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  • 1
    Publication Date: 2024-04-25
    Keywords: AGE; CDRILL; Core; Core drilling; DEPTH, sediment/rock; Foraminiferal geochemistry; Hole; Manganese/Iron ratio; Manganese/Titanium ratio; NGHP-01-01A; oxygen and carbon isotopes; Sample code/label; Section; Section position; Temperature; Titanium/Calcium ratio; trace element
    Type: Dataset
    Format: text/tab-separated-values, 72607 data points
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  • 2
    Publication Date: 2024-04-25
    Keywords: AGE; Calcium carbonate; Calcium carbonate, coarse fraction 〉 63 µm; CDRILL; Core; Core drilling; DEPTH, sediment/rock; Foraminifera, benthic δ13C; Foraminifera, benthic δ18O; Foraminifera, planktic, Magnesium/Calcium ratio; Foraminifera, planktic, Manganese/Calcium ratio; Foraminifera, planktic δ13C; Foraminifera, planktic δ18O; Foraminiferal geochemistry; Hole; Interval number; NGHP-01-01A; oxygen and carbon isotopes; Sample code/label; Sea surface temperature; Sea surface temperature, standard error; Section; Temperature; trace element; δ18O, seawater, reconstructed; δ18O, seawater, reconstructed, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 4005 data points
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  • 3
    Publication Date: 2024-04-25
    Description: The evolution of the South Asian monsoon (SAM) is not well-constrained prior to the Pleistocene, primarily due to a lack of recovered marine sediment archives. This study presents geochemical data from Site NGHP-01-01A in the eastern Arabian Sea from the Oligocene to Early Miocene (~32–20 Ma) to reconstruct the oceanographic evolution of this region through this interval. Analyses consist of planktic and benthic foraminiferal oxygen and carbon isotopes, and planktic foraminiferal trace elements (Mg/Ca and Mn/Ca), as well as seawater d18O (d18Osw) and Mg/Ca-derived temperatures. Along with XRF-derived elemental analysis, these reveal the Oligocene–Miocene transition (~23.7–22.7 Ma) to be a key initiation/intensification of the proto-SAM system, with the development of an intense oxygen minimum zone and monsoonal atmospheric circulation.
    Keywords: Foraminiferal geochemistry; oxygen and carbon isotopes; Temperature; trace element
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 4
    Publication Date: 2018-02-28
    Description: Modern analogs are an essential part of palaeoclimate studies, because they provide the basis for the understanding of geochemical signatures of fossils. Ostreoids are common in many sedimentary sequences and because of their fast growth, high temporal resolution sampling of past seasonal variability is possible. Here, two shell structures of modern Giant Pacific Oysters (Crassostrea gigas), the chalky substance and foliate layers, have been sampled for trace element distributions (Mg, Sr, Mn) and stable isotope variability (C, O, Ca). Oxygen isotopes exhibit a clear seasonal signature. Mean carbon isotope values of different oysters agree within 0.1‰, but ontogenic variability is complicated by shell growth patterns and potential small vital effects. The calcium isotope ratios are found to be constant throughout ontogeny within analytical precision at a value of δ44/40Ca = 0.68 ± 0.16‰ (2 sd) SRM–915a which is consistent with other bivalve species. Calcium isotope ratios in oyster shell material might thus be a possible proxy for palaeo seawater calcium isotope ratios. Element/Ca ratios are significantly higher in the chalky substance than in the foliate layers and especially high Sr/Ca and Mn/Ca ratios are observed for the first growth season of the oysters. Mg/Ca ratios in the chalky substance show a negative correlation with δ18O values, compatible with a temperature dependence, whereas this correlation is absent in the foliate layers. Seasonal changes of Sr/Ca are controlled by metabolic processes, whereas for Mn/Ca an additional environmental control is evident.
    Type: Article , PeerReviewed
    Format: text
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  • 5
    Publication Date: 2024-02-07
    Description: Petrography of recrystallised ikaite from Ocean Drilling Program material has been presented previously from Nankai Trough and Congo (ex-Zaire) deep-sea fan. This paper expands on the Nankai Trough ikaite observations, drawing on evidence from Laptev Sea, South Georgia, Okhotsk Sea, and coastal lagoon Point Barrow. However, even though many ikaite and glendonite sites occur at high latitudes, it cannot be that ikaite forms exclusively in polar environments, as demonstrated by the occurrences in the low latitude low temperature deep sea sediments offshore Gulf of Guinea (Angola Congo) and mid-latitude deep-sea trenches offshore Japan. Recrystallised ikaite occurs as mm large, zoned calcite crystals in all samples, along with secondary phases of calcite. Our data set is unique in that the origin, storage, and recrystallisation process of natural formed ikaite is recorded in detail and confirms that glendonite petrographic characteristics are a consequence of the structure and chemistry of recrystallising ikaite and not the physical or geochemical environment. The transformation of man-made ikaite to calcite as recorded in laboratory studies, is a process very similar to the one we have observed for natural ikaite. Most significant is that there is variation in the order of the calcite types within a single sample, leading to the conclusion that the variation is a consequence of impurities and geochemical variability in the ikaite, not the external environment. Morphological observations reveal similarities in ikaite and glendonite, this and the similarity in internal textures in glendonite and recrystallised ikaite confirms that glendonite may be used as an indicator of past presence of ikaite.
    Type: Article , PeerReviewed
    Format: text
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  • 6
    Publication Date: 2024-02-07
    Description: Marine sedimentary ikaite is the parent mineral to glendonite, stellate pseudomorphs found throughout the geological record which are most usually composed of calcite. Ikaite is known to be metastable at earth surface temperatures and pressures, readily breaking down to more stable carbonate polymorphs when exposed to warm (ambient) conditions. Yet the process of transformation of ikaite to calcite is not well understood, and there is an ongoing debate as to the palaeoclimatic significance of glendonites in the geological record. This study uses a combination of techniques to examine the breakdown of ikaite to calcite, outside of the ikaite growth medium, and to assess the palaeoclimatic and palaeoenvironmental significance of stable and clumped isotope compositions of ikaite-derived calcite. Powder X-ray diffraction shows that ikaite undergoes a quasi- solid-state transformation to calcite during heating of samples in air, yet when ikaite transforms under a high temperature differential, minor dissolution-recrystallisation may also occur with the ikaite structural waters. No significant isotopic equilibration to transformation temperature is observed in the resulting calcite. Therefore, in cases of transformation of ikaite in air, clumped and stable isotope thermometry can be used to reconstruct ikaite growth temperatures. In the case of ancient glendonites, where transformation of the ikaite occurred in contact with the interstitial waters of the host sediments over unknown timescales, it is uncertain whether the reconstructed clumped isotope temperatures reflect ikaite crystallisation or its transformation temperatures. Yet clumped and stable isotope thermometry may still be used conservatively to estimate an upper limit for bottom water temperatures. Furthermore, stable isotope along with element/Ca ratios shed light on the chemical environment of ikaite growth. Our data indicate that a range of (bio)geochemical processes may act to promote ikaite formation at different marine sedimentary sites, including bacterial sulphate reduction and anaerobic oxidation of methane. The colours of the ikaites, from light brown to dark brown, indicate a high organic matter content, favouring high rates of bacterial sulphate reduction as the main driver of ikaite precipitation. Highest Mg/Ca ratios are found in the most unstable ikaites, indicating that Mg acts to destabilise ikaite structure.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 7
    Publication Date: 2019-04-02
    Description: A high-resolution stratigraphic analysis of the Upper Cretaceous Gurpi Formation has been undertaken in the Shahneshin section (Zagros Basin, Iran). New results on calcareous nannofossils, planktic foramini- fers, dino fl agellate cysts and high-resolution carbon and oxygen stable isotopes form the basis of a reference section for the eastern Tethys that spans the upper Coniacian to the late Danian. Carbon- isotope correlation to Gubbio, Italy and the NW German chalk allows for the identi fi cation of many isotopic events as well as for the de fi nition of new events in the Campanian and Maastrichtian. Our results allow for a review of the accurate position of the Coniacian/Santonian, Santonian/Campanian, and Campanian/Maastrichtian stage boundaries relative to carbon isotopes and plankton bioevents. The reliability of Coniacian to Maastrichtian planktic foraminifer, dino flagellate cysts and calcareous nannofossil biohorizons is assessed.
    Description: Published
    Description: 312-340
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Beasley, C., Kender, S., Giosan, L., Bolton, C. T., Anand, P., Leng, M. J., Nilsson-Kerr, K., Ullmann, C. V., Hesselbo, S. P., & Littler, K. Evidence of a South Asian proto-monsoon during the Oligocene-Miocene transition. Paleoceanography and Paleoclimatology, 36(9), (2021): e2021PA004278, https://doi.org/10.1029/2021PA004278.
    Description: The geological history of the South Asian monsoon (SAM) before the Pleistocene is not well-constrained, primarily due to a lack of available continuous sediment archives. Previous studies have noted an intensification of SAM precipitation and atmospheric circulation during the middle Miocene (∼14 Ma), but no records are available to test how the monsoon changed prior to this. In order to improve our understanding of monsoonal evolution, geochemical and sedimentological data were generated for the Oligocene-early Miocene (30–20 Ma) from Indian National Gas Hydrate Expedition 01 Site NGHP-01-01A in the eastern Arabian Sea, at 2,674 m water depth. We find the initial glaciation phase (23.7–23.0 Ma) of the Oligocene-Miocene transition (OMT) to be associated with an increase in water column ventilation and water mass mixing, suggesting an increase in winter monsoon type atmospheric circulation, possibly driven by a relative southward shift of the intertropical convergence zone. During the latter part of the OMT, or “deglaciation” phase (23.0–22.7 Ma), a long-term decrease in Mn (suggestive of deoxygenation), increase in Ti/Ca and dissolution of the biogenic carbonate fraction suggest an intensification of a proto-summer SAM system, characterized by the formation of an oxygen minimum zone in the eastern Arabian Sea and a relative increase of terrigenous material delivered by runoff to the site. With no evidence at this site for an active SAM prior to the OMT we suggest that changes in orbital parameters, as well as possibly changing Tethyan/Himalayan tectonics, caused this step change in the proto-monsoon system at this intermediate-depth site.
    Description: This research forms part of a PhD study funded by the Natural Environment Research Council (NERC) Centre for Doctoral Training in Oil & Gas (grant number NE/M00578X/1) awarded to C. Beasley, and was also supported by a NERC National Environmental Isotope Facility Steering Committee grant (IP-1865-1118) awarded to S. Kender. L. Giosan acknowledges funding from USSP and WHOI and thanks colleagues from the NGHP-01 expedition. C. Ullmann acknowledges funding via NERC grant NE/N018508/1.
    Keywords: South Asian Monsoon ; Foraminiferal stable isotopes ; Trace elements ; Arabian Sea ; Oligocene-Miocene transition
    Repository Name: Woods Hole Open Access Server
    Type: Article
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