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  • 1
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The chemical composition of snowmelt, groundwater, and streamwater was monitored during the spring of 1991 and 1992 in a 200-ha subalpine catchment on the western flank of the Rocky Mountains near Steamboat Springs, Colorado. Most of the snowmelt occurred during a one-month period annually that began in mid-May 1991 and mid-April 1992. The average water quality characteristics of individual sampling sites (meltwater, streamwater, and groundwater) were similar in 1991 and 1992. The major ions in meltwater were differentially eluted from the snowpack, and meltwater was dominated by Ca2+, SO 4 2− , and NO 3 − . Groundwater and streamwater were dominated by weathering products, including Ca2+, HCO 3 − (measured as alkalinity), and SiO2, and their concentrations decreased as snowmelt progressed. One well had extremely high NO 3 − . concentrations, which were balanced by Ca2+ concentrations. For this well, hydrogen ion was hypothesized to be generated from nitrification in overlying soils, and subsequently exchanged with other cations, particularly Ca2+. Solute concentrations in streamwater also decreased as snowmelt progressed. Variations in groundwater levels and solute concentrations indicate that most of the meltwater traveled through the surficial materials. A mass balance for 1992 indicated that the watershed retained H+, NH 4 + , NO 3 − , SO 4 2− and Cl− and was the primary source of base cations and other weathering products. Proportionally more SO 4 2− was deposited with the unusually high summer rainfall in 1992 compared to that released from snowmelt, whereas NO 3 − was higher in snowmelt and Cl− was the same. The sum of snowmelt and rainfall could account for greater than 90% of the H+ and NH 4 + retained by the watershed and greater than 50% of the NO 3 − .
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 105 (1998), S. 263-275 
    ISSN: 1573-2932
    Keywords: chloride ; hydrograph separation ; Panola Mountain Research Watershed ; streamflow ; tracer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract An analysis of chloride (Cl-) concentrations and fluxes at the 41 ha Panola Mountain Research Watershed indicates that Cl- may be used effectively to differentiate "new" and "old" water flow through the hillslope and their respective contributions to streamwater. Rainfall and throughfall, the "new" water inputs, are marked by low Cl- concentrations (〈15 µeq L-1). Stormwater moves rapidly to depth along preferred pathways in a deciduous forest hillslope, as evidenced by low Cl- concentrations (〈20 µeq L-1) in mobile soil water from zero-tension stainless-steel pan lysimeters. "Old" waters, matrix soil waters and groundwater, typically have high Cl- concentrations (〉30 µeq L-1). Timing of soil water transport is not sufficiently rapid to suggest that soil water from this hillslope site (20 m from the stream) contributes to streamwater during individual rainstorms. The source of streamflow, therefore, must be a combination of channel interception, overland flow and soil water from near-channel areas, and runoff from a 3 ha bedrock outcrop in the headwaters. Groundwater contribution to streamflow was estimated using Cl- concentrations of throughfall and groundwater as the two end members for a two-component hydrograph separation. For the study period, groundwater contributed 79% of the streamflow and from 1985 to 1995, contributed 75% of the streamflow. Rainfall was the source of 45% of the Cl- flux from the watershed in the long term; the remaining Cl- is hypothesized to be derived from dry deposition, consistent with the enrichment noted for throughfall. At peak flow during individual rainstorms, "new" water can contribute 95% of the runoff.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 91 (1996), S. 283-298 
    ISSN: 1573-2932
    Keywords: dry deposition ; charge density ; chloride ; colorimetry ; ion balance ; ion chromatography ; recycling ; watershed budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Colorimetric Cl− data from natural solutions that contain dissolved organic carbon (DOC) may be biased high. We evaluated aquatic Cl- concentrations in ecosystem compartments at the Bear Brook Watershed, Maine, and from lakes in Maine, using ion chromatography and colorimetry. DOC imparts a positive interference on colorimetric Cl− results proportional to DOC concentrations at approximately 0.8 µeq Cl−/L per mg DOC/L. The interference is not a function of Cl− concentration. The resulting bias in concentrations of Cl− may be 50% or more of typical environmental values for Cl− in areas remote from atmospheric deposition of marine aerosols. Such biased data in the literature appear to have led to spurious conclusions about recycling of Cl− by forests, the usefulness of Cl− as a conservative tracer in watershed studies, and calculations of elemental budgets, ion balance, charge density of DOC, and dry deposition factors.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-2932
    Keywords: atmospheric deposition ; coniferous ; deciduous ; dendrochemistry ; dry deposition ; foliage ; loblolly pine ; precipitation ; stemflow ; sulfur ; sulfur dioxide ; throughfall
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Atmospheric deposition and above-ground cycling of sulfur (S) were evaluated in adjacent deciduous and coniferous forests at the Panola Mountain Research Watershed (PMRW), Georgia, U.S.A. Total atmospheric S deposition (wet plus dry) was 12.9 and 12.7 kg ha-1 yr-1 for the deciduous and coniferous forests, respectively, from October 1987 through November 1989. Dry deposition contributes more than 40% to the total atmospheric S deposition, and SO2 is the major source (∼55%) of total dry S deposition. Dry deposition to these canopies is similar to regional estimates suggesting that 60-km proximity to emission sources does not noticeably impact dry deposition at PMRW. Below-canopy S fluxes (throughfall plus stemflow) in each forest are 37% higher annually in the deciduous forest than in the coniferous forest. An excess in below-canopy S flux in the deciduous forest is attributed to leaching and higher dry deposition than in the coniferous forest. Total S deposition to the forest floor by throughfall, stemflow and litterfall was 2.4 and 2.8 times higher in the deciduous and coniferous forests, respectively, than annual S growth requirement for foliage and wood. Although S deposition exceeds growth requirement, more than 95% of the total atmospheric S deposition was retained by the watershed in 1988 and 1989. The S retention at PMRW is primarily due to SO4 2- adsorption by iron oxides and hydroxides in watershed soils. The S content in white oak and loblolly pine boles have increased more than 200% in the last 20 yr, possibly reflecting increases in emissions.
    Type of Medium: Electronic Resource
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