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  • 1995-1999  (3)
  • 1997  (3)
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  • 1995-1999  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 1058-1064 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In the study of interfacial diffusion processes in polymer light-emitting diodes, the use of high-energy ion-scattering techniques can be of great value due to the possibility of quantitative elemental depth profiling. However, ion irradiation of polymers is known to cause various degradation effects, including the loss of hydrogen. Since the hydrogen loss determines the accuracy of depth profiling, it is an interesting subject for study in order to define experimental conditions in which the degradation is suppressed. The loss of hydrogen from porphyrins (organic solar cells) has been measured by means of elastic recoil detection analysis with 2, 4, and 7.6 MeV He+ beams. A theoretical model is proposed in which the hydrogen loss is described through the formation and recombination of free hydrogen radicals. A distinct difference is introduced between direct recombination processes and the diffusion of radicals out of the ion track. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Scandinavian journal of medicine & science in sports 7 (1997), S. 0 
    ISSN: 1600-0838
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine , Sports Science
    Notes: The present study investigated factors that contribute to the formation of a previously reported knee joint flexor moment during the stance phase of walking. Contradictory results have been reported on this flexor moment, which some but not all individuals exhibit. Seven healthy male subjects were high speed filmed while walking across a force platform, and EMG recordings were obtained from five leg muscles. To investigate segment interactions, net joint moments about the ankle, knee and hip joint were calculated by inverse dynamics and each term in the equation used for the moment calculation was evaluated during the timeecourse of the step cycle. To test the hypothesis that net joint moments are balanced by an external moment formed by the resulting ground reaction vector multiplied by the perpendicular distance to the actual joint, external moment arms were calculated by the floor reaction force vector approach (FRFV). Contrasting two subjects with different net joint moments about the knee and ankle joint revealed that the knee joint flexor moment could not be explained by an opposite external moment. The external moments were calculated by a simplified method (FRFV) in which the point of force application is incorrect for joints above the ankle joint. However, at the ankle joint the net joint moment was always opposed by an external moment of opposite polarity. A detailed examination of the equation used for the net joint moment calculation showed that a knee joint flexor moment can be caused directly by a large plantar flexor moment about the ankle joint. For example, the soleus muscle can pull the tibia and generate an extensor moment about the knee joint, which in turn has to be opposed by a knee flexor moment from the hamstring muscles. Otherwise the desired joint angles cannot be obtained during human walking. It is therefore suggested that the kinematics regarding how the foot is placed on the ground may influence the net ankle joint moment, while the moment patterns about the knee and hip joint are determined by segment interaction and the requirements for controlling the direction of the resulting ground reaction vector. In vertical jumping it is advantageous to generate extensor moments about the knee and hip joint simultaneously, while in horizontal locomotion this would result in inefficient vertical movements.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 339 (1997), S. 708-713 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The influence of the chemical structure of rigid star-shaped multipodes composed of an adamantane central core and short rigid branches on the glass formation and crystallisation is analysed. It was found that esters of 1,3,5,7-adamantanetetracarboxylic acid with various phenols (3a-c) and esters of 1,3,5,7-tetrahydroxyadamantane with various benzoic acid derivatives (4a-c) display both crystalline and glassy states with high glass transition temperatures and melting temperatures. These quantities strongly depend on the restriction of the rotational motions about the ester groups connecting the core and the branches.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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