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  • 2015-2019  (25)
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  • 1
    Keywords: Hochschulschrift ; Labradorsee ; Oberflächenwasser ; Meeresströmung
    Type of Medium: Online Resource
    Pages: Online-Ressource (213 Seiten = 8 MB) , Diagramme, Karten
    DDC: 550
    Language: English
    Note: Zusammenfassung in deutscher und englischer Sprache
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  • 2
    Publication Date: 2021-03-18
    Description: The quantitative reconstruction of past seawater salinity has yet to be achieved and the search for a direct and independent salinity proxy is ongoing. Recent culture and field studies show a significant positive correlation of Na/Ca with salinity in benthic and planktonic foraminiferal calcite. For accurate paleoceanographic reconstructions, consistent and reliable calibrations are necessary, which are still missing. In order to assess the reliability of foraminiferal Na/Ca as a direct proxy for seawater salinity, this study presents electron microprobe Na/Ca data, measured on cultured specimens of Trilobatus sacculifer. The culture experiments were conducted over a wide salinity range of 26 to 45, while temperature was kept constant. To further understand potential controlling factors of Na incorporation, measurements were also performed on foraminifera cultured at various temperatures in the range of 19.5 °C to 29.5 °C under constant salinity conditions. Foraminiferal Na/Ca ratios positively correlate with seawater salinity (Na/Caforam = 0.97 + 0.115 ⋅ Salinity, R = 0.97, p 〈 0.005). Temperature on the other hand exhibits no statistically significant relationship with Na/Ca ratios indicating salinity to be the dominant factor controlling Na incorporation. The culturing results are corroborated by measurements on T. sacculifer from Caribbean and Gulf of Guinea surface sediments. In conclusion, planktonic foraminiferal Na/Ca can be applied as a reliable proxy for reconstructing sea surface salinities, albeit species-specific calibrations might be necessary.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2020-02-06
    Description: The Labrador Sea is one of the key areas for deep water formation driving the Atlantic thermohaline circulation and thus plays an important role in Northern Hemisphere climatic fluctuations. In order to better constrain the overturning processes and the origins of the distinct water masses, combined dissolved Hf–Nd isotopic compositions and rare earth element (REE) distribution patterns were obtained from four water depth profiles along a section across the Labrador Sea. These were complemented by one surface sample off the southern tip of Greenland, three shallow water samples off the coast of Newfoundland, and two deep water samples off Nova Scotia. Although light REEs are markedly enriched in the surface waters off the coast of Newfoundland compared to north Atlantic waters, the REE concentration profiles are essentially invariant throughout the water column across the Labrador Sea. The hafnium concentrations of surface waters exhibit a narrow range between 0.6 and 1 pmol/kg but are not significantly higher than at depth. Neodymium isotope signatures (ɛNd) vary from unradiogenic values between −16.8 and −14.9 at the surface to more radiogenic values near −11.0 at the bottom of the Labrador Sea mainly reflecting the advection of the Denmark Strait Overflow Water and North East Atlantic Deep Water, the signatures of which are influenced by weathering contributions from Icelandic basalts. Unlike Nd, water column radiogenic Hf isotope signatures (ɛHf) are more variable representing diverse weathering inputs from the surrounding landmasses. The least radiogenic seawater ɛHf signatures (up to −11.7) are found in surface waters close to Greenland and near the Canadian margin. This reflects the influence of recirculating Irminger Current Waters, which are affected by highly unradiogenic inputs from Greenland. A three to four ɛHf unit difference is observed between Denmark Strait Overflow Water (ɛHf ∼ −4) and North East Atlantic Deep Water (ɛHf ∼ −0.1), although their source waters have essentially the same ɛNd signature. This most likely reflects different weathering signals of hafnium delivered to Denmark Strait Overflow Water and North East Atlantic Deep Water (incongruent weathering of old rocks from Greenland versus basaltic rocks from Iceland). In addition, the ɛHf data resolve two layers within the main body of Labrador Sea Water not visible in the ɛNd distribution, which are shallow Labrador Sea Water (ɛHf ∼ −2) and deep Labrador Sea Water (ɛHf ∼ −4.5). The latter layer was formed between the late 1980’s and mid 1990’s during the last cold state of the Labrador Sea and underwent substantial modification since its formation through the admixture of Irminger Water, Iceland Slope Water and North East Atlantic Deep Water, which is reflected in its less radiogenic ɛHf signature. The overall behavior of Hf in the water column suggests its higher sensitivity to local changes in weathering inputs on annual to decadal timescales. Although application of Hf isotopes as a tracer for global water mass mixing is complicated by their susceptibility to incongruent weathering inputs they are a promising tracer of local processes in restricted basins such as the Labrador Sea.
    Type: Article , PeerReviewed
    Format: text
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  • 4
    Publication Date: 2022-01-31
    Description: The Labrador Current is part of the anticlockwise subpolar gyre and plays a major role in the formation of North Atlantic Deep Water. It is influenced by the West Greenland and Baffin currents supplying warmer Atlantic and cold polar waters, respectively. During the early Holocene, at the final stage of the last deglaciation, meltwater and iceberg discharge caused highly variable conditions in the Labrador Current. In order to assess its sensitivity to such freshening, this study provides a well-resolved Holocene paleoclimatic record from the Labrador Shelf. Based on benthic foraminiferal faunal and alkenone biomarker analyses, we differentiated four distinct climatic periods in the western Labrador Sea. From 8.9 to 8.6 ka BP, the Labrador Shelf was dominated by polar water outflow from Baffin Bay and covered by perennial sea ice. Between 8.6 and 7.4 ka BP, a strong subsurface inflow of warmer Atlantic water masses is ascribed to an intensification and redirection of the West Greenland Current. At 7.4 ka BP, the decreased influence of Atlantic water masses on the Labrador Shelf marks the establishment of winter convection leading to the formation of Labrador Sea Water in the central basin. Concurrently, an intensified polar water outflow through the Canadian Gateways strengthened the inner Labrador Current, and higher primary productivity suggests longer spring blooms because of a shorter sea-ice season during the Holocene Thermal Maximum. In the late Holocene after 3 ka BP, periodic fluctuations of primary productivity may tentatively be correlated with stronger and weaker northwesterly winds.
    Type: Article , PeerReviewed
    Format: text
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  • 5
    Publication Date: 2022-01-31
    Description: A significant reduction in the Atlantic Meridional Overturning Circulation and rapid northern Hemisphere cooling 8200 years ago have been linked to the final melting of the Laurentide Ice Sheet. Although many studies associated this cold event with the drainage of Lake Agassiz-Ojibway, recent model simulations have shown that the Hudson Bay Ice Saddle collapse would have had much larger effects on the Atlantic Meridional Overturning Circulation than the lake outburst itself. Based on a combination of Mg/Ca and oxygen isotope ratios of benthic foraminifera, this study presents the first direct evidence of a major Labrador shelfwater freshening at 8.5 ka BP, which we associate with the Hudson Bay Ice Saddle collapse. The freshening is preceded by a subsurface warming of the western Labrador Sea, which we link to the strengthening of the West Greenland Current that could concurrently have accelerated the ice saddle collapse in Hudson Bay.
    Type: Article , PeerReviewed
    Format: text
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  • 6
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    PANGAEA
    In:  Supplement to: Lehmann, Nadine; Granger, Julie; Kienast, Markus; Brown, Kevin S; Rafter, Patrick A; Martínez Méndez, Gema; Mohtadi, Mahyar (2018): Isotopic evidence for the evolution of subsurface nitrate in the Western Equatorial Pacific. Journal of Geophysical Research: Oceans, 123(3), 1684-1707, https://doi.org/10.1002/2017JC013527
    Publication Date: 2023-03-03
    Description: Subsurface waters from both hemispheres converge in the Western Equatorial Pacific (WEP), some of which form the Equatorial Undercurrent (EUC) that influences equatorial Pacific productivity across the basin. Measurements of nitrogen (N) and oxygen (O) isotope ratios in nitrate (d15N-NO3 and d18O-NO3), the isotope ratios of dissolved inorganic carbon (d13C-DIC), and complementary biogeochemical tracers reveal that northern and southern WEP waters have distinct biogeochemical histories. Organic matter remineralization plays an important role in setting the nutrient characteristics on both sides of the WEP. However, remineralization in the northern WEP contributes a larger concentration of the nutrients, consistent with the older "age" of northern thermocline- and intermediate-depth waters. Remineralization introduces a relatively low d15N-NO3 to northern waters, suggesting the production of sinking organic matter by N2 fixation at the surface - consistent with the notion that N2 fixation is quantitatively important in the North Pacific. In contrast, remineralization contributes elevated d15N-NO3 to the southern WEP thermocline, which we hypothesize to derive from the vertical flux of high-d15N material at the southern edge of the equatorial upwelling. This signal potentially masks any imprint of N2 fixation from South Pacific waters. The observations further suggest that the intrusion of high d15N-NO3 and d18O-NO3 waters from the eastern margins is more prominent in the northern than southern WEP. Together, these north-south differences enable the examination of the hemispheric inputs to the EUC, which appear to derive predominantly from southern hemisphere waters.
    Keywords: Center for Marine Environmental Sciences; CTD/Rosette; CTD-RO; Date/Time of event; Density, mass density; Density, sigma-theta (0); DEPTH, water; Difference; EISPAC/WESTWIND; Elevation of event; Event label; GeoB17401-1; GeoB17403-1; GeoB17404-1; GeoB17407-1; GeoB17412-1; GeoB17413-2; GeoB17417-1; GeoB17420-1; GeoB17424-1; GeoB17426-1; GeoB17428-2; GeoB17432-1; GeoB17433-1; GeoB17434-1; GeoB17436-2; Latitude of event; Longitude of event; MARUM; Nitrate; Oxygen; Oxygen saturation; Phosphate; Pressure, water; Salinity; Silicate; SO228; Sonne; Temperature, water; δ13C, dissolved inorganic carbon; δ13C, dissolved inorganic carbon, standard deviation; δ15N, nitrate; δ15N, nitrate, standard deviation; δ18O, nitrate; δ18O, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 88998 data points
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  • 7
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    PANGAEA
    In:  Supplement to: Bostock, Helen C; Prebble, Joseph G; Cortese, Giuseppe; Hayward, Bruce William; Calvo, Eva; Quirós-Collazos, Lucía; Kienast, Markus; Kim, K (2019): Paleoproductivity in the SW Pacific Ocean During the Early Holocene Climatic Optimum. Paleoceanography and Paleoclimatology, 34(4), 580-599, https://doi.org/10.1029/2019PA003574
    Publication Date: 2023-01-30
    Description: In this study we examined a wide range of paleo-productivity proxies along a latitudinal transect (36-58°S) of 6 cores in the SW Pacific during the early Holocene climatic optimum, to explore regional patterns of productivity in a slightly warmer-than present world. We used a range of sedimentological, geochemical and paleontological proxies including carbonate content and mass accumulation rates, opal content and mass accumulation rates, alkenone concentrations, a foraminiferal productivity index and dinoflagellate cyst productivity index, nitrogen isotopes and elemental concentrations from micro-XRF. During the early Holocene there is a small increase in productivity in the subtropical waters, no change at the subtropical frontal zone, and conflicting evidence in records immediately south of the subtropical front, where an increase is inferred from one core site, but not at the other. Evidence for an increase in productivity in Antarctic Surface Waters south of the polar front, is also equivocal. We infer a small increase in productivity in subtropical waters and the ocean just south of the subtropical front was associated with changes in the ocean circulation of the SW Pacific, driven by changes in the Southern Hemisphere Westerly Winds split jet structure in this region.
    Keywords: Dinoflagellate cysts; Earth System Models; Foraminifera; paleoproductivity; Southern Hemisphere Westerly Winds; SW Pacific
    Type: Dataset
    Format: application/zip, 7 datasets
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  • 8
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    PANGAEA
    In:  Supplement to: Mirzaloo, Maryam; Nürnberg, Dirk; Kienast, Markus; van der Lubbe, H J L (2019): Synchronous Changes in Sediment Transport and Provenance at the Iceland‐Faroe Ridge Linked to Millennial Climate Variability From 55 to 6 ka BP. Geochemistry, Geophysics, Geosystems, 20(8), 4184-4201, https://doi.org/10.1029/2019GC008298
    Publication Date: 2023-01-30
    Description: We present lithogenic grain-size composition, high-resolution XRF bulk chemistry records, weighted coarse bulk fraction (〉150 μm) and the isotopic record of benthic foraminifera (C.wuellestorfi) of gravity sediment cores P457-905 and P57-909 from the southwestern flank of the Iceland-Faroe Ridge.
    Keywords: Dansgaard-Oeschger Oscillation; grain-size end-members; Iceland-Scotland Overflow; sediment provenances; sediment transport
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 9
    Publication Date: 2023-03-03
    Description: We present lithogenic grain-size composition, high-resolution XRF bulk chemistry records, weighted coarse bulk fraction (〉150 μm) and the isotopic record of benthic foraminifera (C.wuellestorfi) of gravity sediment cores P457-909 from the southwestern flank of the Iceland-Faroe Ridge.
    Keywords: AGE; Cibicidoides wuellerstorfi, δ13C; Cibicidoides wuellerstorfi, δ18O; Dansgaard-Oeschger Oscillation; DEPTH, sediment/rock; End member; GC; grain-size end-members; Gravity corer; Iceland-Scotland Overflow; Ice rafted debris; log-Titanium/Potassium ratio; log-Zirconium/Rubidium ratio; POS457; POS457_909-2; Poseidon; sediment provenances; sediment transport
    Type: Dataset
    Format: text/tab-separated-values, 1232 data points
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  • 10
    Publication Date: 2023-03-03
    Description: We present lithogenic grain-size composition, high-resolution XRF bulk chemistry records, weighted coarse bulk fraction (〉150 μm) and the isotopic record of benthic foraminifera (C.wuellestorfi) of gravity sediment cores P457-905 from the southwestern flank of the Iceland-Faroe Ridge.
    Keywords: AGE; Cibicidoides wuellerstorfi, δ13C; Cibicidoides wuellerstorfi, δ18O; Dansgaard-Oeschger Oscillation; DEPTH, sediment/rock; End member; GC; grain-size end-members; Gravity corer; Iceland-Scotland Overflow; Ice rafted debris; log-Titanium/Potassium ratio; log-Zirconium/Rubidium ratio; POS457; POS457_905-2; Poseidon; sediment provenances; sediment transport
    Type: Dataset
    Format: text/tab-separated-values, 2787 data points
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