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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 2807-2816 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 972-979 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We study the capillary wave model of the liquid–vapor interface and derive expressions valid in arbitrary dimensions for the density profile and the density–density pair correlation function. The latter is inverted to give an explicit expression for the direct correlation function. We examine the effects of long wavelength density fluctuations on these functions in dimensions d〈3 and discuss the applicability of the model to a real liquid–vapor system.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 6494-6505 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We compare the predictions of the capillary wave model for fluid interfaces with known exact expressions, due to Triezenberg, Zwanzig, and Wertheim, that relate the surface tension to the interfacial structure, and find agreement in all dimensions. It is shown that contrary to the case d〈3, the interfacial pair correlation function does not obey scaling in d=3 dimensions on length scales less than the capillary length Lc. Nevertheless, once the sensitive dependence on the gravitational field and the short distance cutoff is properly taken into account, we find no evidence for recent allegations that the capillary wave model leads to inherently inconsistent results for the direct correlation function in d=3. Several issues regarding the connection with density functional theory and the interpretation of the Triezenberg–Zwanzig formula, on which these results touch, are discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 4751-4760 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The potential energy between molecules is often represented as a sum of pairwise additive potentials for all atom pairs in both molecules. Such atomistic potentials encode much physical and chemical information, and in particular give an accurate representation of the molecular shape. However, the number of terms in the sum for a pair of molecules goes as N2 where N is the number of atoms in a molecule, and thus grows rapidly inefficient for large N. Starting with an atomistic pairwise additive potential for Copper Phthalocyanine (CuPc), a planar tile-shaped molecule with 57 atoms, we determine a simpler reduced intermolecular potential consisting of a sum of effective pair interactions between 13 appropriately chosen "interaction sites'' on each molecule. This potential reproduces many qualitative features of the full atomistic potential model for CuPc including the very anisotropic molecular shape, but is much easier to evaluate numerically, requiring only 1% as much computation time as the full atomistic potential. Crystal structures of CuPc using both the atomistic and reduced potentials are determined and compared, and a discussion of diffusion barriers is given. Some of the general issues and physical considerations that arise when attempting this reduction are discussed along with other possible applications of these ideas. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 93 (1989), S. 6969-6975 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 53 (2002), S. 533-562 
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract This article reviews a new and general theory of nonuniform fluids that naturally incorporates molecular scale information into the classical van der Waals theory of slowly varying interfaces. The method optimally combines two standard approximations, molecular (mean) field theory to describe interface formation and linear response (or Gaussian fluctuation) theory to describe local structure. Accurate results have been found in many different applications in nonuniform simple fluids and these ideas may have important implications for the theory of hydrophobic interactions in water.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 124 (1986), S. 383-414 
    ISSN: 1420-9136
    Keywords: Rock friction ; constitutive behaviour ; granite ; stability of sliding ; earthquake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract An understanding of the frictional sliding on faults that can lead to earthquakes requires a knowledge of both constitutive behavior of the sliding surfaces and its mechanical interaction with the loading system. We have determined the constitutive parameters for frictional sliding of initially bare surfaces of Westerly granite, using a recently developed high pressure rotary shear apparatus that allows long distances of sliding and therefore a greater assurance of attaining steady state behavior. From experiments conducted at room temperature and normal stresses of 27–84 MPa several important results have been found. (1) A gouge layer 100 to 200 μm thick was developed from the initially bare rock surfaces after 18 to 70 mm of sliding. (2) The steady state frictional resistance, attained after about 10 mm of sliding, is proportional to the negative of the logarithm of the sliding velocity. (3) Abrup changes in the velocity of sliding result in initial changes in the frictional resistance, which have the same sign as the velocity change, and are followed by a gradual decay to a new steady state value over a characteristic distance of sliding. This velocity weakening behavior is essentially identical with that found by several previous workers on the same material at lower normal stress. (4) Our results are well described by a two state variable constitutive law. The values of the constitutive parameters are quite similar to those found previously at low normal stress, but the characteristic distance is about an order of magnitude smaller than that found at 10 MPa normal stress with thicker layers of coarser gouge. (5) We have approximated our results with a one state variable constitutive law and compared the results with the predictions of existing nonlinear stability analysis; in addition, we have extended the stability analysis to systems possessing two state variables. With such formulations good agreement is found between the experimentally observed and theoretically predicted transitions between stable and unstable sliding. These results allow a better understanding of the instabilities that lead to earthquakes.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 125 (1987), S. 679-698 
    ISSN: 1420-9136
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1420-9136
    Keywords: Rock friction ; fault mechanics ; earthquakes ; serpentine ; constitutive behavior
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Laboratory studies of the frictional behavior of rocks can provide important information about the strength and sliding stability of natural faults. We have conducted friction experiments on antigorite and lizardite serpentinites, rocks common to both continental and oceanic crustal faults. We conducted both velocity-step tests and timed-hold tests on bare surfaces and gouge layers of serpentinite at room temperature. We find that the coefficient of friction of lizardite serpentinite is quite low (0.15–0.35) and could explain the apparent low stresses observed on crustal transform faults, while that of antigorite serpentinite is comparable to other crustal rocks (0.50–0.85). The frictional behavior of both types of serpentinite is well described by a two-mechanism model combining state-variable-dominated behavior at high slip velocities and flow-dominated behavior at low velocities. The two-mechanism model is supported by data from velocity-step tests and timed-hold tests. The low velocity behavior of serpentinite is strongly rate strengthening and should result in stable fault creep on natural faults containing either antigorite or lizardite serpentinite.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 64 (1991), S. 823-827 
    ISSN: 1572-9613
    Keywords: Liquid-vapor interface ; fluctuations ; scaling picture
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We argue that the capillary wave model provides an accurate description of long wavelength fluctuations of the liquid-vapor interface in three dimensions, provided that effects of external fields are properly taken into account.
    Type of Medium: Electronic Resource
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