Description: The recovery of natural gas from CH4-hydrate deposits in sub-marine and sub-permafrost environments through injection of CO2 is considered a suitable strategy towards emission-neutral energy production. This study shows that the injection of hot, supercritical CO2 is particularly promising. The addition of heat triggers the dissociation of CH4-hydrate while the CO2, once thermally equilibrated, reacts with the pore water and is retained in the reservoir as immobile CO2-hydrate. Furthermore, optimal reservoir conditions of pressure and temperature are constrained. Experiments were conducted in a high-pressure flow-through reactor at different sediment temperatures (2 °C, 8 °C, 10 °C) and hydrostatic pressures (8 MPa, 13 MPa). The efficiency of both, CH4 production and CO2 retention is best at 8 °C, 13 MPa. Here, both CO2- and CH4-hydrate as well as mixed hydrates can form. At 2 °C, the production process was less effective due to congestion of transport pathways through the sediment by rapidly forming CO2-hydrate. In contrast, at 10 °C CH4 production suffered from local increases in permeability and fast breakthrough of the injection fluid, thereby confining the accessibility to the CH4 pool to only the most prominent fluid channels. Mass and volume balancing of the collected gas and fluid stream identified gas mobilization as equally important process parameter in addition to the rates of methane hydrate dissociation and hydrate conversion. Thus, the combination of heat supply and CO2 injection in one supercritical phase helps to overcome the mass transfer limitations usually observed in experiments with cold liquid or gaseous CO2.

Description: The accumulation of methane hydrate in marine sediments is controlled by a number of physical and biogeochemical parameters including the thickness of the gas hydrate stability zone (GHSZ), the solubility of methane in pore fluids, the accumulation of particulate organic carbon at the seafloor, the kinetics of microbial organic matter degradation and methane generation in marine sediments, sediment compaction and the ascent of deep-seated pore fluids and methane gas into the GHSZ. Our present knowledge on these controlling factors is discussed and new estimates of global sediment and methane fluxes are provided applying a transport-reaction model at global scale. The modeling and the data evaluation yield improved and better constrained estimates of the global pore volume within the modern GHSZ ( ≥ 44 × 1015 m3), the Holocene POC accumulation rate at the seabed (~1.4 × 1014 g yr−1), the global rate of microbial methane production in the deep biosphere (4−25 × 1012 g C yr−1) and the inventory of methane hydrates in marine sediments ( ≥ 455 Gt of methane-bound carbon).

Description: Cruise MSM34 of R/V MARIA S. MERIAN aimed to investigate a possible test site location for the German SUGAR project. The well sealed gas hydrate deposit should be accessible by the mobile drilling device MeBo 200. During the two legs of cruise MSM34 of R/V MARIA S. MERIAN regional 2D seismic surveying, high resolution 2D and 3D seismic imaging, geo-chemical sampling, heatflow measurements and long-term piezometer installations were undertaken. A grid of 28 2D seismic profiles was collected across the palaeo Danube delta. A number of inactive and partly buried channel systems could be mapped. Most of them were underlain by one or more bottom simulation reflectors (BSR) indicating the existence of gas hydrates. Based on the seismic brute stack images and the limits of the MeBo drilling device a prospective channel system with indications for possible gas hydrate formation at shallow depth (BSR, inverted strong amplitudes) could be identified in about 1500 m water depth. High resolution 2D seismic and 3D P-Cable seismic were used together with OBS deployments in order to allow structural mapping and physical description of the channel infill. Heatflow measurements and geochemical analyses of gravity and multi corer samples accompany these investigations. Neither the multibeam water column images nor Parasound records show any evidence of flares (gas bubbles in the water column) in this working area suggesting a well sealed hydrate reservoir. Active gas expulsion from the seafloor was observed at about 200 m water depth circling around a slump area. The base plane of the failed sediment volume builds the current seafloor at about 600 m to 700 m water depth. On regional 2D seismic profiles a BSR has been mapped underneath the slope failure with unexpectedly strong upward bending. High resolution 2D and 3D P-Cable seismic investigations with complementary OBS deployment will allow imaging the BSR outline. Moreover velocity analyses, heatflow measurements and geo-chemical samples will be available for a detailed description of hydrate distribution and sediment parameters. In a third working area high resolution 2D seismic reflection profiles were acquired across a fully buried channel system. Together with the regional seismic lines slope failure of the channel fill material can be studied across the slope extension of the system. In summary cruise MSM34 achieved all proposed aims. Based on new regional seismic acquisition two working areas were selected for 3D high resolution studies. Investigations of a promising location for a SUGAR pilot site will be supported by a test location for slope stability and analyses of fluid migration pathways in a buried canyon site.