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  • Data  (2)
  • AGE; CALYPSO; Calypso Corer; DEPTH, sediment/rock; Gas chromatography - Isotope ratio mass spectrometer (GC-IRMS); IMAGES IV-IPHIS III; Indo-Pacific Warm Pool; Leaf wax; Marion Dufresne (1995); MD111; MD982152; MD98-2152; n-Alkanoic acid C30, δD; precipitation; δ Deuterium, precipitation  (1)
  • calibration; lakes  (1)
  • 2020-2024  (2)
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  • Data  (2)
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  • 2020-2024  (2)
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  • 1
    Publication Date: 2023-06-27
    Description: The stable hydrogen isotopes of C30-Alkanoic acids were measured from marine sediment core MD98-2152, collected off the southern coast of Sumatra, likely reflecting rainfall over southern Sumatra and western Java. The record extends to ~450,000 years before present and includes the five most recent glacial periods. To purify the leaf wax fatty acids for analysis, organic material was extracted from the sediment using an Accelerated Solvent Extractor, leaf waxes were isolated from each total lipid extract using column chromatography then methylated with methanol of a known isotopic composition to form fatty acid methyl esters, and purified with a final column. Hydrogen isotopes were measured using a gas chromatography-isotope ratio-monitoring mass spectrometer against Vienna Standard Mean Ocean Water (VSMOW). The hydrogen isotopes of the leaf wax fatty acids were then used in tandem with previously measured carbon isotopes of the same samples to calculate the hydrogen isotope values of precipitation, accounting for vegetation changes, through time following the methods in Tierney et al. (2017). This data was collected with the purpose of examining rainfall variability in the southern Indo-Pacific Warm Pool during glacial climates and to improve the spatial coverage of precipitation isotope records in the region. The age model and leaf wax carbon isotopes for MD98-2152 are available in Windler et al. (2019).
    Keywords: AGE; CALYPSO; Calypso Corer; DEPTH, sediment/rock; Gas chromatography - Isotope ratio mass spectrometer (GC-IRMS); IMAGES IV-IPHIS III; Indo-Pacific Warm Pool; Leaf wax; Marion Dufresne (1995); MD111; MD982152; MD98-2152; n-Alkanoic acid C30, δD; precipitation; δ Deuterium, precipitation
    Type: Dataset
    Format: text/tab-separated-values, 724 data points
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2024-04-20
    Description: Despite widespread use of branched glycerol dialkyl glycerol tetraethers (brGDGTs) for paleo-temperature reconstruction, no global calibration for their application in lakes has been generated since improved analytical methods have allowed for the separation of the structural isomers [Hopmans et al., 2016]. This is a substantial obstacle for the application of this tool as soil calibrations underestimate temperature values when applied to lake sediments. In order to generate a global calibration, we present a comprehensive dataset (N = 272) of lacustrine brGDGT distributions, consisting of both new and previously reported samples [Boldt et al., 2015; Dang et al., 2018; 2016; Li et al., 2017; Stefanescu et al., 2021], spanning a wide range of geographical locations. In addition, we compiled environmental information from these locations through in situ measurements [Li et al., 2017] and literature search for pH, conductivity, and nutrient content. For parameters such as mean annual air temperature (MAAT), temperature of months above freezing (MAF), mean annual precipitation (MAP), we estimated values from either the CRU [Osborn and Jones, 2014] or PRISM [https://prism.oregonstate.edu/] products depending on the location. Our new calibration [Martínez-Sosa et al., 2021] facilitates the use of lacustrine brGDGTs to reconstruct continental temperatures, a vital piece of information for understanding past climates.
    Keywords: calibration; lakes
    Type: Dataset
    Format: application/zip, 36.8 kBytes
    Location Call Number Limitation Availability
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