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  • 11
    Publication Date: 2019-07-17
    Description: Although commonly reported in marine and freshwater environments, little is known about the biological sources of long chain alkyl 1,13- and 1,15-diols, and factors controlling their distributions. Here we analyzed the occurrence and distribution of these lipids in a comprehensive set of marine surface sediments and compare their distributions with environmental conditions like sea surface temperature (SST), salinity and nutrient concentrations. Fractional abundances of the C28 1,13-, C30 1,13- and C30 1,15-diols show a strong correlation with SST and based on these results, we propose the Long chain Diol Index (LDI), which expresses the C30 1,15-diol abundance relative to those of C28 1,13-, C30 1,13- and C30 1,15-diols. The LDI shows a strong linear correlation with SST (LDI = 0.033 � SST + 0.095; R2 = 0.969, n = 162) over a temperature range of �3 to 27 �C. Long chain diol distributions in sediments from the South Atlantic close to the Congo River outflow (West Africa) provided a 43 kyr LDI SST record. This record reflects several known climatic events and shows similarities with an alkenone- derived SST record obtained using the same suite of sediments, both in trend and in terms of absolute SST. This confirms the potential of the LDI as a proxy for palaeo-SST reconstruction.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 12
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    Pergamon-Elsevier
    In:  EPIC3Deep Sea Research Part I: Oceanographic Research Papers, Pergamon-Elsevier, 88, pp. 17-29, ISSN: 0967-0637
    Publication Date: 2014-06-25
    Description: In this study we reconstruct sea surface temperatures (SSTs) using two lipid-based biomarker proxies (alkenone unsaturation index View the MathML sourceU37K′ and TEX86 index based on glycerol dibiphytanyl glycerol tetraethers) in 36 surface sediment samples from the Indonesian continental margin off west Sumatra and south of Java and the Lesser Sunda Islands. Comparison of measured temperatures (World Ocean Atlas 09) to reconstructed temperatures suggests that SST estimates based on View the MathML sourceU37K′ reflect the SE monsoon SST in the upwelling area south of Java and the Lesser Sunda Islands. Estimates based on TEX86 using the calibration for temperatures 〉20 °C (View the MathML sourceTEX86H) are up to 2 °C lower than View the MathML sourceU37K′-based SSTs. This offset is possibly related to either one or a combination of two factors: (i) the depth habitats of the source organisms and (ii) different seasonal production and/or seasonality of export associated with phytoplankton blooming triggered by primary productivity. In the non-upwelling area off west Sumatra, the alkenone-based SSTs are cooler than measured temperatures during the entire year, likely reflecting the limitations of the View the MathML sourceU37K′ proxy beyond 28 °C, while reconstructed temperatures based on View the MathML sourceTEX86H are consistent with mean annual SST.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 13
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 19 (2004): PA4029, doi:10.1029/2003PA000892.
    Description: We compare a new mid-Pleistocene sea surface temperature (SST) record from the eastern tropical Atlantic to changes in continental ice volume, orbital insolation, Atlantic deepwater ventilation, and Southern Ocean front positions to resolve forcing mechanisms of tropical Atlantic SST during the mid-Pleistocene transition (MPT). At the onset of the MPT, a strong tropical cooling occurred. The change from a obliquity- to a eccentricity-dominated cyclicity in the tropical SST took place at about 650 kyr BP. In orbital cycles, tropical SST changes significantly preceded continental ice-volume changes but were in phase with movements of Southern Ocean fronts. After the onset of large-amplitude 100-kyr variations, additional late glacial warming in the eastern tropical Atlantic was caused by enhanced return flow of warm waters from the western Atlantic driven by strong trade winds. Pronounced 80-kyr variations in tropical SST occurred during the MPT, in phase with and likely directly forced by transitional continental ice-volume variations. During the MPT, a prominent anomalous long-term tropical warming occurred, likely generated by extremely northward displaced Southern Ocean fronts. While the overall pattern of global climate variability during the MPT was determined by changes in mean state and frequency of continental ice volume variations, tropical Atlantic SST variations were primarily driven by early changes in Subantarctic sea-ice extent and coupled Southern Ocean frontal positions.
    Description: The Dutch scientific funding organization (NWO) is thanked for financial support (project 75019617).
    Keywords: Sea surface temperatures ; Mid-Pleistocene transition ; Tropical Atlantic
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 14
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA1019, doi:10.1029/2005PA001134.
    Keywords: Sea-surface temperatures ; Mid-Pleistocene transition ; Tropical Atlantic
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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