Beschreibung: The 2013 US GEOTRACES Eastern Pacific Zonal Transect (GP16) extended from the Peruvian coast to Tahiti, along a line that fell between 10 and 15°S. This transect sampled the Peruvian oxygen deficient zone (ODZ) and the hydrothermal plume extending from the East Pacific Rise (EPR) for a variety of trace elements and isotopes (TEIs). Here we report nutrient and hydrographic measurements collected on this cruise, as well as results from an Optimum Multiparameter Analysis (OMPA) to quantify the fractional contributions of endmember water masses in each sample. The primary goals of this study were to better understand the distribution of water masses in the eastern tropical Pacific, and to help interpret TEI measurements collected on this cruise, as well as related studies carried out in the region. In the thermocline, Equatorial Subsurface Water (ESSW) dominated the low oxygen waters of the eastern tropical South Pacific, blending into Eastern South Pacific Intermediate Water (ESPIW) and South Pacific Central Water (SPCW) further west. Below the thermocline, distributions of Antarctic Intermediate Water (AAIW) and Equatorial Pacific Intermediate Water (EqPIW) were relatively homogenous along the section between 800 and 1200 m depth. Deeper in the water column, distinct water mass signatures were found on opposite sides of the EPR: southward flowing Pacific Deep Water (PDW) dominated the basin east of the EPR, while the northward flowing Antarctic Bottom Water (AABW) and Lower Circumpolar Deep Water (LCDW) had the strongest contributions on the western side of the EPR. These findings support previous studies that indicate the Peruvian ODZ is largely contained within ESSW and that the EPR plays an important role in steering water mass distributions in the deep waters of the tropical Pacific. Overall, these results agree well with previous water mass analyses in this region and are consistent with the general circulation patterns in the eastern tropical Pacific.

Beschreibung: Highlights: • GEOTRACES releases its first integrated and quality controlled Intermediate Data Product 2014 (IDP2014). • The IDP2014 digital data are available at http://www.bodc.ac.uk/geotraces/data/idp2014/ in 4 different formats. • The eGEOTRACES Electronic Atlas at http://egeotraces.org/ provides 329 section plots and 90 animated 3D tracer scenes. • The new 3D scenes provide geographical and bathymetric context crucial for tracer assessment and interpretation. Abstract: The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEIs) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including ASCII spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the IDP2014 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2014 data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes.

Beschreibung: Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T1/2 = 5.75 yr), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf 228Ra fluxes are combined with TEI/ 228Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3–23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean.

Beschreibung: Along mid-ocean ridges, submarine venting has been found at all spreading rates and in every ocean basin. By contrast, intraplate hydrothermal activity has only been reported from five locations, worldwide. Here we extend the time series at one of those sites, Teahitia Seamount, which was first shown to be hydrothermally active in 1983 but had not been revisited since 1999. Previously, submersible investigations had led to the discovery of low-temperature (≤30°C) venting associated with the summit of Teahitia Seamount at ≤1500 m. In December 2013 we returned to the same site at the culmination of the US GEOTRACES Eastern South Tropical Pacific (GP16) transect and found evidence for ongoing venting in the form of a non-buoyant hydrothermal plume at a depth of 1400 m. Multi-beam mapping revealed the same composite volcano morphology described previously for Teahitia including four prominent cones. The plume overlying the summit showed distinct in situ optical backscatter and redox anomalies, coupled with high concentrations of total dissolvable Fe (≤186 nmol/L) and Mn (≤33 nmol/L) that are all diagnostic of venting at the underlying seafloor. Continuous seismic records from 1986-present reveal a ∼15 year period of quiescence at Teahitia, following the seismic crisis that first stimulated its submersible-led investigation. Since 2007, however, the frequency of seismicity at Teahitia, coupled with the low magnitude of those events, are suggestive of magmatic reactivation. Separately, distinct seismicity at the adjacent Rocard seamount has also been attributed to submarine extrusive volcanism in 2011 and in 2013. Theoretical modeling of the hydrothermal plume signals detected suggest a minimum heat flux of 10 MW at the summit of Teahitia. Those model simulations can only be sourced from an area of low-temperature venting such as that originally reported from Teahitia if the temperature of the fluids exiting the seabed has increased significantly, from ≤30°C to ∼70°C. These model seafloor temperatures and our direct plume observations are both consistent with reports from Loihi Seamount, Hawaii, ∼10 year following an episode of seafloor volcanism. We hypothesize that the Society Islands hotspot may be undergoing a similar episode of both magmatic and hydrothermal reactivation.

Beschreibung: The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017. This article is part of a special issue entitled: Conway GEOTRACES - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.

Beschreibung: Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES program as well as a proof-of-concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes, and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T1/2=5.75 y), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange, and rivers. Model-derived shelf 228Ra fluxes are combined with TEI/ 228Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn, and Zn inputs and exceed published estimates of atmospheric deposition by factors of ~3-23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean.

Beschreibung: Abstract The {GEOTRACES} Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international {GEOTRACES} programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEIs) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The {IDP2014} covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The {TEI} data in the {IDP2014} are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including {ASCII} spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the {IDP2014} also contains data quality flags and 1-� data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the {IDP2014} data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes.

Beschreibung: Dataset: GP15 TDS and OCS Leg 1

Beschreibung: This dataset includes total dissolved sulfide (TDS) and carbonyl sulfide (OCS) data from Leg 1 (Seattle, WA to Hilo, HI) of the US GEOTRACES Pacific Meridional Transect (PMT) cruise (GP15, RR1814) conducted on R/V Roger Revelle from September to October 2018. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/873908

Beschreibung: NSF Division of Ocean Sciences (NSF OCE) OCE-1737342