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  • 2020-2024  (4)
  • 1
    Publikationsdatum: 2023-07-19
    Beschreibung: Large Igneous Provinces (LIPs) are unusual volcanic events in which massive amounts of melt (∼106 km3) erupt in relatively short time periods (〈106 years). Most LIP magmas have undergone extensive fractional crystallization and crustal contamination, but the crustal magmatic plumbing systems and the processes triggering eruptions are poorly understood. We present new major and trace element and radiogenic isotope data for 43 individual lava flows from a continuous 1,200 m thick stratigraphic profile through the upper, most voluminous part of the Deccan LIP (Bushe to Mahabaleshwar Formations). Eruption rates for this section are constrained by published paleomagnetic directions and absolute U‐Pb ages for zircons from weathered flow tops exposed in the profile. We find four magmatic sequences each lasting ∼104–∼105 years during which major and trace element compositions change systematically, followed by an abrupt change in geochemistry at the start of a new sequence. Within each sequence, the MgO content and proportion of crustal contamination decrease progressively, indicating a continuous replenishment of the associated magma reservoirs with less contaminated but more evolved melts. These geochemical signatures are best explained by repeated episodes of melt recharge, mixing, and eruption of variably evolved magmas originating from relatively small magma reservoir located in different crustal levels.
    Beschreibung: Plain Language Summary: Volcanism occurs predominantly at plate boundaries, either at mid‐ocean ridges or subduction zones, where most mantle melts are produced. However, the Earth's history is punctuated by volcanic events which are not related to plate boundary processes and during which large amounts of melt erupt (∼106 km3) in relatively short periods of time (〈106 years). These Large Igneous Provinces (LIPs) are associated with the activity of mantle plumes and eruption rates during their main stages are significantly higher than those of today's largest magmatic systems. However, since no LIP is currently active, the architecture of the associated plumbing systems is relatively unknown. In order to understand the magmatic processes during the emplacement of a LIP, we generated geochemical data from a continuous stratigraphic profile covering the most voluminous stage of the ∼66 Ma Deccan LIP. By combining these new data with published paleomagnetic directions and absolute U‐Pb ages for zircons, we found four eruption sequences each lasting ∼104–∼105 years. During these sequences, geochemical compositions change systematically, which is best explained by repeated episodes of melt recharge, mixing, and eruption of variably evolved magmas originating from relatively small magma reservoirs located at different crustal levels.
    Beschreibung: Key Points: Four recharge‐crystallization‐eruption sequences fed the most voluminous Deccan lava. Magmatic plumbing system with interconnected small‐ to medium‐sized magma reservoirs. Complex emplacement history including multiple stages of ascent, mixing, and storage.
    Beschreibung: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Beschreibung: https://doi.org/10.26022/IEDA/112672
    Schlagwort(e): ddc:551.9 ; intraplate processes ; magma chamber processes ; magma genesis and partial melting ; major and trace element geochemistry ; radiogenic isotope geochemistry
    Sprache: Englisch
    Materialart: doc-type:article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Publikationsdatum: 2024-02-07
    Beschreibung: Abundant volcanic activity occurs in the back-arc region of the northern Tofua island arc where the Northeast Lau Spreading Centre (NELSC) propagates southwards into older crust causing the formation of numerous seamounts at the propagating rift tip. An off-axis volcanic diagonal ridge (DR) occurs at the eastern flank of the NELSC, linking the large rear-arc volcano Niuatahi with the NELSC. New geochemical data from the NELSC, the southern propagator seamounts, and DR reveal that the NELSC lavas are tholeiitic basalts whereas the rear-arc volcanoes typically erupt lavas with boninitic composition. The sharp geochemical boundary probably reflects the viscosity contrast between off-axis hydrous harzburgitic mantle and dry fertile mantle beneath the NELSC. The new data do not indicate an inflow of Samoa plume mantle into the NELSC, confirming previously published He isotope data. The NELSC magmas form by mixing of an enriched and a depleted Indian Ocean-type upper mantle end-member implying a highly heterogeneous upper mantle composition in this area. Most NELSC lavas are little affected by a slab component implying that melting is adiabatic beneath the spreading center. The DR lavas show the influence of a component from the subducted Louisville Seamount Chain, which was previously thought to be restricted to the nearby arc volcanoes Niuatoputapu and Tafahi. This signature is rarely detected along the NELSC implying little mixing of melts from the low-viscosity hydrous portion of the mantle wedge beneath the rear-arc volcanoes into the melting region of the dry mantle beneath the NELSC.
    Materialart: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: other
    Format: other
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2023-12-11
    Beschreibung: Drill core samples from the Profitis Ilias Pb-Zn-Cu-Ag-Au vein mineralization on Milos Island, Greece provide new insights into (i) the metal sources, (ii) the primary vertical metal(loid) distribution, and (iii) the supergene enrichment processes in a transitional shallow-marine to subaerial hydrothermal environment. Metal contents of unaltered and altered host rocks combined with Pb isotope analyses of hydrothermal sulfides suggest that most metal(loid)s were derived by leaching of basement rocks, whereas the distinct enrichment of Te is related to the addition of Te by a magmatic fluid. The trace element contents of base metal sulfides record decreasing Au, Te, Se, and Co, but increasing Ag, Sb, and Tl concentrations with increasing elevation that can be related to progressive cooling and fluid boiling during the hypogene stage. The formation of base metal veins with porous pyrite hosting hessite inclusions at ~ 400 m below the surface was triggered by vigorous fluid boiling. By contrast, the enrichment of native Au associated with oxidized Fe and Cu phases in the shallower part of the hydrothermal system resulted from supergene remobilization of trace Au by oxidizing meteoric water after tectonic exhumation to subaerial levels. Disseminated pyrite with higher Tl/Pb ratios and locally elevated Hg concentrations relative to vein pyrite reflects infiltration of the host rocks by boiled liquids and condensed vapor fluids. The vertical and temporal evolution of the Profitis Ilias mineralization, therefore, provides unique insights into the transport and precipitation of Au, Ag, Te, and related metal(loid)s by multiple fluid processes.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2024-04-22
    Beschreibung: Seafloor massive sulfides are modern analogues to ancient volcanogenic massive sulfide deposits, which are particularly enriched in volatile and precious metals (e.g., Te, Au, Ag, Cu, Bi, Se) in subduction-related settings. However, the sources of metals are still poorly constrained, and it remains elusive, whether magmatic volatile influx controls their distribution in submarine hydrothermal systems on the plate tectonic-scale. Here, we demonstrate, for the first time, that Te, As, and Sb contents as well as related Te/As and Te/Sb ratios vary systematically with the δ34S composition of pyrite and native S, as reported by high-resolution coupled SIMS δ34S and trace element LA-ICP-MS micro-analysis. The better correlation of element ratios (Te/As, Te/Sb) opposed to trace element contents (e.g., Te) with δ34S in pyrite demonstrates that element ratios provide a more robust record of magmatic volatile influx than their absolute contents. On this basis, we define a quantitative threshold of high Te/As (〉0.004) and Te/Sb (〉0.6) ratios in pyrite that are indicative of magmatic volatile influx to submarine subduction-related hydrothermal systems. Two-component fluid mixing simulations further revealed that 〈5 % of magmatic volatile influx drastically changes the Te/As (and Te/Sb) ratio of the modelled fluid, but only slightly changes its δ34S composition. This suggests that Te/As and Te/Sb ratios are more sensitive to a magmatic volatile influx into seawater-dominated hydrothermal systems than δ34S signatures if the magmatic volatile influx was low. Beyond this, our results demonstrate that magma-derived fluid mixing with seawater only has a negligible effect on the magmatic volatile record of Te/As and Te/Sb, while the S isotope system is prone for seawater overprinting leading to commonly ambiguous source signatures. Thus, Te/As and Te/Sb systematics in pyrite provide a robust proxy to evaluate the contribution of magmatic volatiles to submarine hydrothermal systems from the grain- to plate tectonic-scale.
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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