Doping with Compatible Dopants -- 2.3.2.1 Types of Doping Agents -- 2.3.2.2 Doping Techniques -- 2.3.2.3 Mechanism of Doping -- 2.3.2.4 Influence of Doping on Conductivity -- 2.3.3 Electrochemical Polymerization -- 2.3.4 Photochemical Synthesis -- 2.4 Various Issues for Synthesis -- 2.4.1 Vapor-Phase Polymerization -- 2.4.2 Hybrid Conducting Polymers -- 2.4.3 Nanostructure Conducting Polymers -- 2.4.4 Narrow Bandgap Conducting Polymers -- 2.4.5 Synthesis in Supercritical CO2 -- 2.4.6 Biodegradability and Biocompatibility of Conducting Polymers -- 2.5 Applications. , 2.6 Future Scope for Applications -- 2.7 Conclusions -- Abbreviations -- References -- Chapter 3. Conducting Polymer Derived Materials for Batteries -- 3.1 Introduction -- 3.2 Theory -- 3.3 Discussion on Conducting Polymer-Derived Materials -- 3.3.1 PEDOT Derivatives -- 3.3.1.1 Structural Properties -- 3.3.1.2 Electrochemical Studies of PEDOT and Its Derivatives -- 3.3.1.3 Magnetic Properties -- 3.3.2 PPy for the Energy-Storage Devices -- 3.3.2.1 Structural Property of PPy -- 3.3.2.2 Electrochemical Properties of Polypyrrol -- 3.3.2.3 Magnetic Properties -- 3.3.3 PANI for Battery Application -- 3.3.3.1 Structural Properties -- 3.3.3.2 Electrochemical Properties of PANI for Battery Electrode -- 3.3.3.3 Magnetic Properties of PANI -- 3.4 Summary and Conclusions -- References -- Chapter 4. An Overview on Conducting Polymer-Based Materials for Battery Application -- 4.1 Introduction -- 4.2 Principle of Conducting Polymer Battery -- 4.3 Assortment of Conducting Polymer Electrodes for Battery Application -- 4.4 Mechanism of Conducting Polymers in Rechargeable Batteries -- 4.5 Organic Conducting Polymer for Lithium-ion Battery -- 4.5.1 Types of Organic Conducting Polymers -- 4.6 Synthesis of Conducting Polymer -- 4.6.1 Hard-template Method -- 4.6.2 Soft-template Method -- 4.6.3 Template-free Technique -- 4.6.4 Self-Assembly or Interfacial -- 4.6.5 Electrospinning -- 4.7 Characterization -- 4.7.1 Surface Characterization by AFM and AFMIR -- 4.7.2 Transmission Electron Microscopy -- 4.7.3 Electrochemical Characterization -- 4.8 Applications of Various Conducting Polymers in Battery -- 4.8.1 Polyacetylene Battery -- 4.8.2 Polyaniline Batteries -- 4.8.3 Poly (p-phenylene) Batteries -- 4.8.4 Heterocyclic Polymer Batteries -- 4.9 Summary and Outlook -- References -- Chapter 5. Polymer-Based Binary Nanocomposites -- 5.1 Introduction -- 5.2 Binary Composites. , 5.3 Nanostructured CPs -- 5.4 Strategies to Improve Performance -- 5.4.1 Low-dimensional Capacitors -- 5.4.2 Hybrid Capacitors -- 5.4.2.1 Hybrid Electrode Material -- 5.5 CP/Carbon-based Binary Composite -- 5.6 CP/Metal Oxides Binary Composites -- 5.7 CP/Metal Sulfides Binary Complexes -- 5.8 Other Cp-supported Binary Complexes -- 5.9 Conclusion -- References -- Chapter 6. Polyaniline-Based Supercapacitor Applications -- 6.1 Introduction -- 6.2 Polyaniline (PANI) and Its Application Potential -- 6.3 Supercapacitors -- 6.3.1 PANI in Supercapacitors -- 6.3.2 PANI and Carbon Composites -- 6.3.3 PANI/Porous and Carbon Composites -- 6.3.4 PANI/Graphene Composites -- 6.3.5 PANI/CNTs Composites -- 6.3.6 Polyaniline Activation/Carbonization -- 6.3.7 Composites of Polyaniline with Various Conductive Polymer Blends -- 6.3.8 Composites of Polyaniline with Transition Metal Oxides -- 6.3.9 Composites of Polyaniline Core-Shells with Metal Oxides -- 6.3.10 PANI-modified Cathode Materials -- 6.3.11 PANI-modified Anode Materials -- 6.4 Redox-active Electrolytes for PANI Supercapacitors -- 6.5 Examples of Various Polyaniline-based Supercapacitor -- 6.5.1 Composites of Polyaniline Doped with CoCl2 as Materials for Electrodes -- 6.5.2 Composites of Polyaniline Nanofibers with Graphene as materials for electrodes -- 6.5.3 Composites of Polyaniline (PANI) with Graphene Oxide as Electrode Materials -- 6.5.4 Hybrid Films of Manganese Dioxide and Polyaniline as Electrode Materials -- 6.5.5 Composites of Activated Carbon/Polyaniline with Tungsten Trioxide as Electrode Materials -- 6.5.6 PANI- and MOF-based Flexible Solid-state Supercapacitors -- 6.5.7 Polyaniline-based Nickel Electrodes for Electrochemical Supercapacitors -- 6.5.8 Hydrogel of Ultrathin Pure Polyaniline Nanofibers in Supercapacitor Application -- Conclusion -- Acknowledgements -- References. , Chapter 7. Conductive Polymer-derived Materials for Supercapacitor -- 7.1 Introduction -- 7.2 Types of Supercapacitor -- 7.3 Parameters of Supercapacitors -- 7.4 Conducting Polymers (CPs) as Electrode Materials -- 7.4.1 Class of Conducting Polymer as Supercapacitor Electrode -- 7.5 Polyaniline (PANI)-based Electrode -- 7.6 Polypyrrole (PPy)-based Electrode -- 7.7 Polythiophene (PTh)-based Electrode -- 7.8 Conclusions -- Acknowledgement -- References -- Chapter 8. Conducting Polymer-Metal Based Binary Composites for Battery Applications -- 8.1 Conducting polymer (CPs) -- 8.2 Conducting polymers conductivity -- 8.3 Conducting polymer composites -- 8.3.1 Metal center nanoparticles -- 8.3.2 Metal nanoparticles -- 8.4 Conducting Polymer Based Binary Composites -- 8.4.1 Metal Matrix Composites (MMC) -- 8.4.2 Poly (Thiophene) composite -- 8.4.3 Poly (Para-Phenylene Vinylene) composite -- 8.4.4 Poly (Carbazole) composite -- 8.4.5 Vanadium oxide based conducting composite -- 8.4.6 PANI-V2O5 composite -- 8.4.7 Poly(N-sulfo propyl aniline)-V2O5 composite -- 8.5 Conducting polymer composite battery applications -- 8.5.1 Conducting polymer composite for Lithium-ion (Li+) based battery -- 8.5.2 Conducting polymer composites for Sodium-ion (Na+) based Battery -- 8.5.3 Conducting Polymer composite for Mg-Ion (Mg+2) Based Battery -- 8.6 Conducting polymer based composites for electrode materials -- References -- Chapter 9. Novel Conducting Polymer-Based Battery Application -- 9.1 Conducting Polymers (CPs) -- 9.1.1 Poly(Acetylene) -- 9.1.2 Poly(Thiophene) -- 9.1.3 Poly(Aniline) -- 9.1.4 Poly(Pyrrole) -- 9.1.5 Poly(Paraphenylene) and Poly(Phenylene) -- 9.2 Battery Applications of Conducting Polymers -- 9.2.1 Lithium Sulfide batteries -- 9.2.2 Binder for Lithium sulfide battery cathode -- 9.2.3 Sulfur encapsulation for electrode materials. , 9.2.4 Sulfur Encapsulation through Conductive Polymers -- 9.2.5 Conducting polymer anodes for Lithium sulfide battery -- 9.2.6 Conducting polymer as materials interlayer -- 9.3 Li+-ion-based Battery Applications of Conducting Polymers -- 9.4 Na+- ion-based Battery Applications of Conducting Polymers -- 9.5 Mg+2-ion-based Battery Applications of Conducting Polymers -- References -- Chapter 10. Conducting Polymer-Carbon-Based Binary Composites for Battery Applications -- Abbreviations -- 10.1 Introduction -- 10.2 Batteries -- 10.2.1 Types of Batteries -- 10.2.2 Electrode Materials -- 10.3 Conducting Polymer-Carbon-Based Binary Composite in Battery Applications -- 10.3.1 Polyaniline PANI-Carbon-Based Composite -- 10.3.2 Polypyrrole (PPy)-Carbon-Based Composite -- 10.3.3 Poly(3,4-ethylenedioxythiophene) (PEDOT)-Carbon-Based Composite -- 10.3.4 Others Conducting Polymer-Carbon-Based Composite -- 10.4 Conclusions -- Acknowledgements -- References -- Chapter 11. Polyethylenedioxythiophene-Based Battery Applications -- 11.1 Chemistry of PEDOT -- 11.1.1 PEDOT Synthesis and Morphology -- 11.1.1.1 Synthetic Techniques to Achieve Desired Morphologies -- 11.1.2 PEDOT-Based Nanocomposites -- 11.2 PEDOT-Based Polymers in Lithium-Sulfur Batteries -- 11.3 Lithium-Air Battery Based on PEDOT or PEDOT:PSS -- 11.3.1 PEDOT-Based Nanocomposites for Li-O2 Batteries -- 11.3.2 PEDOT:PSS-Based Li-O2 Battery Cathodes -- 11.4 Lithium and Alkali Ion Polythiophene Batteries -- 11.4.1 Cathodes -- 11.4.1.1 Cathode Binders and Composites -- 11.4.2 Anodes -- 11.4.2.1 Anode Binders and Composites -- 11.4.3 All-Polythiophene and Metal-Free Batteries -- References -- Chapter 12. Polythiophene-Based Supercapacitor Applications -- 12.1 Introduction -- 12.2 Properties of Polythiophene (PTh) -- 12.3 Synthesis of Polythiophene -- 12.4 Charge Storage in Polythiophene Electrochemical Capacitors. , 12.5 Polythiophene Electrode Fabrication.
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  • 8
    Online Resource
    Online Resource
    Milton :Taylor & Francis Group,
    Keywords: Porous materials. ; Electronic books.
    Description / Table of Contents: Internationally assembled experts in the field describe developments and advances in synthesis, tuning parameters, and applications of porous polymers. Chapter topics span basic studies, novel issues, and applications addressing all aspects in a one-stop reference on porous polymers.
    Type of Medium: Online Resource
    Pages: 1 online resource (277 pages)
    Edition: 1st ed.
    ISBN: 9781000567168
    DDC: 547/.7
    Language: English
    Note: Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- Editors -- Contributors -- Chapter 1: Introduction to Porous Polymers -- 1.1 Introduction -- 1.2 Types of Porous Polymers -- 1.3 Synthetic Methods for Porous Polymer Network -- 1.4 Conclusion -- References -- Chapter 2: Hyper-crosslinked Polymers -- 2.1 Introduction -- 2.1.1 Overview -- 2.1.2 Porous Polymer -- 2.1.3 Crosslinking -- 2.2 Hyper-crosslinked Polymers -- 2.3 Synthesis Methods of HCPs -- 2.3.1 Post-crosslinking Polymer Precursors -- 2.3.2 Direct One-Step Polycondensation -- 2.3.3 Knitting Rigid Aromatic Building Blocks by External Crosslinkers -- 2.4 Structure and Morphology of HCPs -- 2.4.1 Nanoparticles -- 2.4.2 Hollow Capsules -- 2.4.3 2D Membranes -- 2.4.4 Monoliths -- 2.5 HCPs Properties -- 2.5.1 Polymer Surface -- 2.5.1.1 Hydrophilicity -- 2.5.1.2 Hydrophobicity -- 2.5.1.3 Amphiphilicity -- 2.5.2 Porosity and Surface Area -- 2.5.3 Swelling Behavior -- 2.5.4 Thermomechanical Properties -- 2.6 Functionalization of HCPs -- 2.7 Characterization of HCPs -- 2.7.1 Compositional and Structural Characterization -- 2.7.2 Morphological Characterization -- 2.7.3 Porosity and Surface Area Analysis -- 2.7.4 Other Analysis -- 2.8 Applications -- 2.8.1 Storage Capacity -- 2.8.1.1 Storage of Hydrogen -- 2.8.1.2 Storage of Methane -- 2.8.1.3 CO 2 Capture -- 2.8.2 Environmental Remediation -- 2.8.3 Heterogeneous Catalysis -- 2.8.4 Drug Delivery -- 2.8.5 Sensing -- 2.8.6 Other Applications -- 2.9 Conclusion -- References -- Chapter 3: Porous Ionic Polymers -- 3.1 Introduction: A Distinctive Feature of the Porous Structure of Ionic Polymers -- 3.2 Ionic Polymers in Dry State -- 3.3 Ionic Polymers in Swollen State: Hsu-Gierke Model -- 3.4 Modifications of Hsu-Gierke Model: Hydration of Ion Exchange Polymers. , 3.5 Methods for Research of Porous Structure of Ionic Polymers -- 3.5.1 Nitrogen Adsorption-Desorption -- 3.5.2 Mercury Intrusion -- 3.5.3 Adsorption-Desorption of Water Vapor -- 3.5.4 Differential Scanning Calorimetry -- 3.5.5 Standard Contact Porosimetry -- 3.6 Conclusions -- References -- Chapter 4: Analysis of Qualitative and Quantitative Criteria of Porous Plastics -- 4.1 Introduction -- 4.2 Sorting of Porous Polymers -- 4.2.1 Macroporous Polymers -- 4.2.2 Microporous Polymers -- 4.2.3 Mesoporous Polymers -- 4.3 Methodology -- 4.3.1 AHP Analysis -- 4.4 Conclusions -- References -- Chapter 5: Novel Research on Porous Polymers Using High Pressure Technology -- 5.1 Background -- 5.2 Porous Polymers Based on Natural Polysaccharides -- 5.3 Parameters Involved in the Porous Polymers Processing by High Pressure -- 5.4 Supercritical Fluid Drying for Porous Polymers Processing -- 5.5 Porous Polymers for Foaming and Scaffolds by Supercritical Technology -- 5.6 Supercritical CO 2 Impregnation in Porous Polymers for Food Packaging -- 5.7 Synthesis of Porous Polymers by Supercritical Emulsion Templating -- 5.8 Porous Polymers as Supports for Catalysts Materials by Supercritical Fluid -- 5.9 Porous Metal-Organic Frameworks Polymers by Supercritical Fluid Processing -- 5.10 Concluding Remarks -- Acknowledgments -- References -- Chapter 6: Porous Polymer for Heterogeneous Catalysis -- 6.1 Introduction -- 6.2 Stability and Functionalization of POPs -- 6.3 Strategies for Synthesizing POP Catalyst -- 6.3.1 Co-polymerization -- 6.3.1.1 Acidic and Basic Groups -- 6.3.1.2 Ionic Groups -- 6.3.1.3 Ligand Groups -- 6.3.1.4 Chiral Groups -- 6.3.1.5 Porphyrin Group -- 6.3.2 Self-polymerization -- 6.3.2.1 Organic Ligand Groups -- 6.3.2.2 Organocatalyst Groups -- 6.3.2.3 Ionic Groups -- 6.3.2.4 Chiral Ligand Groups -- 6.3.2.5 Porphyrin Groups. , 6.4 Applications of Various Porous Polymers -- 6.4.1 CO 2 Capture and Utilization -- 6.4.1.1 Ionic Liquid/Zn-PPh 3 Integrated POP -- 6.4.1.1.1 Mechanism of the Cycloaddition Reaction -- 6.4.1.2 Triphenylphosphine-based POP -- 6.4.2 Energy Storage -- 6.4.3 Heterogeneous Catalysis -- 6.4.3.1 Cu(II) Complex on Pyridine-based POP for Nitroarene Reduction -- 6.4.3.2 POP-supported Rhodium for Hydroformylation of Olefins -- 6.4.3.3 Ni(II)-metallated POP for Suzuki-Miyaura Crosscoupling Reaction -- 6.4.3.4 Ru-loaded POP for Decomposition of Formic Acid to H 2 -- 6.4.3.5 Porphyrin-based POP to Support Mn Heterogeneous Catalysts for Selective Oxidation of Alcohols -- 6.4.3.5.1 Mechanism of the Oxidation of Alcohols by TFP-DPMs -- 6.4.4 Photocatalysis -- 6.4.4.1 Conjugated Porous Polymer Based on Phenanthrene Units -- 6.4.4.2 (dipyrrin)(bipyridine)ruthenium(II) Visible Light Photocatalyst -- 6.4.4.3 Carbazole-based CMPs for C-3 Functionalization of Indoles -- 6.4.4.3.1 Mechanism of C-3 Formylation of N-methylindole by CMP-CSU6 Polymer Catalyst -- 6.4.4.3.2 The Mechanism for C-3 Thiocyanation of 1H-indole -- 6.4.5 Electrocatalysis -- 6.4.5.1 Redox-active N-containing CPP for Oxygen Reduction Reaction (ORR) -- References -- Chapter 7: Triazine Porous Frameworks -- 7.1 Introduction -- 7.2 Synthetic Procedures of CTFs and Their Structural Designs -- 7.2.1 Ionothermal Trimerization Strategy -- 7.2.2 High Temperature Phosphorus Pentoxide (P 2 O 5)-Catalyzed Method -- 7.2.3 Amidine-based Polycondensation Methods -- 7.2.4 Superacid Catalyzed Method -- 7.2.5 Friedel-Crafts Reaction Method -- 7.3 Applications of CTFs -- 7.3.1 Adsorption and Separation -- 7.3.1.1 CO 2 Capture and Separation -- 7.3.1.2 The Removal of Pollutants -- 7.3.2 Heterogeneous Catalysis -- 7.3.3 Applications for Energy Storage and Conversion -- 7.3.3.1 Metal-Ion Batteries -- 7.3.3.2 Supercapacitors. , 7.3.4 Electrocatalysis -- 7.3.5 Photocatalysis -- 7.3.6 Other Applications of CTFs -- References -- Chapter 8: Advanced Separation Applications of Porous Polymers -- 8.1 Introduction -- 8.2 Advanced Separation Applications -- 8.3 Separation through Adsorption -- 8.4 Water Treatment -- 8.5 Conclusion -- Abbreviations -- References -- Chapter 9: Porous Polymers for Membrane Applications -- 9.1 Introduction -- 9.2 Introduction to Synthesis of Porous Polymeric Particles -- 9.3 Preparation of Porous Polymeric Membrane -- 9.4 Morphology of Membrane and Its Parameters -- 9.5 Emerging Applications of Porous Polymer Membranes -- 9.6 Polysulfone and Polyvinylidene Fluoride Used as Porous Polymers for Membrane Application -- 9.6.1 Polysulfone Membranes -- 9.6.2 Polyvinylidene Fluoride Membranes -- 9.7 Use of Porous Polymeric Membranes for Sensing Application -- 9.8 Use of Porous Polymeric Electrolytic Membranes Application -- 9.9 Use of Porous Polymeric Membrane for Numerical Modeling and Optimization -- 9.10 Use of Porous Polymers for Biomedical Application -- 9.11 Use of Porous Polymeric Membrane in Tissue Engineering -- 9.12 Use of Porous Polymeric Membrane in Wastewater Treatment -- 9.13 Use of Porous Polymeric Membrane for Dye Rejection Application -- 9.14 Porous Polymeric Membrane Antifouling Application -- 9.15 Porous Polymeric Membrane Used for Fuel Cell Application -- 9.16 Conclusion -- References -- Chapter 10: Porous Polymers in Solar Cells -- 10.1 Introduction -- 10.1.1 Si-based Solar Cells -- 10.1.2 Thin-film Solar Cells -- 10.1.3 Organic Solar Cells -- 10.2 Porous Polymers in DSSCs -- 10.2.1 Porous Polymers in Electrodes -- 10.2.2 Porous Polymer as a Counter Electrode -- 10.2.3 Porous Polymers in TiO 2 Photoanode -- 10.2.4 Porous Polymers in Electrolyte -- 10.2.5 Porous Polymer as Energy Conversion Film. , 10.2.5.1 Polyvinylidene Fluoride-co-Hexafluoropropylene (PVDF-HFP) Membranes -- 10.2.5.2 Pyridine-based CMPs Aerogels (PCMPAs) -- 10.2.6 Porous Polymers in Coating of Solar Cell -- 10.2.7 Porous Polymers as Photocatalyst or Electrocatalyst -- 10.3 Perovskite Solar Cells -- 10.3.1 Porous Polymers in Electron Transport Layers -- 10.3.2 Porous Polymers in Hole Transport Layers -- 10.3.3 Porous Polymer as Energy Conversion Film -- 10.3.4 Porous Polymers as Interlayers -- 10.3.5 Porous Polymers in Morphology Regulations -- 10.4 Porous Polymers in Silicon Solar Cell -- 10.5 Miscellaneous -- 10.5.1 Porous Polymers in Solar Evaporators -- 10.5.2 Charge Separation Systems in Solar Cells -- 10.5.3 Porous Polymers in ZnO Photoanode -- 10.6 Conclusions -- References -- Chapter 11: Porous Polymers for Hydrogen Production -- 11.1 Introduction -- 11.1.1 Approaches Utilized for the Generation of Porous Polymers (PPs) -- 11.1.1.1 Infiltration -- 11.1.1.2 Layer-by-Layer Assembly (LbL) -- 11.1.1.3 Conventional Polymerization -- 11.1.1.4 Electrochemical Polymerization -- 11.1.1.5 Controlled/Living Polymerization (CLP) -- 11.1.1.6 Macromolecular Design -- 11.1.1.7 Self-assembly -- 11.1.1.8 Phase Separation -- 11.1.1.9 Solid and Liquid Templating -- 11.1.1.10 Foaming -- 11.2 Various Porous Polymers for H 2 Production -- 11.2.1 Photocatalysts Based on Conjugated Microporous Polymers -- 11.2.2 Conjugated Microporous Polymers -- 11.2.3 Porous Conjugated Polymer (PCP) -- 11.2.4 Membrane Reactor -- 11.2.5 Paper-Structured Catalyst with Porous Fiber-Network Microstructure -- 11.2.6 Porous Organic Polymers (POPs) -- 11.2.7 PEM Water Electrolysis -- 11.2.8 Microporous Inorganic Membranes -- 11.2.9 Hybrid Porous Solids for Hydrogen Evolution -- 11.3 Other Alternatives for Hydrogen Production -- 11.3.1 Metal-Organic Frameworks (MOFs) -- 11.3.2 Covalent Organic Frameworks. , 11.3.3 Photochemical Device.
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  • 9
    Online Resource
    Online Resource
    Newark :John Wiley & Sons, Incorporated,
    Keywords: Geochemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (208 pages)
    Edition: 1st ed.
    ISBN: 9781119710080
    DDC: 551.9
    Language: English
    Note: Cover -- Half-Title Page -- Series Page -- Title Page -- Copyright Page -- Contents -- Preface -- 1 Toxic Geogenic Contaminants in Serpentinitic Geological Systems: Occurrence, Behavior, Exposure Pathways, and Human Health Risks -- 1.1 Introduction -- 1.2 Serpentinitic Geological Systems -- 1.2.1 Nature, Occurrence, and Geochemistry -- 1.2.2 Occurrence and Behavior of Toxic Contaminants -- 1.3 Human Exposure Pathways -- 1.3.1 Occupational Exposure -- 1.3.2 Non-Occupational Exposure Routes -- 1.4 Human Health Risks and Their Mitigation -- 1.4.1 Health Risks -- 1.4.2 Mitigating Human Exposure and Health Risks -- 1.5 Future Perspectives -- 1.6 Conclusions -- Acknowledgements -- References -- 2 Benefits of Geochemistry and Its Impact on Human Health -- 2.1 Introduction -- 2.2 General Overview of Geochemistry and Human Health -- 2.2.1 Types of Geochemistry -- 2.2.2 Some Beneficial Effect of Some Mineral With Health Benefits -- 2.2.3 Application of Geochemistry on Human Health -- 2.3 Conclusion and Recommendations -- References -- 3 Applications of Geochemistry in Livestock: Health and Nutritional Perspective -- 3.1 Introduction -- 3.2 General and Global Perspective About Geochemistry in Livestock -- 3.3 Types of Geochemistry and Their Numerous Benefits -- 3.3.1 Analytical Geochemistry -- 3.3.2 Isotope Geochemistry -- 3.3.3 Low Temperature Geochemistry -- 3.3.4 Organic and Petroleum Geochemistry -- 3.4 Application of Geochemistry in Livestock -- 3.5 Geochemistry and Animal Health -- 3.6 General Overview of Geochemistry in Livestock's Merits of Geochemistry/Essential Minerals in Livestocks -- 3.6.1 Specific Examples of Authors That Have Used Essential Minerals in Livestock -- 3.6.2 Livestock in Relation to Geominerals -- 3.6.3 Trace Minerals Parallel Importance in Livestock -- 3.6.4 Heavy Metals Impact Livestock -- 3.7 Conclusion and Recommendations. , References -- 4 Application in Geochemistry Toward the Achievement of a Sustainable Agricultural Science -- 4.1 Introduction -- 4.2 General Overview on the Utilization of Geochemistry and Their Wide Application on Agriculture -- 4.2.1 Classification -- 4.2.2 Chemical Composition of Rocks -- 4.2.3 Effect of Some Beneficial Minerals in Agriculture -- 4.2.4 Beneficial Mineral Nutrients That are Crucial to the Development of Plants -- 4.3 Role of Geochemistry in Agriculture -- 4.4 Geochemical Effects of Heavy Metals on Crops Health -- 4.5 Conclusion and Recommendations -- References -- 5 Geochemistry, Extent of Pollution, and Ecological Impact of Heavy Metal Pollutants in Soil -- 5.1 Introduction -- 5.2 Material and Methods -- 5.2.1 Review Process -- 5.2.2 Ecological Risk Index -- 5.3 Toxic Heavy Metal and Their Impact to the Ecosystems -- 5.3.1 Arsenic -- 5.3.2 Cadmium -- 5.3.3 Chromium -- 5.3.4 Copper -- 5.3.5 Lead -- 5.3.6 Nickel -- 5.3.7 Zinc -- 5.4 Metal Pollution in Soil Across the Globe -- 5.5 Ecological and Human Health Risk Impacts of Heavy Metals -- 5.6 Conclusion -- References -- 6 Isotope Geochemistry -- 6.1 Introduction -- 6.2 Basic Definitions -- 6.2.1 The Notation -- 6.2.2 The Fractionation Factor -- 6.2.3 Isotope Fractionation -- 6.2.4 Mass Dependent and Independent Fractionations -- 6.3 Application of Traditional Isotopes in Geochemistry -- 6.3.1 Geothermometer -- 6.3.2 Isotopes in Biological System -- 6.3.3 Isotopes in Archaeology -- 6.3.4 Isotopes in Fossils and the Earliest Life -- 6.3.5 Isotopes in Hydrothermal and Ore Deposits -- 6.4 Non-Traditional Isotopes in Geochemistry -- 6.4.1 Application in Tracing of Source -- 6.4.2 Application in Process Tracing -- 6.4.3 Biological Cycling -- 6.5 Conclusion -- References -- 7 Environmental Geochemistry -- 7.1 Introduction -- 7.2 Overview of the Environmental Geochemistry -- 7.3 Conclusions. , 7.4 Abbreviations -- Acknowledgment -- References -- 8 Medical Geochemistry -- 8.1 Introduction -- 8.2 The Evolution of Geochemistry -- 8.3 This Science has Expanded Considerably to Become Distinct Branches -- 8.3.1 Cosmochemistry -- 8.3.2 The Economic Importance of Geochemistry -- 8.3.3 Analytical Geochemistry -- 8.3.4 Geochemistry of Radioisotopes -- 8.3.5 Medical Geochemistry and Human Health -- 8.3.6 Environmental Health and Safety -- 8.4 Conclusion -- References -- 9 Inorganic Geochemistry -- 9.1 Introduction -- 9.2 Elements and the Earth -- 9.2.1 Iron -- 9.2.2 Oxygen -- 9.2.3 Silicon -- 9.2.4 Magnesium -- 9.3 Geological Minerals -- 9.3.1 Quartz -- 9.3.2 Feldspar -- 9.3.3 Amphibole -- 9.3.4 Pyroxene -- 9.3.5 Olivine -- 9.3.6 Clay Minerals -- 9.3.7 Kaolinite -- 9.3.8 Bentonite, Montmorillonite, Vermiculite, and Biotite -- 9.4 Characterization Techniques -- 9.4.1 Powder X-Ray Diffraction -- 9.4.2 X-Ray Fluorescence Spectra -- 9.4.3 X-Ray Photoelectron Spectra -- 9.4.4 Electron Probe Micro-Analysis -- 9.4.5 Inductively Coupled Plasma Spectrometry -- 9.4.6 Fourier Transform Infrared Spectroscopy -- 9.4.7 Scanning Electron Microscopy Analysis -- 9.4.8 Energy Dispersive X-Ray Analysis -- 9.5 Conclusion -- References -- 10 Introduction and Scope of Geochemistry -- 10.1 Introduction -- 10.1.1 Periodic Table and Electronic Configuration -- 10.2 Periodic Properties -- 10.2.1 Ionization Enthalpy -- 10.2.2 Electron Affinity -- 10.2.3 Electro-Negativity -- 10.3 Chemical Bonding -- 10.3.1 Ionic Bond -- 10.3.2 Covalent Bond -- 10.3.3 Metallic Bond -- 10.3.4 Hydrogen Bond -- 10.3.5 Van der Waals Forces -- 10.4 Geochemical Classification and Distribution of Elements -- 10.4.1 Lithophiles -- 10.4.2 Siderophiles -- 10.4.3 Chalcophiles -- 10.4.4 Atmophiles -- 10.4.5 Biophiles -- 10.5 Chemical Composition of the Earth -- 10.6 Classification of Earth's Layers. , 10.6.1 Based on Chemical Composition -- 10.6.2 Based on Physical Properties -- 10.7 Spheres of the Earth -- 10.7.1 Geosphere/Lithosphere -- 10.7.2 Hydrosphere -- 10.7.3 Biosphere -- 10.7.4 Atmosphere -- 10.7.5 Troposphere -- 10.7.6 Stratosphere -- 10.7.7 Mesosphere -- 10.7.8 Thermosphere and Ionosphere -- 10.7.9 Exosphere -- 10.8 Sub-Disciplines of Geochemistry -- 10.9 Scope of Geochemistry -- 10.10 Conclusion -- References -- Index -- EULA.
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  • 10
    Online Resource
    Online Resource
    Newark :John Wiley & Sons, Incorporated,
    Keywords: Polysaccharides-Industrial applications. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (800 pages)
    Edition: 1st ed.
    ISBN: 9781119711391
    Language: English
    Note: Cover -- Half-Title Page -- Series Page -- Title Page -- Copyright Page -- Contents -- Preface -- 1 Natural Polysaccharides From Aloe vera L. Gel (Aloe barbadensis Miller): Processing Techniques and Analytical Methods -- 1.1 Introduction -- 1.1.1 Gel Composition from A. vera -- 1.2 Applications of A. vera Mucilaginous Gel or Fractions -- 1.3 Aloe vera Gel Processing -- 1.3.1 Obtaining Polysaccharide Fraction or Acemannan -- 1.4 Analytical Methods Applied -- 1.4.1 Total Carbohydrates, Oligosaccharides, Acemannan and Free Sugars -- 1.4.2 Analytical Techniques -- 1.4.2.1 Chromatography Analysis -- 1.4.2.2 Infrared Spectroscopy (IR) -- 1.4.2.3 Nuclear Magnetic Resonance Spectroscopy -- 1.4.2.4 Mass Spectrometry -- 1.4.2.5 Ultraviolet-Visible Spectroscopy -- 1.4.2.6 Comprehensive Microarray Polymer Profiling -- 1.5 Conclusion -- References -- 2 Cell Wall Polysaccharides -- 2.1 Introduction to Cell Wall -- 2.2 Plant Cell Wall Polysaccharides -- 2.2.1 Cellulose -- 2.2.2 Hemicellulose -- 2.2.2.1 Xyloglucan -- 2.2.2.2 Xylans -- 2.2.2.3 Mannans -- 2.2.3 Callose -- 2.2.4 Pectic Polysaccharides -- 2.2.4.1 Homogalacturonan (HG) -- 2.2.4.2 Arabinan -- 2.3 Algal Cell Wall Polysaccharides -- 2.3.1 Alginates -- 2.3.2 Sulfated Galactans -- 2.3.3 Fucoidans -- 2.4 Fungal Cell Wall Polysaccharides -- 2.4.1 Glucan -- 2.4.2 Chitin and Chitosan -- 2.5 Bacterial Cell Wall Polysaccharides -- 2.5.1 Peptidoglycan -- 2.5.2 Lipopolysaccharides -- References -- 3 Marine Polysaccharides: Properties and Applications -- 3.1 Introduction -- 3.2 Polysaccharide Origins -- 3.3 Properties -- 3.3.1 Cellulose -- 3.3.2 Chitosan -- 3.3.3 Alginate -- 3.3.4 Carrageenan -- 3.3.5 Agar -- 3.3.6 Porphyran -- 3.3.7 Fucoidan -- 3.3.8 Ulvan -- 3.3.9 Exopolysaccharides From Microalgae -- 3.4 Applications of Polysaccharides -- 3.4.1 Biomedical Applications -- 3.4.1.1 Cellulose -- 3.4.1.2 Chitosan. , 3.4.1.3 Alginate -- 3.4.2 Food Applications -- 3.4.2.1 Cellulose -- 3.4.2.2 Chitosan -- 3.4.2.3 Alginates -- 3.4.2.4 Carrageenan -- 3.4.2.5 Agar -- 3.4.3 Pharmaceutical and Nutraceutical Applications -- 3.4.3.1 Cellulose -- 3.4.3.2 Chitosan -- 3.4.3.3 Alginate -- 3.4.3.4 Carrageenan -- 3.4.3.5 Porphyran -- 3.4.3.6 Fucoidan -- 3.4.4 Agriculture -- 3.5 Conclusions -- References -- 4 Seaweed Polysaccharides: Structure, Extraction and Applications -- 4.1 Introduction -- 4.1.1 Agar -- 4.1.2 Carrageenan -- 4.1.3 Alginate (Alginic Acid, Algin) -- 4.1.4 Fucoidan -- 4.1.5 Laminaran -- 4.1.6 Ulvan -- 4.2 Conclusion -- References -- 5 Agars: Properties and Applications -- 5.1 History and Origin of Agar -- 5.1.1 Agarophytes Used in Agar Manufacturing -- 5.2 Physical Properties of Agar Producing Seaweeds -- 5.3 Agar Manufacturing -- 5.3.1 Types of Agar Manufacturing -- 5.3.1.1 Freeze-Thaw Method -- 5.3.1.2 Syneresis Method -- 5.4 Structure of Agar -- 5.5 Heterogeneity of Agar -- 5.6 Physico-Chemical Characteristics of Agar -- 5.7 Chemical Characteristics of Agar -- 5.8 Factors Influencing the Characteristics of Agar -- 5.8.1 Techniques to Analyze the Fine Chemical Structure of Agar -- 5.8.2 Synergies and Antagonisms of Agar Gels -- 5.9 Uses of Agar in Various Sectors -- 5.9.1 Applications of Agar in Food Industry -- 5.9.2 Application of Agar in Harvesting Insects and Worms -- 5.9.3 Vegetable Tissue Culture Formulations -- 5.9.4 Culture Media for Microbes -- 5.9.5 Industrial Applications of Agar -- 5.10 Conclusion and Discussion -- References -- 6 Biopolysaccharides: Properties and Applications -- 6.1 Structure and Classification of Biopolysaccharides -- 6.1.1 Structure -- 6.1.2 Classification -- 6.1.3 Structural Characterization Techniques -- 6.2 Uses and Applications of Biopolysaccharides -- 6.2.1 Functional Fibers -- 6.2.2 Biomedicine. , 6.2.2.1 Tissue Engineering -- 6.2.2.2 Wound Healing -- 6.2.2.3 Drug Loading and Delivery -- 6.2.2.4 Therapeutics -- 6.2.3 Cosmetics -- 6.2.4 Foods and Food Ingredients -- 6.2.5 Biofuels -- 6.2.6 Wastewater Treatment -- 6.2.7 Textiles -- 6.3 Conclusion -- References -- 7 Chitosan Derivatives: Properties and Applications -- 7.1 Introduction -- 7.2 Properties of Chitosan Derivatives -- 7.2.1 Physiochemical Properties -- 7.2.2 Functional Properties -- 7.2.3 Biological Properties of Chitosan -- 7.3 Applications of Chitosan Derivatives -- 7.3.1 Anticancer Agents -- 7.3.2 Bone Tissue Material Formation -- 7.3.3 Wound Healing, Tissue Regeneration and Antimicrobial Resistance -- 7.3.4 Drug Delivery -- 7.3.5 Chromatographic Separations -- 7.3.6 Waste Management -- 7.3.7 Food Industry -- 7.3.8 In Cosmetics -- 7.3.9 In Paint as Antifouling Coatings -- 7.4 Conclusions -- Acknowledgement -- References -- 8 Green Seaweed Polysaccharides Inventory of Nador Lagoon in North East Morocco -- 8.1 Introduction -- 8.2 Nador Lagoon: Situation and Characteristics -- 8.3 Seaweed -- 8.4 Polysaccharides in Seaweed -- 8.5 Algae Polysaccharides in Nador Lagoon's Seaweed -- 8.5.1 C. prolifera -- 8.5.1.1 Sulfated Galactans -- 8.5.2 U. rigida & -- E. intestinalis -- 8.5.2.1 Ulvan -- 8.5.3 C. adhaerens, C. bursa, C. tomentosum -- 8.5.3.1 Sulfated Arabinans -- 8.5.3.2 Sulfated Arabinogalactans -- 8.5.3.3 Mannans -- 8.6 Conclusion -- References -- 9 Salep Glucomannan: Properties and Applications -- 9.1 Introduction -- 9.2 Production -- 9.3 Composition and Physicochemical Structure -- 9.4 Rheological Properties -- 9.5 Purification and Deacetylation -- 9.6 Food Applications -- 9.6.1 Beverage -- 9.6.2 Ice Cream and Emulsion Stabilizing -- 9.6.3 Edible Film/Coating -- 9.6.4 Gelation -- 9.7 Health Benefits -- 9.8 Conclusions and Future Trends -- References. , 10 Exudate Tree Gums: Properties and Applications -- 10.1 Introduction -- 10.1.1 Gum Arabic -- 10.1.2 Gum Karaya -- 10.1.3 Gum Kondagogu -- 10.1.4 Gum Ghatti -- 10.1.5 Gum Tragacanth -- 10.1.6 Gum Olibanum -- 10.2 Nanobiotechnology Applications -- 10.3 Minor Tree Gums -- 10.4 Conclusions -- Acknowledgment -- References -- 11 Cellulose and its Derivatives: Properties and Applications -- 11.1 Introduction -- 11.2 Main Raw Materials -- 11.3 Composition and Chemical Structure of Lignocellulosic Materials -- 11.4 Cellulose: Chemical Backbone and Crystalline Formats -- 11.5 Cellulose Extraction -- 11.5.1 Mechanical Methods -- 11.5.2 Chemical Methods -- 11.6 Cellulose Products and its Derivatives -- 11.7 Main Applications -- 11.8 Conclusion -- References -- 12 Starch and its Derivatives: Properties and Applications -- 12.1 Introduction -- 12.2 Physicochemical and Functional Properties of Starch -- 12.2.1 Size, Morphology and Crystallinity of Starch Granules -- 12.2.2 Physical Properties due to Associated Lipids, Proteins and Phosphorus With Starch Granules -- 12.2.3 Solubility and Swelling Capacity of Starch -- 12.2.4 Gelatinization and Retrogradation of Starch -- 12.2.5 Birefringence and Glass Transition Temperature of Starch -- 12.2.6 Rheological and Thermal Properties of Starch -- 12.2.7 Transmittance and Opacity of Starch -- 12.2.8 Melt Processability of Starch -- 12.3 Modification of Starch -- 12.3.1 Physical Modification of Starch -- 12.3.2 Chemical Modification of Starch -- 12.3.3 Dual Modification of Starch -- 12.3.4 Enzymatic Modification of Starch -- 12.3.5 Genetic Modification of Starch -- 12.4 Application of Starch and its Derivatives -- 12.4.1 In Food Industry -- 12.4.2 In Paper Industry -- 12.4.3 Starch as Binders -- 12.4.4 In Detergent Products -- 12.4.5 As Biodegradable Thermoplastic Materials or Bioplastics. , 12.4.6 In Pharmaceutical and Cosmetic Industries -- 12.4.7 As Industrial Raw Materials -- 12.4.8 As Adsorbents for Environmental Applications -- 12.4.9 As Food Packaging Materials -- 12.4.10 In Drug Delivery -- 12.4.11 As Antimicrobial Films and Coatings -- 12.4.12 In Advanced Functional Materials -- 12.5 Conclusion -- References -- 13 Crystallization of Polysaccharides -- 13.1 Introduction -- 13.2 Principles of Crystallization of Polysaccharides -- 13.3 Techniques for Crystallinity Measurement -- 13.4 Crystallization Behavior of Polysaccharides -- 13.4.1 Cellulose -- 13.4.2 Chitosan and Chitin -- 13.4.3 Starch -- 13.5 Polymer/Polysaccharide Crystalline Nanocomposites -- 13.6 Conclusion -- References -- 14 Polysaccharides as Novel Materials for Tissue Engineering Applications -- 14.1 Introduction -- 14.2 Types of Scaffolds for Tissue Engineering -- 14.3 Biomaterials for Tissue Engineering -- 14.4 Polysaccharide-Based Scaffolds for Tissue Engineering -- 14.4.1 Alginate-Based Scaffolds -- 14.4.2 Chitosan-Based Scaffolds -- 14.4.3 Cellulose-Based Scaffolds -- 14.4.4 Dextran and Pullulan-Based Scaffolds -- 14.4.5 Starch-Based Scaffolds -- 14.4.6 Xanthan-Based Scaffolds -- 14.4.7 Glycosaminoglycans-Based Scaffolds -- 14.5 Current Challenges and Future Perspectives -- Acknowledgements -- References -- 15 Structure and Solubility of Polysaccharides -- 15.1 Introduction -- 15.2 Polysaccharide Structure and Solubility in Water -- 15.3 Solubility and Molecular Weight -- 15.4 Solubility and Branching -- 15.5 Polysaccharide Solutions -- 15.6 Conclusions -- Acknowledgments -- References -- 16 Polysaccharides: An Efficient Tool for Fabrication of Carbon Nanomaterials -- 16.1 Introduction -- 16.2 Aerogels -- 16.2.1 Plant and Bacterial Cellulose -- 16.2.2 Carbon Derived From Nanocrystalline Cellulose of Plant Origin. , 16.2.3 Carbon Aerogels Produced From Bacterial Cellulose.
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