Description: The Upper Critical Zone (UCZ) of the Bushveld Igneous Complex displays spectacular layering in the form of cyclic units comprising a basal chromitite layer overlain by a sequence of silicate cumulates in the order, from bottom to top, pyroxenite–norite–anorthosite. Electron microprobe and laser ablation inductively coupled plasma mass spectrometry analyses of chromite and silicate minerals in layers between the UG2 chromitite and the Merensky Reef reveal variations in major and trace element compositions that defy explanation with existing models of cumulate mineral–melt evolution. The anomalous features are best developed at sharp contacts of chromitite with adjacent anorthosite and pyroxenite cumulates. Here, chromite compositions change abruptly from high and constant Mg/(Mg + Fe 2+ ) and Fe 2+ /Fe 3+ ratios in chromitite layers to variable and generally lower values in chromite disseminated in silicate layers. Furthermore, the composition of disseminated chromites varies depending on the host silicate assemblage; for example, in Ti, V and Zn contents. Importantly, the abrupt change in chromite composition across the chromitite–silicate layer contacts is independent of the thickness of the chromitite layer and the estimated mass proportions of chromite to intercumulus liquid. Chemical variations in plagioclase are also abrupt and some are hard to reconcile with conventional models of re-equilibration with intercumulus liquid. Among those features is the decoupling of alkalis from other incompatible lithophile elements. In comparison with cumulus plagioclase, intercumulus poikilitic plagioclase in chromitite layers is enriched in rare earth elements but strongly depleted in equally incompatible Li, K and Rb. Strong alkali depletion is also observed in intercumulus pyroxene from ultramafic cumulates and chromitite layers. To explain these features, we propose a new model of post-cumulus recrystallization, which intensifies the modal layering in the crystal–liquid mush, producing the observed sequence of nearly monomineralic layers of chromitite, pyroxenite and anorthosite that define the cyclic units. The crucial element of this model is the establishment of redox potential gradients at contacts between chromite-rich cumulates and adjacent silicate layers owing to peritectic reactions between the crystals and intercumulus melt. Because basaltic melts are ionic electrolytes with Na + as the main charge carrier, the redox potential gradient induces electrochemical migration of Na + and other alkali ions. Selective mobility of alkalis can explain the enigmatic features of plagioclase composition in the cyclic units. Sodium migration is expected to cause remelting of previously formed cumulates and major changes in modal mineral proportions, which may eventually result in the formation of sharply divided monomineralic layers. The observed variations in ferric/ferrous iron ratios in chromite from the cyclic units and Fe distribution in plagioclase imply a redox gradient of the order of 0·9 log-units f O 2 , equivalent to a potential gradient of 60 mV. Preliminary estimates suggest that the resulting electrochemical flux of Na + ions is sufficient to mobilize about one-third of the total Na content of a 1 m thick mush layer within 10 years. The proposed electrochemical effect of post-cumulus crystallization is enhanced by the presence of cumulus chromite but, in principle, it can operate in any type of cumulates in which ferrous and ferric iron species are distributed unequally between crystalline and liquid phases.

Description: The so-called 8.2 ka event represents one of the most prominent cold climate anomalies during the Holocene warm period. Accordingly, several studies have addressed its trigger mechanisms, absolute dating and regional characteristics so far. However, knowledge about subsequent climate recovery is still limited although this might be essential for the understanding of rapid climatic changes. Here we present a new sub-decadally resolved and precisely dated oxygen isotope (δ¹⁸O) record for the interval between 7.7 and 8.7 ka BP (10³ calendar years before AD 1950), derived from the calcareous valves of benthic ostracods preserved in the varved lake sediments of pre-Alpine Mondsee (Austria). Besides a clear reflection of the 8.2 ka event, showing a good agreement in timing, duration and magnitude with other regional stable isotope records, the high-resolution Mondsee lake sediment record provides evidence for a 75-year-long interval of higher-than-average δ¹⁸O values directly after the 8.2 ka event, possibly reflecting increased air temperatures in Central Europe. This observation is consistent with evidence from other proxy records in the North Atlantic realm, thus most probably reflecting a hemispheric-scale climate signal rather than a local phenomenon. As a possible trigger we suggest an enhanced resumption of the Atlantic meridional overturning circulation (AMOC), supporting assumptions from climate model simulations.

Description: Stimulation of rocks deteriorates the equilibrium distribution of rare earth elements and yttrium (REY) between solids and brines. By stimulation of the Permian, Lower Rotliegend formations in the well Groß Schönebeck 3/90 the volcanites are less affected by stimulation than the overlying conglomerate and sandstones. Brines from different lithological sections differ in REY patterns and gain anomalies of Eu, Gd, and Y during processes of recrystallization. The initially small anomalies increase during stimulation but decrease with both ongoing pumping and recrystallization. The REY patterns and their Eu, Gd, Y anomalies of brines from the conglomerate and volcanites distinctively differ from those of the sandstones. The Gd and Y anomalies are strongly correlated and both increase in sandstones with distance from the underlying conglomerate and volcanite. The correlation plot of Gd and Y anomalies does not describe a mixing line between brines from the volcanite and conglomerate but it reveals the extent of recrystallization of rapid precipitations and growth of minerals immediately after the stimulation and the slow re-equilibration of REY between solids and brines in each section of rocks. Extreme recrystallization occurred within the conglomerates, the least ones in the volcanite. REY patterns with their characteristic Eu, Gd, and Y anomalies are reliable indicators of the source of brines after stimulation. The time-dependence of changes of Eu, Gd and Y anomalies reflect the process of recrystallization.

Description: Lake Sihailongwan in Jilin province, NE China, provides the first continuous and almost entirely seasonally laminated sediment record on the East Asian mainland comprising the complete Holocene, the Late-glacial period, and large parts of the Last Glacial. Sediment and palynological proxy data provide a finely resolved regional environmental history of the East Asian monsoon. A varve-based chronology (shl-vc2) has been established for the last 65,000 years and allows a detailed comparison with other long regional and global palaeoclimate records. Vegetation density of the study area depends, on the long run, on precessionally forced insolation changes, with superimposed millennial-scale variability during the Last Glacial. Periodic increase of organic carbon content and thermophilous tree species like Ulmus and Fraxinus and contemporary decrease of shrub Alnus precisely mirror millennial-scale climatic variations primarily known from Greenland ice-cores as Dansgaard-Oeschger cycles, as well as Late-glacial period climate changes. Percentages of trees & shrubs pollen and in particular lake productivity-related data reveal substantial differences between interstadial intensities, with those between 50 and 60 ka BP being more pronounced than the following ones.

Description: Laminated lake sediments from the Dead Sea basin provide high-resolution records of climatic variability in the eastern Mediterranean region, which is especially sensitive to changing climatic conditions. In this study, we aim on detailed reconstruction of climatic fluctuations and related changes in the frequency of flood and dust deposition events at ca. 3300 and especially at 2800 cal. yr BP from high-resolution sediment records of the Dead Sea basin. A ca. 4-m-thick, mostly varved sediment section from the western margin of the Dead Sea (DSEn – Ein Gedi profile) was analysed and correlated to the new International Continental Scientific Drilling Program (ICDP) Dead Sea Deep Drilling Project core 5017-1 from the deep basin. To detect even single event layers, we applied a multi-proxy approach of high-resolution microscopic thin section analyses, micro-X-ray fluorescence (µ-XRF) element scanning and magnetic susceptibility measurements, supported by grain size data and palynological analyses. Based on radiocarbon and varve dating, two pronounced dry periods were detected at ~3500–3300 and ~3000–2400 cal. yr BP which are differently expressed in the sediment records. In the shallow-water core (DSEn), the older dry period is characterised by a thick sand deposit, whereas the sedimentological change at 2800 cal. yr BP is less pronounced and characterised mainly by an enhanced frequency of coarse detrital layers interpreted as erosion events. In the 5017-1 deep-basin core, both dry periods are depicted by halite deposits. The onset of the younger dry period coincides with the Homeric Grand Solar Minimum at ca. 2800 cal. yr BP. Our results suggest that during this period, the Dead Sea region experienced an overall dry climate, superimposed by an increased occurrence of flash floods caused by a change in synoptic weather patterns.