Note: Front Cover -- The Determination of Organic Peroxides -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- 1. Lipid Peroxides -- 2 . Polymers -- 3 . Petrochemicals -- 4 . Irradiation -- 5. Miscellaneous -- References -- CHAPTER 2 . STRUCTURE AND REACTIVITY -- 1 . Classification of peroxides -- 2 . Reactivity -- References -- CHAPTER 3. IODOMETRIC METHODS -- 1 . General comments -- 2. Choice of solvent -- 3 . Reaction conditions -- 4 . Titration with thiosulphate -- References -- CHAPTER 4 . FERROUS ION METHODS -- 1 . Introduction -- 2 . Choice of reagent -- 3. Choice of solvent -- 4 . Titration with titanous ions -- 5 . Titration with dichromate ions -- 6 . Titration with mercurous ions -- References -- CHAPTER 5. FURTHER TITRIMETRIC REAGENTS -- 1 . Introduction -- 2 . Arsenious methods -- 3 . Stannous methods -- 4 . Titanous methods -- 5 . Titration with anions -- 6. Sulphides and mercaptans -- References -- CHAPTER 6 . COLORIMETRIC METHODS -- 1 . Introduction -- 2 . Ferrous ions -- 3 . Leuco base of methylene blue -- 4 . Iodine -- 5. iV,A^'-Dimethyl-/?-phenylenediamme -- 6. Other colorimetric reagents -- References -- CHAPTER 7 . POLAROGRAPHIC METHODS -- 1 . Introduction -- 2 . Electrode reaction -- 3 . Polarographic teclmiques for peroxides -- 4 . Nature and concentration of peroxide -- 5 . Solvents and supporting electrolytes -- References -- CHAPTER 8. SPECTROSCOPIC TECHNIQUES -- 1 . Introduction -- 2 . Ultraviolet and visible absorption -- 3 . Infrared absorption -- 4 . Raman spectroscopy -- References -- CHAPTER 9 . CHROMATOGRAPHIC METHODS A. COLUMN CHROMATOGRAPHY -- 1 . Introduction -- 2 . Column techniques -- 3 . Solvent medium -- 4 . Stationary phase -- 5 . Type of peroxide -- References -- CHAPTER 10 . CHROMATOGRAPHIC METHODS B. PAPER CHROMATOGRAPHY -- 1 . Introduction -- 2 . Choice of paper. , 3. Mobile phase -- 4 . General techniques -- 5 . Chemical structure -- 6 . Detection -- 7 . Class of peroxide -- References -- CHAPTER 11 . CHROMATOGRAPHIC METHODS C. THIN-LAYER CHROMATOGRAPHY -- 1 . Introduction -- 2 . Adsorbents -- 3 . Solvent systems -- 4. Detection -- 5. Techniques -- 6. Applications -- References -- CHAPTER 12. CHROMATOGRAPHIC METHODS D. GAS CHROMATOGRAPHY -- 1. Introduction -- 2. Solid support -- 3. Stationary phase -- 4. Column temperature -- 5. Functional groups -- 6. Quantitative analysis -- References -- CHAPTER 13. CHOICE OF METHOD -- 1. Introduction -- 2. Concentration of peroxide -- 3. Reactivity of peroxide -- 4. Nature of the sample -- INDEX.

Note: Front Cover -- The Determination of Epoxide Groups -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- 1. General considerations -- 2. The determination of epoxide groups -- 3. Analytical methods -- References -- CHAPTER 2. METHODS INVOLVING EPOXIDE RING-OPENING BY HALOGEN ACIDS -- INTRODUCTION -- 1. Procedures considered -- 2. General comments -- 3. Interference effects -- 4. Convenience of the various procedures -- 5. Accuracy -- 6. Conclusions -- References -- CHAPTER 3. OTHER METHODS FOR EPOXIDE DETERMINATION -- INTRODUCTION -- 1. Methods considered -- 2. General comments -- References -- CHAPTER 4. CONCLUSIONS -- Chemical methods -- Physical methods -- Very sensitive methods -- Final comments -- INDEX.

Note: Front Cover -- The Determination of Carboxylic Functional Groups -- Copyright Page -- Table of Contents -- Preface -- CHAPTER 1. INTRODUCTION -- CHAPTER 2. THE DETERMINATION OF CARBOXYLIC ACIDS -- 1. GENERAL -- 2. ACID-BASE EQUILIBRIUM IN WATER -- 3 . ACID-BASE EQUILIBRIUM IN NON-AQUEOUS MEDIA -- 4 . TITRIMETRIC DETERMINATION OF ACIDS -- 5. SPECTROPHOTOMETRIC METHODS -- 6. CHROMATOGRAPHIC METHODS -- 7. COUNTERCURRENT SEPARATION OF ORGANIC ACIDS -- 8. ELECTROPHORETIC SEPARATION OF ORGANIC ACIDS -- 9 . POLAROGRAPHY OF ORGANIC ACIDS -- 10. SOME OTHER CHEMICAL METHODS -- REFERENCES -- CHAPTER 3. THE DETERMINATION OF ACID ANHYDRIDES AND ACID CHLORIDES -- A. ACID ANHYDRIDES -- B. ACID CHLORIDES -- REFERENCES -- CHAPTER 4. THE DETERMINATION OF ESTERS -- 1. GENERAL -- 2. SAPONIFICATION METHODS -- 3 . SOME SPECIFIC METHODS -- 4. SPECTROSCOPIC METHODS -- 5. CHROMATOGRAPHY OF ESTERS -- 6 . SOME OTHER PHYSICAL METHODS -- 7. DETERMINATION OF LACTONES -- REFERENCES -- CHAPTER 5. DETERMINATION OF AMIDES -- 1. GENERAL -- 2. GENERAL METHODS -- 3 . USE OF GRIGNARD'S REAGENT -- 4. SPECIFIC METHODS FOR PRIMARY AMIDES -- REFERENCES -- CHAPTER 6. THE ANALYSIS OF BINARY AND TERNARY MIXTURES -- 1. GENERAL -- 2. DIFFERENTIATION OF ACIDS -- 3. MIXTURES OF ACIDS AND ANHYDRIDES -- 4. MIXTURES OF ACIDS AND ACID CHLORIDES -- 5. MIXTURES OF ACIDS AND ESTERS -- 6. MIXTURES OF ACIDS AND AMIDES -- REFERENCES -- INDEX.

Note: Front Cover -- Analytical Methods for Organic Cyano Groups -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- References -- PART A: CHEMICAL METHODS -- GENERAL INTRODUCTION -- CHAPTER 2. REACTIONS OF (ADDITION TO) THE CYANO GROUP -- Introduction -- 1. Reduction: -CN-CH2-NH2 -- 2. Hydrolysis -- 3. Addition of Hydrogen Sulphide -- 4. Addition of Alcohols -- 5. Addition of Ammonia -- 6. Addition of Hydroxylamine -- 7. Addition of Hydrazine -- 8. Addition of Mercaptans -- 9. Addition of Polyphenols -- 10. Addition of Grignard Reagent -- 11. Preparation of N-(2-Chloroalkyl) amides -- 12. Formation of Metal Complexes -- References -- CHAPTER 3. REACTIONS OF GROUPS ACTIVATED BY THE CYANO GROUP -- Introduction -- 1. α,β-Unsaturated Nitriles -- 2. Compounds Containing the - CH2CN or =CHCN Group -- 3. Compounds Containing the - NH - or NH2 Group Attached to -CN -- References -- CHAPTER 4. REACTIONS OF GROUPS SENSIBLY UNAFFECTED BY THE CYANO GROUP -- 1. Higher Aliphatic Nitriles -- 2.β,γ-Unsaturated Nitriles -- 3. Aromatic Groups in Nitriles -- 4. Halogen Atoms in Trichloroacetonitrile -- 5. Azo Group in Azobisisobutyronitrile -- 6. Hydrazo Group in 2,2'-Hydrazobisisobutyronitrile -- 7. Ester Group in Nitriles -- 8. Amino Groups (not Directly Linked to a Cyano Group) -- 9. Amidino or Guanidino Group in Dicyanodiamide -- 10. Cobalt in Vitamin B12 (Cyanocobalamin) -- 11. 5,6-Dimethylbenzimidazole in Vitamin B12 -- References -- CHAPTER 5. DEGRADATION REACTIONS DURING WHICH THE CYANO GROUP REMAINS INTACT -- Introduction -- 1. Pyrolysis without Added Reagent -- 2. Pyrolysis in Presence of Oxidising Agents -- 3. Pyrolysis in Presence of a Base -- 4. Reductive Fission of N-cyano Compounds -- 5. Hydrolytic Fission of Cyanohydrins -- 6. Formation of Bromine Cyanide, BrCN. , 7. Elimination of the Cyano Group in the Analytical Methods for Ethyl Dimethylphosphoramidocyanidate (Tabun) -- 8. Elimination of the Cyano Group as Hydrocyanic Acid in Determination of Vitamin B12 -- 9. Formation of Thiocyanic Acid by Reaction with Sulphur -- References -- CHAPTER 6. DEGRADATION REACTIONS INVOLVING DESTRUCTION OF THE CYANO GROUP -- References -- CHAPTER 7. MISCELLANEOUS CHEMICAL METHODS -- References -- PART B: PHYSICAL METHODS -- GENERAL INTRODUCTION -- CHAPTER 8. SPECTROSCOPIC AND SPECTROPHOTOMETRIC METHODS -- 1. Infrared -- 2. Ultraviolet and Visible -- 3. Mass Spectrometry -- 4. Flame Spectroscopy -- 5. Nuclear Magnetic Resonance -- References -- CHAPTER 9. CHROMATOGRAPHIC METHODS -- 1. Gas Chromatography -- 2. Other Chromatographic Methods, Principally PC and TLC -- References -- CHAPTER 10. ION EXCHANGE -- References -- CHAPTER 11. POLAROGRAPHY -- References -- CHAPTER 12. AZEOTROPIC DISTILLATION -- References -- AUTHOR INDEX -- SUBJECT INDEX.

Note: Front Cover -- Periodate Oxidation of Diol and Other Functional Groups: Analytical and Structural Applications -- Copyright Page -- Table of Contents -- PREFACE -- INTRODUCTION -- CHAPTER 1. HISTORY -- Literature Cited -- CHAPTER 2. PREPARATION AND PROPERTIES OF PERIODATES -- Preparation -- Solubility -- Stability of Aqueous Solutions -- Standard Potentials -- Ionization of Periodic Acid -- Structure of Periodates -- Literature Cited -- CHAPTER 3. MECHANISM OF PERIOD ATE OXIDATION -- 1,2-Diols -- 1,2-Hydroxycarbonyl Compounds and 1,2-Diketones -- 1,2-Aminoalcohols -- Active Méthylène Groups -- Literature Cited -- CHAPTER 4. ANOMALOUS PERIODATE OXIDATIONS -- Overoxidation -- Sulfur-containing Compounds -- Phenols -- Flavanols -- Amines -- Amino Acids -- Unsaturated Sugars -- Amino Sugars -- Proteins -- Oxidations at Elevated Temperature -- Oxidations in the Presence of Light -- Literature Cited -- CHAPTER 5. PERIODATE OXIDATION IN STRUCTURAL STUDIES -- Structure Assignment based on Periodate Oxidation Information -- Structure Assignment based on Periodate Oxidation and Other Information -- Structure and End-group Assay of Polysaccharides -- Nature of the Product of Periodate Oxidation -- Literature Cited -- CHAPTER 6. ANALYTICAL METHODS -- Conditions of the Oxidation -- Determination of Oxidant Consumption -- Other Methods for Periodate Determination -- Determination of Acid Produced -- Determination of Other Acids -- Determination of Formaldehyde -- Determination of Acetaldehyde -- Determination of Ammonia and Amines -- Determination of Carbon Dioxide -- Recommended General Methods -- Conclusions -- Literature Cited -- CHAPTER 7. SYNTHETIC AND OTHER APPLICATIONS OF PERIODATE OXIDATIONS -- Literature Cited -- AUTHOR INDEX -- SUBJECT INDEX.

Note: Front Cover -- The Determination of Hydrazino-Hydrazide Groups -- Copyright Page -- Table of Contents -- Dedication -- PREFACE -- GENERAL INTRODUCTION -- CHAPTER 1. OXIDATION METHODS -- 1. Use of Bromate -- 2. Use of Bromine -- 3. Use of N-Bromosuccinimide -- 4. Use of Ceric Sulfate -- 5. Use of Ceric Sulfate-Iodine Monochloride -- 6. Use of Diethylenetetraammonium Ceric Sulfate -- 7. Use of Chloramine-T -- 8. Use of Chloramine-T-Iodine Monochloride -- 9. Use of Chloramine-B -- 10. Use of Chloramine-B-Iodine Monochloride -- 11. Use of Copper Oxide -- 12. Use of Copper Oxide-Fehling's Solution -- 13. Use of Copper Sulfate -- 14. Use of Dichromate -- 15. Use of Potassium Ferricyanide-Ascorbic Acid -- 16. Use of Ferricyanide-Ceric Sulfate -- 17. Use of Ferricyanide-Zinc Sulfate -- 18. Use of Hypochlorous Acid -- 19. Use of Hypochlorite -- 20. Use of lodic Acid -- 21. Use of Iodine -- 22. Use of Iodate -- 23. Use of Periodate -- 24. Use of Periodate-Iodine Bromide -- 25· Use of Periodate-Iodine Cyanide -- 26. Use of Permanganate -- 27. Use of Selenious Acid -- 28. Use of Thallium -- 29. Use of Vanadic Acid -- References -- CHAPTER 2. GASOMETRIC METHODS -- 1. Use of Bromate -- 2. Use of Bromine-Hypobromite -- 3. Use of Cupric-Fehling's Solution -- 4. Use of Cupric Sulfate -- 5. Use of Ferricyanide -- 6. Use of Iodate -- 7. Use of Lead Oxide -- 8. Use of Mercuric Chloride -- References -- CHAPTER 3. COLORIMETRIC AND SPECTROPHOTOMETRIC METHODS -- 1. Determination of Isonicotinic Acid Hydrazide (INH) -- 2. Determination of Maleic Hydrazide -- 3. Determination of Hydrazine -- 4. Determination of Hydrazine and Benzylhydrazine -- 5. Determination of 1,1-Dimethylhydrazine (UDMH) -- 6. Determination of Monomethylhydrazine -- References -- CHAPTER 4. CHROMATOGRAPHIC METHODS -- 1. Ion Exchange Chromatography -- 2. Paper Chromatography. , 3. Thin Layer Chromatography -- References -- CHAPTER 5. COULOMETRIC METHODS -- 1. Determination of Hydrazine and Substituted Hydrazines -- References -- CHAPTER 6. POLAROGRAPHIC METHODS -- 1. Determination of Hydrazine, Phenylhydrazine, and Semicarbazide -- 2. Determination of Isonicotinic Acid Hydrazide -- 3. Determination of p,p-Oxybis (Benzenesulfonyl) Hydrazide -- References -- CHAPTER 7. ACID-BASE METHODS -- 1. Aqueous Methods -- 2. Non-aqueous Methods -- References -- CHAPTER 8. THE ANALYSIS OF MIXTURES -- 1. Hydrazine-l,l-Dimethylhydrazine Mixtures -- 2. Hydrazine-Monomethylhydrazine Mixtures -- 3. Hydrazine-1,1-Dimethylhydrazine and Monomethylhydrazine-1,1-Dimethylhydrazine Mixtures -- 4. Hydrazine-Monomethylhydrazine-I,I- Dimethylhydrazine Mixtures -- 5. Hydrazine-Aniline Mixtures -- 6. Hydrazine-Ammonia Mixtures -- 7. Hydrazine-Ammoida-Hydrogen-Nitrogen-Argon Mixtures -- 8. Hydrazine-Hydroxylamine Mixtures -- 9. Hydrazine-Ammonium Hydroxide-Hydroxylamine Mixtures -- 10. Hydrazine-Hydrazine Nitrate Mixtures -- 11. Determination of Diethylenetriamine (DETA) with either Hydrazine, Monomethylhydrazine, or 1,1-Dimethylhydrazine -- References -- CHAPTER 9. OTHER QUALITATIVE AND QUANTITATIVE TESTS -- 1. Spot Tests -- 2. Microbiological Tests -- 3. Field Tests -- References -- CHAPTER 10. THE USE OF HYDRAZINES AS ANALYTICAL REAGENTS -- 1. Use of 1,1-Dimethylhydrazine -- 2. Use of 2,4-Dinitrophenylhydrazine -- 3. Use of 1,5-Diphenylcarbazide -- 4. Use of Hydrazine -- 5. Use of 2-Hydrazinobenzothiazole -- 6. Use of Isonicotinic Acid Hydrazide -- 7. Use of Oxalyldihydrazide -- 8. Use of Phenylhydrazine -- 9. Use of Salicyloylhydrazide -- 10. Use of Semicarbazide -- References -- AUTHOR INDEX -- SUBJECT INDEX -- OTHER TITLES IN THE SERIES IN ORGANIC FUNCTIONAL GROUP ANALYSIS.