Description: Highlights • There is direct and indirect evidence for hydrate occurrence in several areas around Europe. • Hydrate is particularly widespread offshore Norway and Svalbard and in the Black Sea. • Hydrate occurrence often coincides with conventional thermogenic hydrocarbon provinces. • The regional abundance of hydrate in Europe is poorly known. Abstract Large national programs in the United States and several Asian countries have defined and characterised their marine methane hydrate occurrences in some detail, but European hydrate occurrence has received less attention. The European Union-funded project “Marine gas hydrate – an indigenous resource of natural gas for Europe” (MIGRATE) aimed to determine the European potential inventory of exploitable gas hydrate, to assess current technologies for their production, and to evaluate the associated risks. We present a synthesis of results from a MIGRATE working group that focused on the definition and assessment of hydrate in Europe. Our review includes the western and eastern margins of Greenland, the Barents Sea and onshore and offshore Svalbard, the Atlantic margin of Europe, extending south to the northwestern margin of Morocco, the Mediterranean Sea, the Sea of Marmara, and the western and southern margins of the Black Sea. We have not attempted to cover the high Arctic, the Russian, Ukrainian and Georgian sectors of the Black Sea, or overseas territories of European nations. Following a formalised process, we defined a range of indicators of hydrate presence based on geophysical, geochemical and geological data. Our study was framed by the constraint of the hydrate stability field in European seas. Direct hydrate indicators included sampling of hydrate; the presence of bottom simulating reflectors in seismic reflection profiles; gas seepage into the ocean; and chlorinity anomalies in sediment cores. Indirect indicators included geophysical survey evidence for seismic velocity and/or resistivity anomalies, seismic reflectivity anomalies or subsurface gas escape structures; various seabed features associated with gas escape, and the presence of an underlying conventional petroleum system. We used these indicators to develop a database of hydrate occurrence across Europe. We identified a series of regions where there is substantial evidence for hydrate occurrence (some areas offshore Greenland, offshore west Svalbard, the Barents Sea, the mid-Norwegian margin, the Gulf of Cadiz, parts of the eastern Mediterranean, the Sea of Marmara and the Black Sea) and regions where the evidence is more tenuous (other areas offshore Greenland and of the eastern Mediterranean, onshore Svalbard, offshore Ireland and offshore northwest Iberia). We provide an overview of the evidence for hydrate occurrence in each of these regions. We conclude that around Europe, areas with strong evidence for the presence of hydrate commonly coincide with conventional thermogenic hydrocarbon provinces.

Description: Highlights • 4D studies of P-Cable HR3D data show good repeatability and a monitoring potential. • The P-Cable system can detect very small subsurface CO2 leaks (1.3–10.6 t). • We conclude that the system can be valuable in monitoring the (shallow) subsurface. The P-Cable technology is an acquisition principle for high-resolution and ultra-high-resolution 3D seismic data. Many 3D seismic datasets have been acquired over the last decade, but the application in time-lapse studies for monitoring of CO2 storage is a new and intriguing topic. High-resolution 3D (HR3D) seismic has the potential to detect and monitor CO2 leakage at carbon capture and storage sites with higher accuracy at depths ∼0−2 km below the seafloor compared to more traditional conventional seismic time-lapse data. Here, we synthesize and evaluate research on detection of subsurface CO2 movement using the P-Cable system and address the comparative advantages and disadvantages of conventional and HR3D technologies for subsurface fluid migration monitoring. Studies on P-Cable 4D seismic data show good repeatability (NRMS, 10–40 %), indicating a future monitoring potential. Analysis of detection limits of CO2 data from a CO2 storage site show the ability to detect very small amounts of CO2 (1.3–10.6 t; 3.3–27.4 % gas saturation) in the shallow subsurface. These detection limits are ∼30−300 times smaller than the detection limits of conventional seismic data at similar depths. We conclude that the P-Cable acquisition system can be a valuable monitoring tool in detecting small leakages and can complement conventional seismic data monitoring of the deeper interval.

Description: The Palaeocene–Eocene Thermal Maximum (PETM) was a global warming event of 5–6 °C around 56 million years ago caused by input of carbon into the ocean and atmosphere. Hydrothermal venting of greenhouse gases produced in contact aureoles surrounding magmatic intrusions in the North Atlantic Igneous Province have been proposed to play a key role in the PETM carbon-cycle perturbation, but the precise timing, magnitude and climatic impact of such venting remains uncertain. Here we present seismic data and the results of a five-borehole transect sampling the crater of a hydrothermal vent complex in the Northeast Atlantic. Stable carbon isotope stratigraphy and dinoflagellate cyst biostratigraphy reveal a negative carbon isotope excursion coincident with the appearance of the index taxon Apectodinium augustum in the vent crater, firmly tying the infill to the PETM. The shape of the crater and stratified sediments suggests large-scale explosive gas release during the initial phase of vent formation followed by rapid, but largely undisturbed, diatomite-rich infill. Moreover, we show that these vents erupted in very shallow water across the North Atlantic Igneous Province, such that volatile emissions would have entered the atmosphere almost directly without oxidation to CO 2 and at the onset of the PETM.

Description: Mechanisms related to sub-seabed fluid flow processes are complex and inadequately understood. Petrophysical properties, availability of gases, topography, stress directions, and various geological parameters determine the location and intensity of leakage which change over time. From tens of seafloor pockmarks mapped along Vestnesa Ridge on the west-Svalbard margin, only six show persistent present-day seepage activity in sonar data. To investigate the causes of such restricted gas seepage, we conducted a study of anisotropy within the conduit feeding one of these active pockmarks (i.e., Lunde Pockmark). Lunde is ∼400–500 m in diameter, and atop a ∼300–400 m wide seismic chimney structure. We study seismic anisotropy using converted S-wave data from 22 ocean-bottom seismometers (OBSs) located in and around the pockmark. We investigate differences in symmetry plane directions in anisotropic media using null energy symmetries in transverse components. Subsurface stress distribution affects fault/fracture orientations and seismic anisotropy, and we use S-wave and high-resolution 3D seismic data to infer stress regimes in and around the active seep site and study the effect of stresses on seepage. We observe the occurrence of changes in dominant fault/fracture and horizontal stress orientations in and around Lunde Pockmark and conclude minimum (NE-SW) and maximum (SE-NW) horizontal stress directions. Our analysis indicates a potential correlation between hydrofractures and horizontal stresses, with up to a ∼32% higher probability of alignment of hydrofractures and faults perpendicular to the inferred minimum horizontal stress direction beneath the Lunde Pockmark area. Key Points The S-wave analysis using ocean-bottom seismic (OBS) data indicates seismic anisotropy around a seeping pockmark on the W-Svalbard Margin The occurrence and orientation of symmetry planes in shallow anisotropic sediments vary across the pockmark Combined analyses using S-wave and 3-D seismic data suggest that preferred fault and fracture orientations follow local stress conditions

Description: The Paleocene Eocene Thermal Maximum (PETM, ~56 Ma) was a rapid global warming of 5-6 ºC resulting from massive (〉2000 Gigatons) carbon emissions. A potential release mechanism is thermogenic gas from contact metamorphism of carbon-bearing sediments due to magma intrusions into sedimentary basins. Here, we present seismic data and borehole information from the North Atlantic Igneous Province. They show that even in the center of the rift system, water depths were sufficiently shallow to allow most gas released from hydrothermal vent systems to bypass the water column. The shape of the vent craters and stratified infill suggest vigorous explosive gas release during the initial phase of vent formation and rapid shallow marine and largely undisturbed infill thereafter. The recorded negative carbon isotope excursion and occurrence of the index taxon Apectodinium augustum in the crater-infill support assignment to a latest Paleocene to earliest Eocene vent formation. The data support a scenario where magmatic sill emplacement and resulting hydrothermal activity rapidly injected thermogenic greenhouse gas into the atmosphere.

Description: The Aurora hydrothermal system, Arctic Ocean, hosts active submarine venting within an extensive field of relict mineral deposits. Here we show the site is associated with a neovolcanic mound located within the Gakkel Ridge rift-valley floor, but deep-tow camera and sidescan surveys reveal the site to be ≥100 m across—unusually large for a volcanically hosted vent on a slow-spreading ridge and more comparable to tectonically hosted systems that require large time-integrated heat-fluxes to form. The hydrothermal plume emanating from Aurora exhibits much higher dissolved CH〈jats:sub〉4〈/jats:sub〉/Mn values than typical basalt-hosted hydrothermal systems and, instead, closely resembles those of high-temperature ultramafic-influenced vents at slow-spreading ridges. We hypothesize that deep-penetrating fluid circulation may have sustained the prolonged venting evident at the Aurora hydrothermal field with a hydrothermal convection cell that can access ultramafic lithologies underlying anomalously thin ocean crust at this ultraslow spreading ridge setting. Our findings have implications for ultra-slow ridge cooling, global marine mineral distributions, and the diversity of geologic settings that can host abiotic organic synthesis - pertinent to the search for life beyond Earth.

Description: This data set contains concentrations of major cations and anions in the pore fluid as well as boron stable isotopic ratios (d11B), stable oxygen and hydrogen isotopes of pore fluid (d18O and dD). Sediment samples were collected by using the seafloor drill rig MARUM-MeBo70 onboard 'RV MARIA S. MERIAN'.