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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Chemistry of materials 4 (1992), S. 249-252 
    ISSN: 1520-5002
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-5002
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 5832-5834 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Sintered xerogel films (porous SiO2) show a higher elastic modulus than other amorphous low dielectric constant (K) materials available for the same value of K. By comparing xerogels that were sintered, templated or made with ethylene glycol or ethanol as solvents, we show that process history is at least as important as the chemistry of the solid matrix or the porosity. The modulus extrapolated to zero porosity for the porous sintered and templated films is the same as those of the dense films made by chemical vapor deposition of SiO2. This suggests that the solid matrix for sintered xerogel films is close to ideal and their modulus is better because of the ordered arrangement of pores and fusion of particles making up the matrix. The modulus measured by nanoindentation on thick xerogel films (〉0.8 μm) is well explained by the open cell foam model. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 6 (1994), S. 1963-1971 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Image Scanning Ellipsometry, a technique to measure the two-dimensional thickness profile of a nonuniform, thin, liquid film, from several nanometers up to tens of microns, in the steady and transient states, was developed and tested. The ability of this full-field imaging technique to map every point on the surface simultaneously was demonstrated by measuring the thickness profiles of very thin, draining, liquid films in the interfacial, transition, hydrodynamic, and capillary regions. Depending on the relative size of the intermolecular, gravitational, and capillary forces, four flow regions were identified. Using a simple model for the transient film thickness profiles of a completely wetting, draining film of FC-70, the experimental results were successfully analyzed in the interfacial, transition, and hydrodynamic regions. A diffusion coefficient for the junction line between the interfacial and transition regions was theoretically and experimentally evaluated.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 3275-3281 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Sintered xerogel films (porous SiO2) show a much higher thermal conductivity than other low dielectric constant (low-K) materials available for the same value of K. The thermal conductivity of xerogels which we have processed using different methods is compared with that of other low-K materials such as silica hybrid (silsesquioxanes) and polymeric low-K materials. The methods used were: (1) single solvent (ethanol) method, (2) binary solvent (mixture of ethanol and ethylene glycol) method, (3) sintering. For the xerogel films, we show that process history is as important as the chemistry of the solid matrix or the porosity in determining the thermal conductivity. The thermal conductivity, measured by the 3-ω method or the photothermal deflection method, is affected by phonon scattering, which in turn is effected by the size and distribution of pores and particles and the presence of imperfections such as interfaces, substituted chemical species, impurities, microcracks, and microporosity. The thermal conductivity extrapolated to zero porosity for porous sintered xerogel films approaches that of thermally grown SiO2 indicating the least phonon scattering of all processing methods. For these films, the elastic modulus is proportional to thermal conductivity squared, in agreement with theories developed for materials with few defects and a connected matrix. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2140-2149 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Isothermal profiles of the extended meniscus in a quartz cuvette were measured in the earth's gravitational field using an image-analyzing intefferometer thai is based on computaer-enhanced video microscopy of the naturally occurring ineetference fringes. These profiles are a function of the stress field. Experimentally, the augmented Young-Laplace equation is an excellent model for the force field at the solid-liquid-vapor intrfeces for heptane and pentane menisci on quartz and tetradecane on SFL6. Effects of refractive indices of the solid and liquid on the measurement techniques were demonsrrauzd. Experimentally obtained values of the disjoining pressure and dispersion constantswere compared to those predicted from the Dzyaloshiniskii-Lifshitz-Pitaevskii theory for an ideal surface and reasonableagreements were obtained. A parameter introduced gives a quantitative measurement of the closeness of the system to equilibrium. The nonequilibrium behavior of this parameter is also presented.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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