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  • 1
    Publication Date: 2022-01-07
    Description: Rivers are viewed as major pathways of microplastic transport from terrestrial areas to marine ecosystems. However, there is paucity of knowledge on the dispersal pattern and transport of microplastics in river sediments. In this study, a three dimensional hydrodynamic and particle transport modelling framework was created to investigate the dispersal and transport processes of microplastic particles commonly present in the environment, namely, polyethylene (PE), polypropylene (PP), polyamide (PA), and polyethylene terephthalate (PET) in river sediments. The study outcomes confirmed that sedimental microplastics with lower density would have higher mobility. PE and PP are likely to be transported for a relatively longer distance, while PA and PET would likely accumulate close to source points. High water flow would transport more microplastics from source points, and high flow velocity in bottom water layer are suggested to facilitate the transport of sedimental microplastics. Considering the limited dispersal and transport, the study outcomes indicated that river sediments would act as a sink for microplastic pollutants instead of being a transport pathway. The patchiness associated with the hotspots of different plastic types is expected to provide valuable information for microplastic source tracking.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2011-05-01
    Description: We present the first single-crystal Raman spectra of the mineral schafarzikite FeSb2O4 from the Pernek locality of the Slovak Republic. In addition, Raman spectra of the natural mineral apuanite Fe2+Fe43+Sb4O12S, originating from the Apuan Alps in Italy, as well as spectra of synthetic ZnSb2O4 and the arsenite mineral trippkeite (CuAs2O4) are presented for the first time. The spectra of the antimonite minerals are characterized by a strong band in the region 660-680 cm-1 with shoulders on either side, and a band of medium intensity near 300 cm-1. The spectrum of the arsenite mineral is characterized by a medium band near 780 cm-1 with a shoulder on the high wavenumber side and a strong band at 370 cm-1. Mode assignments are proposed based on the spectral comparison between the compounds, symmetry modes of the bands and prior literature. The single-crystal spectra of schafarzikite showed good mode separation, allowing bands to be assigned to the symmetry species of A1g, B1g, B2g, or Eg.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 3
    Publication Date: 2012-01-01
    Description: The single-crystal Raman spectra of the natural mineral paulmooreite Pb2As2O5 from the Långban, Filipstad district, Värmland province, Sweden, are presented for the first time. It is a monoclinic mineral containing an isolated [As2O5]4- dimer. Unpolarized single-crystal spectra of the natural and synthetic samples compare favorably with each other and are characterized by strong bands around 186 and 140 cm-1 and three medium bands at 800–700 cm-1. Band assignments were made based on band symmetry and spectral comparison between experimental band positions and those resulting from Hartree-Fock calculation of an isolated [As2O5]4- anion complex. Spectral comparison was also made with lead arsenites such as synthetic PbAs2O4 and Pb2(AsO2)3Cl and natural finnemanite to determine the contribution of the terminal and bridging O in paulmooreite. Bands at 760–733 cm-1 were assigned to terminal As-O vibrations, whereas stretches of the bridging O occur at 562 and 503 cm-1. The single-crystal spectra showed good mode separation, allowing bands to be assigned a symmetry species of Ag or Bg.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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