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  • 1
    In: Geochimica et cosmochimica acta, New York, NY [u.a.] : Elsevier, 1950, 72(2008), 12, Seite 2854-2867, 0016-7037
    In: volume:72
    In: year:2008
    In: number:12
    In: pages:2854-2867
    Type of Medium: Online Resource
    Pages: graph. Darst
    ISSN: 0016-7037
    Language: English
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  • 2
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    In:  Supplement to: Huguet, Carme; de Lange, Gert J; Gustafsson, Örjan; Middelburg, Jack J; Sinninghe Damsté, Jaap S; Schouten, Stefan (2008): Selective preservation of soil organic matter in oxidized marine sediments (Madeira Abyssal Plain). Geochimica et Cosmochimica Acta, 72(24), 6061-6068, https://doi.org/10.1016/j.gca.2008.09.021
    Publication Date: 2024-01-09
    Description: In ocean margin sediments both marine and terrestrial organic matter (OM) are buried but the factors governing their relative preservation and degradation are not well understood. In this study, we analysed the degree of preservation of marine isoprenoidal and soil-derived branched glycerol dialkyl glycerol tetraethers (GDGTs) upon long-term oxygen exposure in OM-rich turbidites from the Madeira Abyssal Plain by analyzing GDGT concentrations across oxidation fronts. Relative to the anoxic part of the turbidites ca. 7-20% of the soil-derived branched GDGTs were preserved in the oxidized part while only 0.2-3% of the marine isoprenoid GDGT crenarchaeol was preserved. Due to these different preservation factors the Branched Isoprenoid Tetraether (BIT) index, a ratio between crenarchaeol and the major branched GDGTs that is used as a tracer for soil-derived organic matter, substantially increases from 0.02 to 0.4. Split Flow Thin Cell (SPLITT) separation of turbidite sediments showed that the enhanced preservation of soil-derived carbon was a general phenomenon across the fine particle size ranges (〈38 mm). Calculations reveal that, despite their relatively similar chemical structures, degradation rates of crenarchaeol are 2-fold higher than those of soil-derived branched GDGTs, suggesting preferential soil OM preservation possibly due to matrix protection.
    Keywords: 157-951; 157-952; Atlantic; Canarias Sea; Carbon, organic, total; COMPCORE; Composite Core; DEPTH, sediment/rock; DSDP/ODP/IODP sample designation; Event label; Joides Resolution; Leg157; Ocean Drilling Program; ODP; PC; Piston corer; Preservation factor; Sample code/label; South Atlantic Ocean; Tyro_90P22; δ13C, organic carbon
    Type: Dataset
    Format: text/tab-separated-values, 80 data points
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  • 3
    Publication Date: 2016-02-01
    Description: That is suggested and widely accepted that a significant portion of the Great Siberian Rivers discharge comes to the Arctic ocean via submarine groundwater discharge (SGD). However, that statement was never proofed by observations. When groundwater discharges from the coastal aquifer to the ocean, the radium isotopes are transported with the groundwater, and they can be measured to trace and quantify SGD, and the flux of constituents associated with SGD. The primary goal of this study is to use radium isotopes to proof that SGD is existing in the Laptev Sea coastal zone close to the Lena River delta, which supposed to be characterized by continuous permafrost with thickness up to 600-800m. If so, we supposed to quantify methane fluxes to the coastal ocean through SGD. Discrete seawater, and Lena river water samples were collected from different horizons from the holes made in fast ice using submerged pump and Niskin bottle in the western part of Buor- Khaya Bay in March-April 2014 and 2015. We identified and traced SGD using short-lived radium (224Ra and 223Ra) and radon (222Rn) isotopes in complex with geophysical (electromagnetic technique), geological (sediment core results from 16 boreholes), hydrological (temperature, salinity), and hydrochemical (total alkalinity, dissolved methane and oxygen) data. It was found that the SGD is controlled by the processes associated with changing state of the subsea permafrost. Thus, this technique can give an unique information about the location of SGD “leakage” sites across the East Siberian Arctic Shelf, which represents 〉 80% of subsea permafrost existing in the entire Arctic ocean
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 4
    Publication Date: 2019-07-16
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 5
    Publication Date: 2017-10-11
    Description: It has been suggested that increasing freshwater discharge to the Arctic Ocean may also occur as submarine groundwater discharge (SGD), yet there are no direct observations of this phenomenon in the Arctic shelf seas. This study tests the hypothesis that SGD does exist in the Siberian-Arctic shelf seas but its dynamics may be largely controlled by complicated geocryological conditions such as permafrost. The field-observational approach in the southeast Laptev Sea used a combination of hydrological (temperature, salinity), geological (bottom sediment drilling, geoelectric surveys) and geochemical (224Ra, 223Ra and 222Rn) techniques. Active SGD was documented in the vicinity of the Lena River delta with two different operational modes. In the first system, groundwater discharges through tectonogenic permafrost talik zones was registered in both wintertime and summertime seasons. The second SGD mechanism was cryogenic squeezing out of brine and water-soluble salts detected on the periphery of ice hummocks in the wintertime season. The proposed mechanisms of groundwater transport and discharge in the arctic land-shelf system is elaborated. Through salinity versus 224Ra and 224Ra/223Ra diagrams, the three main SGD-influenced water masses were identified and their end-member composition was constrained. Further studies should apply these techniques to a broader scale with the objective to reach an estimate of the relative importance of the SGD transport vector relative to surface freshwater discharge for both the water balance and aquatic components such as dissolved organic carbon, carbon dioxide, methane, and nutrients.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 6
    Publication Date: 2022-07-04
    Description: The rapidly changing East Siberian Arctic Shelf (ESAS) receives large amounts of terrestrial organic carbon (OC) from coastal erosion and Russian-Arctic rivers. Climate warming increases thawing of coastal Ice Complex Deposits (ICD) and can change both the amount of released OC, as well as its propensity to be converted to greenhouse gases (fueling further global warming) or to be buried in coastal sediments. This study aimed to unravel the susceptibility to degradation, and transport and dispersal patterns of OC delivered to the ESAS. Bulk and molecular radiocarbon analyses on surface particulate matter (PM), sinking PM and underlying surface sediments illustrate the active release of old OC from coastal permafrost. Molecular tracers for recalcitrant soil OC showed ages of 3.4–13 14C-ky in surface PM and 5.5–18 14C-ky in surface sediments. The age difference of these markers between surface PM and surface sediments is larger (i) in regions with low OC accumulation rates, suggesting a weaker exchange between water column and sediments, and (ii) with increasing distance from the Lena River, suggesting preferential settling of fluvially derived old OC nearshore. A dual-carbon end-member mixing model showed that (i) contemporary terrestrial OC is dispersed mainly by horizontal transport while being subject to active degradation, (ii) marine OC is most affected by vertical transport and also actively degraded in the water column, and (iii) OC from ICD settles rapidly and dominates surface sediments. Preferential burial of ICD-OC released into ESAS coastal waters might therefore lower the suggested carbon cycle climate feedback from thawing ICD permafrost.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
    Format: application/pdf
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