Description: Geochemical data (CH4, SO42−, I−, Cl−, particulate organic carbon (POC), δ13C-CH4, and δ13C-CO2) are presented from the upper 30 m of marine sediment on a tectonic submarine accretionary wedge offshore southwest Taiwan. The sampling stations covered three ridges (Tai-Nan, Yung-An, and Good Weather), each characterized by bottom simulating reflectors, acoustic turbidity, and different types of faulting and anticlines. Sulfate and iodide concentrations varied little from seawater-like values in the upper 1–3 m of sediment at all stations; a feature that is consistent with irrigation of seawater by gas bubbles rising through the soft surface sediments. Below this depth, sulfate was rapidly consumed within 5–10 m by anaerobic oxidation of methane (AOM) at the sulfate-methane transition. Carbon isotopic data imply a mainly biogenic methane source. A numerical transport-reaction model was used to identify the supply pathways of methane and estimate depth-integrated turnover rates at the three ridges. Methane gas ascending from deep layers, facilitated by thrusts and faults, was by far the dominant term in the methane budget at all sites. Differences in the proximity of the sampling sites to the faults and anticlines mainly accounted for the variability in gas fluxes and depth-integrated AOM rates. By comparison, methane produced in situ by POC degradation within the modeled sediment column was unimportant. This study demonstrates that the geochemical trends in the continental margins offshore SW Taiwan are closely related to the different geological settings.

Description: Mud volcanoes are seafloor expressions of focused fluid flow that are common in compressional tectonic settings. New high-resolution 3-D seismic data from the Mercator mud volcano (MMV) and an adjacent buried mud volcano (BMV) image the internal structure of the top 800 m of sediment at both mud volcanoes, revealing that both are linked and have been active episodically. The total volumes of extruded mud range between 0.15 and 0.35 km3 and 0.02–0.05 km3 for the MMV and the BMV, respectively. The pore water composition of surface sediment samples suggests that halokinesis has played an important role in the evolution of the mud volcanoes. We propose that erosion of the top of the Vernadsky Ridge that underlies the mud volcanoes activated salt movement, triggering deep migration of fluids, dissolution of salt, and sediment liquefaction and mobilization since the end of the Pliocene. Since beginning of mud volcanism in this area, the mud volcanoes erupted four times while there was only one reactivation of salt tectonics. This implies that there are other mechanisms that trigger mud eruptions. The stratigraphic relationship of mudflows from the MMV and BMV indicates that the BMV was triggered by the MMV eruptions. This may either be caused by loading-induced hydrofracturing within the BMV or due to a common feeder system for both mud volcanoes. This study shows that the mud volcanoes in the El Arraiche mud volcano field are long-lived features that erupt with intervals of several tens of thousands of years.

Description: Cruise MSM34 of R/V MARIA S. MERIAN aimed to investigate a possible test site location for the German SUGAR project. The well sealed gas hydrate deposit should be accessible by the mobile drilling device MeBo 200. During the two legs of cruise MSM34 of R/V MARIA S. MERIAN regional 2D seismic surveying, high resolution 2D and 3D seismic imaging, geo-chemical sampling, heatflow measurements and long-term piezometer installations were undertaken. A grid of 28 2D seismic profiles was collected across the palaeo Danube delta. A number of inactive and partly buried channel systems could be mapped. Most of them were underlain by one or more bottom simulation reflectors (BSR) indicating the existence of gas hydrates. Based on the seismic brute stack images and the limits of the MeBo drilling device a prospective channel system with indications for possible gas hydrate formation at shallow depth (BSR, inverted strong amplitudes) could be identified in about 1500 m water depth. High resolution 2D seismic and 3D P-Cable seismic were used together with OBS deployments in order to allow structural mapping and physical description of the channel infill. Heatflow measurements and geochemical analyses of gravity and multi corer samples accompany these investigations. Neither the multibeam water column images nor Parasound records show any evidence of flares (gas bubbles in the water column) in this working area suggesting a well sealed hydrate reservoir. Active gas expulsion from the seafloor was observed at about 200 m water depth circling around a slump area. The base plane of the failed sediment volume builds the current seafloor at about 600 m to 700 m water depth. On regional 2D seismic profiles a BSR has been mapped underneath the slope failure with unexpectedly strong upward bending. High resolution 2D and 3D P-Cable seismic investigations with complementary OBS deployment will allow imaging the BSR outline. Moreover velocity analyses, heatflow measurements and geo-chemical samples will be available for a detailed description of hydrate distribution and sediment parameters. In a third working area high resolution 2D seismic reflection profiles were acquired across a fully buried channel system. Together with the regional seismic lines slope failure of the channel fill material can be studied across the slope extension of the system. In summary cruise MSM34 achieved all proposed aims. Based on new regional seismic acquisition two working areas were selected for 3D high resolution studies. Investigations of a promising location for a SUGAR pilot site will be supported by a test location for slope stability and analyses of fluid migration pathways in a buried canyon site.