Description: Remotely Operated Vehicles (ROVs) have proven to be highly effective in recovering well localized samples and observations from the seafloor. In the course of ROV deployments, however, huge amounts of video and photographic data are gathered which present tremendous potential for data mining. We present a new workflow based on industrial software to derive fundamental field geology information such as quantitative stratigraphy and tectonic structures from ROV-based photo and video material. We demonstrate proof of principle tests for this workflow on video data collected during dives with the ROV Kiel6000 on a new hot spot volcanic field that was recently identified southwest of the island of Santo Antão in the Cape Verdes. Our workflow allows us to derive three-dimensional models of outcrops facilitating quantitative measurements of joint orientation, bedding structure, grain size comparison and photo mosaicking within a georeferenced framework. The compiled data facilitate volcanological and tectonic interpretations from hand specimen to outcrop scales based on the quantified optical data. The demonstrated procedure is readily replicable and opens up possibilities for post-cruise “virtual fieldwork” on the seafloor.

Description: During IODP NanTroSEIZE Expedition 322, four packages of tuffaceous sandstones (TST 1, 2, 3a, 3b) were recovered within a moderately lithified and bioturbated silty claystone succession in the Late Miocene (〉 7.6 to ~ 9.1 Ma) upper part of the middle Shikoku Basin deposits. To assess the emplacement processes of the tuffaceous sandstones we investigate modal and geochemical compositions of 24 thin sections that reveal systematic vertical changes within each bed. TST 1, 2 and 3b are single beds whereas TST 3a is composed of at least two beds suggesting several rapidly succeeding sedimentation events. The beds are density-graded such that low-density pyroclasts including pumice lapilli are enriched at the top whereas dense lithic components and minerals are enriched at the bottom. The volcanic glass particles (pumice and shards) that are the dominant modal constituents of each sandstone bed have homogeneous geochemical compositions in each bed. Moreover, TST 1, 2, and 3a glass compositions overlap completely but TST 3b glass has a different composition, as is analogously observed for the mineral compositions. This unique multistage approach of sedimentological and geochemical methods facilitated the detailed investigation of distal volcano-derived, probably tsunamogenic, turbidites in order to contribute to the distinction between primary and secondary induced mass flows. We interpret that all tuffaceous sandstones were emplaced by turbidity currents that were formed during major explosive volcanic eruptions. However, while TST 1, 2, and 3a turbidity currents formed by the entry into the ocean of voluminous pyroclastic flows erupted at a volcano on mainland Japan, TST 3b was emplaced by a turbidity current formed by a shallow submarine or subaerial volcanic eruption at the Izu–Bonin arc where it collided with Japan. These results regarding distal turbidites encourage the revisiting of older marine deposits in the scope of hazard evaluation through past events, especially in regions near to volcanic sources.

Description: Atmospheric deposition of volcanic ash has recently been recognized as an important nutrient source into the surface ocean. Mount Etna (Italy), one of the world's most active volcanoes, is located in the oligotrophic Mediterranean Sea (MedSea). Despite the active volcanism on Mount Etna, the biogeochemical impacts of volcanic ash fallouts on the marine primary productivity (MPP) remain largely unknown. Here we present the results of seawater nutrient release experiments with volcanic ash samples from Mount Etna that have been collected during different eruptive episodes between 2001 and 2007. Our results show that volcanic ash from Mount Etna releases significant amounts of fixed-N (35-855 nmol/g), P (7-970 nmol/g), Si (3-2060 nmol/g), Fe (10-130 nmol/g) and Zn (〈21 nmol/g). We further estimated an example representative of ash-fall from Etna based on the case-study focusing on 4-5 November 2002 activity, by using the general relation between the thicknesses of the ash deposits and the ash depositional areas. Etna explosive eruptions can transport volcanic ash as far as 800 km, with ash emissions exceeding the particle flux during dust storm events (of 10 g/m(2) input) as far as 400 km downwind from the volcano. Our results emphasize that Etna ash can provide a significant supply of nutrients, which can favor the MPP in the central MedSea

Description: This study focuses on the Carboniferous sediments of the Karawanken Mountains (Austria/Slovenia) to identify possible source areas and their geotectonic setting. Provenance analyses have been applied using petrographical and geochemical approaches what also lead to an evaluation of the used methods. Within the Hochwipfel Formation five stratigraphic related petrofacies groups can be defined using the sandstone component inventory. Homogenous provenance results based on major element and trace element data suggest an active continental margin/continental island arc with probably an intraplate signature. Provenance analyses of light minerals point to source areas with basement rocks (mainly metamorphic), arc material and sedimentary rocks. In combination, the rapid and highly variable change of provenance signatures within the stratigraphic succession of the petrofacies types excludes a single provenance in the western part of the Karawanken Mountains. Additionally, changes in composition of the individual petrofacies groups correlate with the stratigraphy in the eastern part. Varying contents of garnet, chromite, hornblende and epidote, within the sedimentary succession of the Hochwipfel sandstones, can partly be attributed to geodynamical changes in the hinterland. The chemical compositions of garnets, tourmalines, and chromites, confirm the results of both geochemistry and sediment petrography. In a quantitative approach based on petrography we can see an equal mixture of all source areas, whereas quantification with a geochemical approach results in c. 11% of material that can be attributed to a passive continental margin source, 28 to 37% to an active continental margin, c. 44% to a magmatic arc setting and 16 to 19% to an oceanic within-plate source area. The resulting model for the geodynamical setting of the Hochwipfel basin during the Late Palaeozoic can be best explained by a forearc basin in the eastern part and various pull-apart basins in the western part, connected through bypasses, at the continental margin of Gondwana and the Palaeotethys. As an additional outcome this study clarifies, that geochemically derived provenance results, based on bulk-rock and mineral composition, recognize best complex geodynamical settings and a mixture of sources since they incorporate best the provenance significant lithic components. On the other hand it points out that an application of additional petrological approaches does not necessarily lead to further information and an elimination of errors but could be essential to define general information of the investigated stratigraphy, like the correlation of deposits with stratigraphy (petrofacies groups).

Description: The dacite to andesite zoned Mateare Tephra is the fallout of a predominantly plinian eruption from Chiltepe peninsula at the western shore of Lake Managua that occurred 3000–6000 years ago. It comprises four units: Unit A of high-silica dacite is stratified, ash-rich lapilli fallout generated by unsteady subplinian eruption pulses affected by minor water access to the conduit and conduit blocking by degassed magma. Unit B of less silicic dacite is well sorted, massive pumice lapilli fallout from the main, steady plinian phase of the eruption. Unit C is andesitic fallout that is continuous from unit B except for the rapid change in chemical composition, which had little influence on the ongoing eruption except for a minor transient reduction of the discharge rate and access of water to the conduit. After this, discharge rate re-established to a strong plinian eruption that emplaced the main part of unit C. This was again followed by water access to the conduit which increased through upper unit C. The lithic-rich lapilli to wet ash fallout of unit D is the product of the fully phreatomagmatic terminal phase of the eruption. A massive well-sorted sand layer, the Mateare Sand, replaces laterally variable parts of unit A and lowermost part of unit B in outcrops up to 32 m above present lake level. The corresponding interval missing in the primary fallout can be identified by comparing the composition of pumice entrained in the sand, and pumice from the local base of unit B on top of the sand, with the compositional gradient in undisturbed fallout. The amount of fallout entrained in the sand decreases with distance to the lake. The Mateare Sand occurs at elevations well above beach levels and its widespread continuous distribution defies a fluviatile origin. Instead, it was produced by lake tsunamis triggered by eruption pulses during the initial unsteady phase of activity. Such tsunamis could threaten areas not affected by fallout, and represent a hazard of particular importance in Nicaragua where two large lakes host several explosive volcanoes.

Description: Two volcanic ash layer dominated marine gravity cores were recovered during research cruise RV Sonne 173/3 along the Pacific margin offshore Nicaragua. Thick ash layers dominate the recovered sediments. Pore water samples of these – one incoming plate and one slope site – sediment cores have been analysed for light rare earth elements, alkalinity, sulphate, phosphate, ammonia, calcium, and manganese contents. The data provide a systematic look at changes in REE during diagenesis proceeding from open ocean sediments to highly reducing near-shore sediments. The pore water patterns of all the dissolved species mentioned above suggest that volcanic glass alteration constitutes a major source for REE release in marine sediments when low rates of anaerobic degradation of organic matter, like typical for incoming plate/open ocean sediments, prevail. Under these conditions the release of REE results in fluxes of at least 0.04 nmol La cm− 2 yr− 1 and 0.09 nmol Ce cm− 2 yr− 1.

Description: Volcano edifice volume calculations are presented for 65 volcanoes of the 1400 km long Chilean Southern Volcanic Zone (SVZ) as a basic step in subduction zone mass budgets. Volume calculations are performed in a Geographical Information System that integrates Digital Elevation Models based on of Shuttle Radar Topography Mission as well as ASTER-GDEM topographic data, LANDSAT satellite images and geological maps. The method of volume calculation is straightforward for isolated, morphologically well-defined stratovolcanoes. Uncertainties increase for volcanic edifices that formed on pre-existing rugged terrain, for multi-phase eruptive centers, as well as for eroded edifices. A revised segmentation of the arc is used to describe the spatial volume distribution of extruded magma along the SVZ and to discuss controlling tectonic factors. Peak volumes between arc and back arc are offset by 400 km. The total volcanic extrusion is in the range of 10–13 km3/km/Ma. Major differences between the SVZ and the Central American subduction system are notable with regard to volcano density and maximum volumes.

Description: The stratigraphic succession of widespread tephra layers in west-central Nicaragua was emplaced by highly explosive eruptions from mainly three volcanoes: the Chiltepe volcanic complex and the Masaya and Apoyo calderas. Stratigraphic correlations are based on distinct compositions of tephras. The total tephras combine to a total on-shore volume of about 37 km3 produced during the last ∼ 60 ka. The total erupted magma mass, including also distal volumes, of 184 Gt (DRE) distributes to 84% into 9 dacitic to rhyolitic eruptions and to 16% into 4 basaltic to basaltic–andesitic eruptions. The widely dispersed tephra sheets have up to five times the mass of their parental volcanic edifices and thus represent a significant albeit less obvious component of the arc volcanism. Eruption magnitudes (M = log10(m) − 7 with m the mass in kg), range from M = 4.1 to M = 6.3. Most of the eruptions were dominantly plinian, with eruption columns reaching variably high into the stratosphere, but minor phreatomagmatic phases were also involved. Two phreatomagmatic eruptions, one dacitic and one basaltic–andesitic, produced mostly pyroclastic surges but also fallout from high eruption columns. Comparison of fallout tephra dispersal patterns with present-day, seasonally changing height-dependant wind directions suggests that 8 eruptions occurred during the rainy season while 5 took place during the dry season. The tephra succession documents two major phases of erosion. The first phase, 〉 17 ka ago, appears to be related to tectonic activity whereas the second phase may have been caused by wet climatic conditions between 2 to 6 ka ago. The Apoyo caldera had two large plinian, caldera-forming eruptions in rapid succession about 24 ka ago and should be considered a silicic volcano with long repose times. Three highly explosive basaltic eruptions were generated at the Masaya Caldera within the last 6 ka. Since then frequent but small eruptions and lava effusion were largely limited to the caldera interior. The dacitic Chiltepe volcanic complex experienced six plinian eruptions during the last 17 ka and seems to be an accelerating system in which eruption magnitude increased while the degree of differentiation of erupted magma decreased at the same time. We speculate that the Chiltepe system might produce the next large-magnitude silicic eruption in west-central Nicaragua.

Description: Four volcanic ash-bearing marine sediment cores and one ash-free reference core were examined during research cruise RV Meteor 54/2 offshore Nicaragua and Costa Rica to investigate the chemical composition of pore waters related to volcanic ash alteration. Sediments were composed of terrigenous matter derived from the adjacent continent and contained several distinct ash layers. Biogenic opal and carbonate were only minor components. The terrigenous fraction was mainly composed of smectite and other clay minerals while the pore water composition was strongly affected by the anaerobic degradation of particulate organic matter via microbial sulphate reduction. The alteration of volcanic matter showed only a minor effect on major element concentrations in pore waters. This is in contrast to prior studies based on long sediment cores taken during the DSDP, where deep sediments always showed distinct signs of volcanic ash alteration. The missing signal of ash alteration is probably caused by low reaction rates and the high background concentration of major dissolved ions in the seawater-derived pore fluids. Dissolved silica concentrations were, however, significantly enriched in ash-bearing cores and showed no relation to the low but variable contents of biogenic opal. Hence, the data suggest that silica concentrations were enhanced by ash dissolution. Thus, the dissolved silica profile measured in one of the sediment cores was used to derive the in-situ dissolution rate of volcanic glass particles in marine sediments. A non-steady state model was run over a period of 43 kyr applying a constant pH of 7.30 and a dissolved Al concentration of 0.05 μM. The kinetic constant (AA) was varied systematically to fit the model to the measured dissolved silica-depth profile. The best fit to the data was obtained applying AA = 1.3 × 10−U9 mol of Si cm− 2 s− 1. This in-situ rate of ash dissolution at the seafloor is three orders of magnitude smaller than the rate of ash dissolution determined in previous laboratory experiments. Our results therefore imply that field investigations are necessary to accurately predict natural dissolution rates of volcanic glasses in marine sediments.

Description: The Masaya Caldera Complex has been the site of three highly explosive basaltic eruptions within the last six thousand years. A Plinian eruption ca. 2 ka ago formed the widespread deposits of the Masaya Triple Layer. We distinguish two facies within the Masaya Triple Layer from each other: La Concepción facies to the south and Managua facies to the northwest. These two facies were previously treated as two separated deposits (La Concepción Tephra and the Masaya Triple Layer of Pérez and Freundt, 2006) because of their distinct regional distribution and internal architectures. However, chemical compositions of bulk rock, matrix and inclusion glasses and mineral phases demonstrate that they are the product of a single basaltic magma batch. Additionally, a marker bed containing fluidal-shaped vesicular lapilli allowed us to make a plausible correlation between the two facies, also supported by consistent lateral changes in lithologic structure and composition, thickness and grain size. We distinguish 10 main subunits of the Masaya Triple Layer (I to X), with bulk volumes ranging between 0.02 and 0.22 km3, adding up to 0.86 km3 (0.4 km3 DRE) for the entire deposit. Distal deposits identified in two cores drilled offshore Nicaragua, at a distance of ∼ 170 km from the Masaya Caldera Complex, increase the total tephra volume to 3.4 km3 or ∼ 1.8 km3 DRE of erupted basaltic magma. Isopleth data of five major fallout subunits indicate mass discharges of 106 to 108 kg/s and eruption columns of 21 to 32 km height, affected by wind speeds of 〈 2 m/s to ∼ 20 m/s which increased during the course of the multi-episodic eruption. Magmatic Plinian events alternated with phreatoplinian eruptions and phreatomagmatic explosions generating surges that typically preceded breaks in activity. While single eruptive episodes lasted for few hours, the entire eruption probable lasted weeks to months. This is indicated by changes in atmospheric conditions and ash-layer surfaces that had become modified during the breaks in activity. The Masaya Triple Layer has allowed to reconstruct in detail how a basaltic Plinian eruption develops in terms of duration, episodicity, and variable access of external water to the conduit, with implications for volcanic hazard assessment.