Description: We present an SiF4 separation line, coupled to a laser fluorination system, which allows for an efficient combined silica d18O and d30Si analysis (50 min per sample). The required sample weight of 1.5–2.0mg allows for high-resolution isotope studies on biogenic opal. Besides analytical tests, the new instrumentation set-up was used to analyse two marine diatom fractions (〉63 mm, 10–20mm) with different diatom species compositions extracted from a Bølling/Allerød–Holocene core section [MD01-2416, North-West (NW) Pacific] to evaluate the palaeoceanographic significance of the diatom isotopic signals and to address isotopic effects related to contamination and species-related isotope effects (vital and environmental effects). While d30Si offsets between the two fractions were not discernible, supporting the absence of species-related silicon isotope effects, systematic offsets occur between the d18O records. Although small, these offsets point to species-related isotope effects, as bias by contamination can be discarded. The new records strengthen the palaeoceanographic history during the last deglaciation in the NW Pacific characterized by a sequence of events with varying surface water structure and biological productivity. With such palaeoceanographic evolution it becomes unlikely that the observed systematic d18O offsets signal seasonal temperature variability. This calls for reconsideration of vital effects, generally excluded to affect d18O measurements.

Description: Organic geochemical and micropaleontological analyses of surface sediments collected in the southern Drake Passage and the Bransfield Strait, Western Antarctic Peninsula, enable a proxy-based reconstruction of recent sea ice conditions in this climate-sensitive area. We study the distribution of the sea ice biomarker IPSO25, and biomarkers of open marine environments such as more unsaturated highly branched isoprenoid alkenes and phytosterols. Comparison of the sedimentary distribution of these biomarker lipids with sea ice data obtained from satellite observations and diatom-based sea ice estimates provide for an evaluation of the suitability of these biomarkers to reflect recent sea surface conditions. The distribution of IPSO25 supports earlier suggestions that the source diatom seems to be common in near-coastal environments characterized by annually recurring sea ice cover, while the distribution of the other biomarkers is highly variable. Offsets between sea ice estimates deduced from the abundance of biomarkers and satellite-based sea ice data are attributed to the different time intervals recorded within the sediments and the instrumental records from the study area, which experienced rapid environmental changes during the past 100 years. To distinguish areas characterized by permanently ice-free conditions, seasonal sea ice cover and extended sea ice cover, we apply the concept of the PIP25 index from the Arctic Ocean to our data and introduce the term PIPSO25 as a potential sea ice proxy. While the trends in PIPSO25 are generally consistent with satellite sea ice data and winter sea ice concentrations in the study area estimated by diatom transfer functions, more studies on the environmental significance of IPSO25 as a Southern Ocean sea ice proxy are needed before this biomarker can be applied for semi-quantitative sea ice reconstructions.

Description: During the last glacial termination, the upper North Pacific Ocean underwent dramatic and rapid changes in oxygenation that lead to the transient intensification of oxygen minimum zones (OMZs), recorded by the widespread occurrence of laminated sediments on circum-Pacific continental margins. We present a new laminated sediment record from the mid-depth (1100 m) northern Bering Sea margin that provides insight into these deglacial OMZ maxima with exceptional, decadal-scale detail. Combined ultrahigh-resolution micro-X-ray-fluorescence (micro-XRF) data and sediment facies analysis of laminae reveal an alternation between predominantly terrigenous and diatom-dominated opal sedimentation. The diatomaceous laminae are interpreted to represent spring/summer productivity events related to the retreating sea ice margin. We identified five laminated sections in the deglacial part of our site. Lamina counts were carried out on these sections and correlated with the Bølling–Allerød and Preboreal phases in the North Greenland Ice Core (NGRIP) oxygen isotope record, indicating an annual deposition of individual lamina couplets (varves). The observed rapid decadal intensifications of anoxia, in particular within the Bølling–Allerød, are tightly coupled to short-term warm events through increases in regional export production. This dependence of laminae formation on warmer temperatures is underlined by a correlation with published Bering Sea sea surface temperature records and δ18O data of planktic foraminifera from the Gulf of Alaska. The rapidity of the observed changes strongly implies a close atmospheric teleconnection between North Pacific and North Atlantic regions. We suggest that concomitant increases in export production and subsequent remineralization of organic matter in the Bering Sea, in combination with oxygen-poor waters entering the Being Sea, drove down oxygen concentrations to values below 0.1 mL L−1 and caused laminae preservation. Calculated benthic–planktic ventilation ages show no significant variations throughout the last deglaciation, indicating that changes in formation rates or differing sources of North Pacific mid-depth waters are not prime candidates for strengthening the OMZ at our site. The age models established by our correlation procedure allow for the determination of calendar age control points for the Bølling–Allerød and the Preboreal that are independent of the initial radiocarbon-based chronology. Resulting surface reservoir ages range within 730–990 yr during the Bølling–Allerød, 800–1100 yr in the Younger Dryas, and 765–775 yr for the Preboreal.