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  • FT-ICR MS  (1)
  • Major ion chemistry  (1)
  • American Geophysical Union  (2)
  • Copernicus Publications on behalf of the European Geosciences Union
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Publisher
  • American Geophysical Union  (2)
  • Copernicus Publications on behalf of the European Geosciences Union
Years
  • 1
    Publication Date: 2022-05-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(6), (2021): e2021GB006938, https://doi.org/10.1029/2021GB006938.
    Description: As climate-driven El Niño Southern Oscillation (ENSO) events are projected to increase in frequency and severity, much attention has focused on impacts regarding ecosystem productivity and carbon balance in Amazonian rainforests, with comparatively little attention given to carbon dynamics in fluvial ecosystems. In this study, we compared the wet 2012 La Niña period to the following normal hydrologic period in the Amazon River. Elevated water flux during the La Niña period was accompanied by dilution of inorganic ion concentrations. Furthermore, the La Niña period exported 2.77 Tg C yr−1 more dissolved organic carbon (DOC) than the normal period, an increase greater than the annual amount of DOC exported by the Mississippi River. Using ultra-high-resolution mass spectrometry, we detected both intra- and interannual differences in dissolved organic matter (DOM) composition, revealing that DOM exported during the dry season and the normal period was more aliphatic, whereas compounds in the wet season and following the La Niña event were more aromatic, with ramifications for its environmental role. Furthermore, as this study has the highest temporal resolution DOM compositional data for the Amazon River to-date we showed that compounds were highly correlated to a 6-month lag in Pacific temperature and pressure anomalies, suggesting that ENSO events could impact DOM composition exported to the Atlantic Ocean. Therefore, as ENSO events increase in frequency and severity into the future it seems likely that there will be downstream consequences for the fate of Amazon Basin-derived DOM concurrent with lag periods as described here.
    Description: This work was partially supported by National Science Foundation grant OCE-1464396 to Robert G. M. Spencer and funding from the Harbourton Foundation to Robert G. M. Spencer, R. Max Holmes, and Bernhard Peucker-Ehrenbrink.
    Description: 2021-12-11
    Keywords: Amazon river ; carbon cycling ; dissolved organic carbon ; dissolved organic matter ; ENSO ; FT-ICR MS
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005414, doi:10.1029/2019JG005414.
    Description: A survey of 25 coastal‐draining rivers across the Canadian Arctic Archipelago (CAA) shows that these systems are distinct from the largest Arctic rivers that drain watersheds extending far south of the Arctic circle. Observations collected from 2014 to 2016 illustrate the influences of seasonal hydrology, bedrock geology, and landscape physiography on each river's inorganic geochemical characteristics. Summertime data show the impact of coincident gradients in lake cover and surficial geology on river geochemical signatures. In the north and central CAA, drainage basins are generally smaller, underlain by sedimentary bedrock, and their hydrology is driven by seasonal precipitation pulses that undergo little modification before they enter the coastal ocean. In the southern CAA, a high density of lakes stores water longer within the terrestrial system, permitting more modification of water isotope and geochemical characteristics. Annual time‐series observations from two CAA rivers reveal that their concentration‐discharge relationships differ compared with those of the largest Arctic rivers, suggesting that future projections of dissolved ion fluxes from CAA rivers to the Arctic Ocean may not be reliably made based on compositions of the largest Arctic rivers alone, and that rivers draining the CAA region will likely follow different trajectories of change under a warming climate. Understanding how these small, coastal‐draining river systems will respond to climate change is essential to fully evaluate the impact of changing freshwater inputs to the Arctic marine system.
    Description: This work was only possible through a network of enthusiastic and devoted collaborators. Partners included Polar Knowledge Canada and the Canadian High Arctic Research Station, the Arctic Research Foundation, the Kugluktuk Angoniatit Association, and the Canadian Arctic GEOTRACES Program. We acknowledge support from the Department of Fisheries and Oceans Canada, the Woods Hole Oceanographic Institution Coastal Ocean Institute, The G. Unger Vetlesen Foundation, Jane and James Orr, and the Woods Hole Research Center. Many thanks go to Austin Maniyogena, Angulalik Pedersen, Adrian Schimnowski, JS Moore, Les Harris, Oksana Schimnowski, as well as Barbara Adjun, Amanda Dumond, and Johnny Nivingalok, and the captains and crew of the research vessels CCGS Amundsen and R/V Martin Bergmann, all of whom supported our research and helped with sample collection. Special thanks also go to Valier Galy, Zhaohui “Aleck” Wang, Marty Davelaar, Michiyo Yamamoto‐Kawai, Hugh McLean, Mike Dempsey, Baba Pedersen, Maureen Soon, Katherine Hoering, Sean Sylva, Ekaterina Bulygina, and Anya Suslova for their invaluable contributions during field program planning, preparations, and laboratory analyses. Robert Max Holmes is thanked for many fruitful discussions. We also thank several anonymous reviewers for their helpful comments on the paper's content and structure. All of the data presented in this paper can be found at https://doi.org/10.1594/PANGAEA.908497.
    Keywords: Arctic Rivers ; Geochemistry ; Major ion chemistry ; Stable isotopes ; Northern hydrology
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Location Call Number Limitation Availability
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