Description: The interplay between sediment deposition patterns, organic matter type and the quantity and quality of reactive mineral phases determines the accumulation, speciation and isotope composition of pore water and solid phase sulfur constituents in marine sediments. Here, we present the sulfur geochemistry of siliciclastic sediments from two sites along the Argentine continental slope--a system characterized by dynamic deposition and reworking, which result in non-steady state conditions. The two investigated sites have different depositional histories but have in common that reactive iron phases are abundant and that organic matter is refractory--conditions that result in low organoclastic sulfate reduction rates. Deposition of reworked, isotopically light pyrite and sulfurized organic matter appear to be important contributors to the sulfur inventory, with only minor addition of pyrite from organoclastic sulfate reduction above the sulfate-methane transition (SMT). Pore-water sulfide is limited to a narrow zone at the SMT. The core of that zone is dominated by pyrite accumulation. Iron monosulfide and elemental sulfur accumulate above and below this zone. Iron monosulfide precipitation is driven by the reaction of low amounts of hydrogen sulfide with ferrous iron and is in competition with the oxidation of sulfide by iron (oxyhydr)oxides to form elemental sulfur. The intervals marked by precipitation of intermediate sulfur phases at the margin of the zone with free sulfide are bordered by two distinct peaks in total organic sulfur. Organic matter sulfurization appears to precede pyrite formation in the iron-dominated margins of the sulfide zone, potentially linked to the presence of polysulfides formed by reaction between dissolved sulfide and elemental sulfur. Thus, SMTs can be hotspots for organic matter sulfurization in sulfide-limited, reactive iron-rich marine sedimentary systems. Furthermore, existence of elemental sulfur and iron monosulfide phases meters below the SMT demonstrates that in sulfide-limited systems metastable sulfur constituents are not readily converted to pyrite but can be buried to deeper sediment depths. Our data show that in non-steady state systems, redox zones do not occur in sequence but can reappear or proceed in inverse sequence throughout the sediment column, causing similar mineral alteration processes to occur at the same time at different sediment depths.

Description: The relationship of sea-level changes and short-term climatic changes with turbidite deposition is poorly documented, although the mechanisms of gravity-driven sediment transport in submarine canyons during sea-level changes have been reported from many regions. This study focuses on the activity of the Dakar Canyon off southern Senegal in response to major glacial/interglacial sea-level shifts and variability in the NW-African continental climate. The sedimentary record from the canyon allows us to determine the timing of turbidite events and, on the basis of XRF-scanning element data, we have identified the climate signal at a sub-millennial time scale from the surrounding hemipelagic sediments. Over the late Quaternary the highest frequency in turbidite activity in the Dakar Canyon is confined to major climatic terminations when remobilisation of sediments from the shelf was triggered by the eustatic sea-level rise. However, episodic turbidite events coincide with the timing of Heinrich events in the North Atlantic. During these times continental climate has changed rapidly, with evidence for higher dust supply over NW Africa which has fed turbidity currents. Increased aridity and enhanced wind strength in the southern Saharan-Sahelian zone may have provided a source for this dust.

Description: Mass wasting processes are a common phenomenon along the continental margin of NW-Africa. Located on the high-upwelling regime off the Mauritanian coastline, the Mauritania Slide Complex (MSC) is one of the largest events known on the Atlantic margin with an affected area of ~30000 km**2. Understanding previous failure events as well as its current hazard potential are crucial for risk assessment with respect to offshore installations and tsunamis. We present the results of geotechnical measurements and strain analyses on sediment cores taken from both the stable and the failed part of the MSC and compare them to previously published geophysical and sedimentological data. The material originates from water depths of 1500-3000 m and consists of detached slide deposits separated by undisturbed hemipelagic sediments. While the hemipelagites are characterized by normal consolidation with a downward increase in bulk density and shear strength (from 1.68 to 1.8 g/cm**3, 2-10 kPa), the slid deposits of the uppermost debris flow event preserve constant bulk density values (1.75 and 1.8 g/cm**3) with incisions marking different flow events. These slid sediments comprise three different matrix types, with normal consolidation at the base (OCR = 1.04), strong overconsolidation (OCR = 3.96) in the middle and normal consolidation to slight overconsolidation at the top (OCR = 0.91-1.28). However, the hemipelagic sediments underlying the debris flow units, which have been 14C dated at 〈24 ka BP, show strong to slight underconsolidation (OCR = 0.65-0.79) with low friction coefficients of µ = 0.18. Fabric analyses show deformation intensities R 〉= 4 (ratio Sigma1/Sigma3) in several of the remobilized sediments. Such high deformation is also attested by observed disintegrated clasts from the underlying unit in the youngest debrites (14C-age of 10.5-10.9 ka BP). These clasts show strong consolidation and intense deformation, implying a pre-slide origin and amalgamation into the mass transport deposits. While previous studies propose an emplacement by retrogressive failure for thick slide deposits separated by undisturbed units, our new data on geotechnical properties, strain and age infer at least two different source areas with a sequential failure mechanism as the origin for the different mass wasting events.