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  • 1
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geophysical journal international 125 (1996), S. 0 
    ISSN: 1365-246X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The microstructural development during nucleation and growth processes is studied numerically. Most of the studies are for the simple case of constant nucleation and growth rates, but a brief discussion is made of the effect of time-dependent nucleation and growth. A 3-D code is used which accounts for not only the nucleation and growth of individual new grains, but also the effects of grain impingement, and which allows for the study of both homogeneous and heterogeneous nucleation.The microstructures are characterized by the grain-size distribution (GSD) and the cluster-size distribution (CSD). In the case of homogeneous nucleation, the development of GSD and CSD can be scaled using the Avrami time τAv and Avrami length τAv, which are related to the nucleation and growth rates. Both scaling constants have a simple physical meaning: the average grain size after the completion of the phase transformation is given by τAv, and the transformation half-time is approximately equal to τAv. the formation of a continuous chain of new-phase grains (percolation transition) is observed at ∼30 per cent transformation degree, and the geometry of the largest cluster near the percolation threshold has fractal characteristics with a fractal dimension of ∼2.5. the presence of preferred sites of nucleation (heterogeneous nucleation), such as grain boundaries, significantly modifies the microstructures when the spacing of nucleation sites is much larger than the Avrami length, the main effects being a reduced percolation threshold and an elongate grain shape. Some applications to the olivine-spinel transformation in subducting slabs and to the crystallization in a hypothetical magma ocean are discussed.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1433-8491
    Keywords: Key words Saccades ; Latency ; Gain ; Fixation ; suppression error ; Neuroleptics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Saccades were elicited in 30 schizophrenic patients before medication, in 17 of them during medication with neuroleptics, and in 12 healthy controls using six paradigms that tested different types of saccades: (a) the externally triggered and visually guided saccades; (b) the externally triggered and internally guided saccades (anti-saccades); and (c) the internally triggered and internally guided saccades (memory-guided saccades). Latency of the primary saccade, gain (eye amplitude to target amplitude), and percentage of unwanted saccades (fixation suppression errors) were calculated. The externally triggered and externally guided saccades were only slightly affected in the patients, indicating that the function of parieto-tectal pathways was preserved. In contrast, the internally guided and externally triggered saccades showed abnormally long latencies, slightly smaller gains, and an increased rate of suppression errors regardless of the medication status. These findings were even more pronounced in the internally triggered and internally guided saccades such as memory-guided saccades. According to animal experiments and studies on patients with disorders of the basal ganglia, the performance of these saccades is based on the function of the pre- and dorsolateral frontal cortex and its connections to the basal ganglia. The minimal improvement of some of the parameters after clinical improvement and during treatment with neuroleptics suggests that the eye-movement deficits are associated with abnormalities of schizophrenia, which do not basically change under medication with neuroleptics. The observed effects of neuroleptics also argue against a primary abnormality in the dopaminergic input to the frontal cortex – basal ganglia oculomotor loop and support the view that there is a primary disturbance of the cortical input to the oculomotor loop through the basal ganglia in schizophrenics.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2020-07-10
    Type: Conference or Workshop Item , NonPeerReviewed
    Format: text
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  • 5
    Publication Date: 2021-07-13
    Description: At the Australian-Pacific plate boundary, the northern Lau Basin is one of the fastest opening back-arc basins on earth. The current configuration of micro-plates, plate boundaries and motions within the northern Lau Basin is quite well understood, but in the southern part of the Lau Basin questions remain about the crustal structure. Here, the Central Lau Spreading Center (CLSC) and the southern tip of the Fonualei Rift and Spreading Center (FRSC) define the diffuse southern boundary of the Niuafo’ou microplate. It remains unclear where the southern plate boundary is located and what kind of boundary it is.We present 1) seismic refraction data of a 200-km long, E-W transect acquired in the transition zone from the eastern side of the CLSC to the southern tip of the FRSC and 2) seismic reflection data of four E-W profiles of varying length, acquired in both the southern part of the Niuafo’ou microplate and the transition in between the CLSC and the FRSC. The seismic data acquisition was accompanied by parametric sediment echosounder, gravimetric and magnetic measurements and was complemented by heat flow probes and dredged samples of the seafloor in the vicinity of the profile.Our travel time tomography reveals a pronounced lateral variation in seismic P-wave velocities from west to east, within the 7-8 km thick back-arc crust. Towards the east, the crust gradually thickens to 13 km of arc crust. The reflection seismic data reveals sediment pockets, varying between 300m to 1000m depth, located on both the thinner back-arc crust and thicker arc crust. In the abyssal regions, faults that cross-cut the basement, but do not reach the surface, are observed on all reflection seismic profiles and are considered inactive today. Towards the west of the profiles, faults reach the surface and are considered active. Rock sampling from this area retrieved predominantly massive aphyric basalts from the back-arc crust in the west. Olivine-rich basalts, andesites, and a broad spectrum of volcaniclastic rocks are the most common rock-type collected from the arc crust in the east.The lack of a thinner crust near the southern tip of the FRSC, the presence of inactive faults that cross-cut the basement, and the presence of active faults in the CLSC suggest that the southern plate boundary of the Niuafo’ou microplate accommodated extension in a wide-rift tectonic setting in the past. Today, this extension is accommodated in the CLSC in a narrow extensional tectonic setting.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 6
    Publication Date: 2021-01-15
    Description: The northern Lau Basin, at the Australian-Pacific plate boundary, is one of the fastest opening back-arc basins on earth. An amalgamation of active rifts and spreading centers accommodates the extension. The current configuration of micro-plates, motions and plate-boundaries within the northern Lau Basin has been studied, but remains complex. Especially in the southern part of the Lau Basin questions remain about the crustal structure. In this area, the Central Lau Spreading Center (CLSC) and the southern tip of the Fonualei Rift and Spreading Center (FRSC) define the diffuse southern boundary of the Niuafo’ou microplate. It remains unclear where the southern plate boundary is located and what kind of boundary it is. We present seismic refraction and reflection data of a 200-km long transect in the transition zone from the eastern side of the CLSC to the southern tip of the FRSC. The seismic data recording was accompanied by parametric sediment echosounder data, gravimetric and magnetic measurements and dredged samples of the seafloor in the vicinity of the profile. A travel time tomography reveals a pronounced lateral variation in seismic P-wave velocities from west to east, within the 7-8 km thick back-arc-crust. Towards the east the crust gradually thickens to 13 km of arc-crust. The reflection seismic data reveals sediment pockets that vary between 300m to 1000m depth and are located on both the thinner back-arc crust and thicker arc-crust. Rock sampling along the transect retrieved predominantly massive aphyric basalts from the back-arc-crust in the west. Ol-Px-Pl-phyric basalts, andesites, and a broad spectrum of volcaniclastic rocks are the most common rock-type collected from the arc-crust in the east. These rocks are currently analyzed to determine the age and geochemical (major, trace element and Sr-Nd-Pb-Hf isotopic) composition of the sampled structures. The lack of a thinner crust near the southern tip of the FRSC is located and a wide distribution of normal faults in the sedimentary basins that reach the surface suggest that the southern plate boundary of the Niuafo’ou microplate actively accommodates extension in a wide rift setting.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 7
    Publication Date: 2021-07-13
    Description: The 2 June 1994 Java (Indonesia) tsunami earthquake ruptured in a seismically quiet subduction zone and generated a larger-than-expected tsunami. Since the peak of the co-seismic slip occurred underneath a local bathymetric high, the 1994 event was previously interpreted as being caused by a subducting seamount. Combining a re-processed seismic reflection line across the rupture area with a refraction tomography P-wave velocity model, multibeam bathymetry, and gravity data suggests that rupture over a subducted seamount is unlikely to explain the seismo-tectonic genesis of the event. The forearc high is rather related to the enhanced back-thrusting activity and an island arc crust backstop in the upper plate. We newly resolve a shallow subducting seamount seaward of the forearc high and up-dip of the rupture area. We propose that this seamount acted as a seismic barrier and may have diverted the co-seismic rupture into the overlying splay faults, which may have contributed to the larger-than-expected tsunami
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 8
    Publication Date: 2021-07-13
    Description: Since the last glaciation the Canadian Arctic Beaufort Shelf is subjected to marine transgression. From subaerial mean annual temperatures during terrestrial exposure of ≤ -20°C, thermal conditions changed up to present submarine bottom water temperatures near -1°C. While conditions during the Pliocene favoured extensive formation of permafrost and gas hydrates, present occurrences are exposed to degradation due to the warmer climate. Today, submerged offshore permafrost is still responding to this thermal change. Ongoing degradation creates the potential of methane release of previously trapped biogenic gas within the relic permafrost and from gas hydrate dissociation. The mobilisation of methane and its possible release to the atmosphere plays a significant role in climate change. Yet, both the extent of permafrost and underlying gas hydrates is still poorly known. Here, we present seismic indicators for offshore permafrost and gas hydrates in 2D multichannel reflection seismic data acquired in the Canadian Beaufort Sea. Seismic lines that run from the shallow shelf towards deeper water show layer-crossing reflections that become gradually shallower towards the north-west into deeper water. These reflections show an amplitude-varying characteristic and are phase-reversed. We first use shot gathers from a synthetic model based on the field seismic acquisition characteristics and borehole geophysical data to verify our general ability to detect permafrost-and gas hydrate-related reflections. The synthetic data were processed using the same data processing applied to the field data and reveal clear top and base of permafrost and gas hydrate reflections. With this encouraging result, we can exclude any potentially misleading processing artefacts in the field seismic data. We interpret the amplitude-varying, phase-reversed and layer-crossing reflections seen in the field data as seismic indicators for the base of permafrost and base of gas hydrates. In contrast to the synthetic data, top of permafrost and top of gas hydrates are not clearly identified in the field data. However, additional seismic indicators support the interpretation of the presence of permafrost including attenuation of acoustic penetration and velocity pull-up effects at presumably horizontal strata. Furthermore, strong amplitude variations beneath the current base of gas hydrates and bright spots indicate trapped free gas accumulations from possible previously dissociated gas hydrates.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 9
    Publication Date: 2021-12-15
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 10
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    In:  [Poster] In: PDAC Convention 2021, 08.03.-11.03.21, Toronto, Canada . 12 Annual PDAC-SEG Student Minerals Colloqium Abstracts ; p. 40 .
    Publication Date: 2021-10-21
    Type: Conference or Workshop Item , NonPeerReviewed
    Format: text
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