Publication Date:
2018-02-28
Description:
A novel Br-bridged Pd chain complex, [Pd(hxn)2Br](TsO)2 (2) (TsO- = p-toluenesulfonate), was synthesized from a new in-plane ligand (3S,4S)-3,4-diaminohexane (hxn). 2 forms PdII/PdIV mixed-valence state, as confirmed by single-crystal X-ray structure analysis and polarized Raman spectra. The hxn ligand provides the additional hydrogen bonds (CH***O) between the methyl group of the ligands and the O atoms of TsO- anions, which are weaker than those observed in the chain complex with hydroxy group, [Pd(dabdOH)2Br]Br2 (1).
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology