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  • 1
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    PANGAEA
    In:  Supplement to: Gromov, Sergey; Brenninkemeijer, Carl A M; Jöckel, Patrick (2017): Uncertainties of fluxes and 13C/12C ratios of atmospheric reactive-gas emissions. Atmospheric Chemistry and Physics, 17(13), 8525-8552, https://doi.org/10.5194/acp-17-8525-2017
    Publication Date: 2023-07-05
    Description: We provide the estimate of the fluxes and 13C/12C ratios of a suite of reactive carbonaceous compounds emitted into the atmosphere. The data are based on an evaluated set-up of the EMAC model (EVAL2, doi:10.5194/gmd-3-717-2010). Please refer to the cited publication for details. Emission sources are integrated into the anthropogenic (ANT), biogenic (BIO) and biomass burning (BB) categories. On-line calculated emissions (e.g. C5H8) and pseudo-emission (nudging) data are not included. The ANT and BIO emissions refer to the year 2000, the BB emissions span the 1997-2005 period. Data for each category is encapsulated in a separate NetCDF file (ver. 4).
    Type: Dataset
    Format: application/zip, 195.6 MBytes
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  • 2
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    Copernicus Publications (EGU)
    In:  Atmospheric Chemistry and Physics, 16 (19). pp. 12477-12493.
    Publication Date: 2019-02-01
    Description: The self-cleaning or oxidation capacity of the atmosphere is principally controlled by hydroxyl (OH) radicals in the troposphere. Hydroxyl has primary (P) and secondary (S) sources, the former mainly through the photodissociation of ozone, the latter through OH recycling in radical reaction chains. We used the recent Mainz Organics Mechanism (MOM) to advance volatile organic carbon (VOC) chemistry in the general circulation model EMAC (ECHAM/MESSy Atmospheric Chemistry) and show that S is larger than previously assumed. By including emissions of a large number of primary VOC, and accounting for their complete breakdown and intermediate products, MOM is mass-conserving and calculates substantially higher OH reactivity from VOC oxidation compared to predecessor models. Whereas previously P and S were found to be of similar magnitude, the present work indicates that S may be twice as large, mostly due to OH recycling in the free troposphere. Further, we find that nighttime OH formation may be significant in the polluted subtropical boundary layer in summer. With a mean OH recycling probability of about 67%, global OH is buffered and not sensitive to perturbations by natural or anthropogenic emission changes. Complementary primary and secondary OH formation mechanisms in pristine and polluted environments in the continental and marine troposphere, connected through long-range transport of O3, can maintain stable global OH levels.
    Type: Article , PeerReviewed
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  • 3
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    Copernicus Publications (EGU)
    In:  Atmospheric Chemistry and Physics, 18 . pp. 9831-9843.
    Publication Date: 2021-02-08
    Description: Unexpectedly large seasonal phase differences between CH4 concentration and its 13C∕12C isotopic ratio and their inter-annual variations observed in southern hemispheric time series have been attributed to the Cl+CH4 reaction, in which 13CH4 is discriminated strongly compared to OH+CH4, and have provided the only (indirect) evidence of a hemispheric-scale presence of oxidative cycle-relevant quantities of tropospheric atomic Cl. Our analysis of concurrent New Zealand and Antarctic time series of CH4 and CO mixing and isotope ratios shows that a corresponding 13C∕12C variability is absent in CO. Using the AC-GCM EMAC model and isotopic mass balancing for comparing the periods of presumably high and low Cl, it is shown that variations in extra-tropical Southern Hemisphere Cl cannot have exceeded 0.9 × 103atomscm−3. It is demonstrated that the 13C∕12C ratio of CO is a sensitive indicator for the isotopic composition of reacted CH4 and therefore for its sources. Despite ambiguities about the yield of CO from CH4 oxidation (with this yield being an important factor in the budget of CO) and uncertainties about the isotopic composition of sources of CO (in particular biomass burning), the contribution of Cl to the removal of CH4 in the troposphere is probably much lower than currently assumed.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2021-05-04
    Description: Atmospheric temperature and ozone photochemistry are recognised to play dominant roles in setting the abundance of 18O18O isotopologues (expressed via Δ36) of atmospheric oxygen. Here, we use the AC-GCM EMAC to simulate the abundance of atmospheric 18O18O in a most consistent to date kinetic chemistry modelling framework. Extensive model diagnostics allow us quantifying contribution of various factors into changes in Δ36 since the last 60 years. It is shown that atmospheric dynamics is another fundamental ingredient of atmospheric Δ36 distribution. We discuss potential applications of clumped O2 composition for quantifying various atmospheric processes like decadal changes in tropospheric O3 abundance or tropopause warming due to volcanism.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 5
    Publication Date: 2024-02-07
    Description: Ice core and marine archives provide detailed quantitative records of last glacial climate changes, whereas comparable terrestrial records from the mid-latitudes remain scarce. Here we quantify warm season land-surface temperatures and precipitation over millennial timescales for central Europe for the period spanning 45,000–22,000 years before present that derive from two temporally overlapping loess-palaeosol-sequences, dated at high resolution by radiocarbon on earthworm calcite granules. Interstadial temperatures were 1–4 °C warmer than stadial climate, a temperature difference which is strongly attenuated compared to Greenland records. We show that climate in the Rhine Valley was significantly cooler during the warm season and overall drier with annual precipitation values reduced by up to 70% compared to the present day. We combine quantitative estimates with mesoscale wind and moisture transport modelling demonstrating that this region was dominated by westerlies and thereby inextricably linked to North Atlantic climate forcing, although ameliorated.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2024-02-07
    Description: It has long been hypothesized that the last glacial maximum (LGM) oversaw cold, arid, windy climates across southern Australia, and that these were driven by intensification and northward expansion of mid-latitude westerly circulation. Moreover, it was recently suggested that Australia experienced an extended LGM which began several millennia before the global peak. Aeolian sedimentary deposits provide key evidence for these hypotheses, and climate modelling an alternative means to test them. As yet, however, combined approaches to reconstructing glacial environments on the continent are scarce. Here we provide new evidence for westerly wind regimes across glacial southeastern Australia. We confirm active transverse lunette deposition at c. 29 ka and c. 23–19 ka in the semi-arid Willandra Lakes, and identify aeolian sand incursions to Spring Creek on the temperate Western Victorian Volcanic Plains from c. 29 ka. The Spring Creek deposits contain a surprising quantity of sand-sized quartz given the basalt setting, which we propose to be allochthonous and likely transported some distance. The site lies more than 50 km east and south of dunefields which were active at the same time and may have contributed sediment via long distance transport. We investigate the hypothesis for northward glacial expansion of westerly winds by combining our sediment records with aeolian particle transport simulations. We find that LGM near-surface winds were dominated by stronger, more focussed westerly air flow across southeastern Australia, compared with presently more diffuse wind regimes. Our results suggest stronger potential for LGM eastward distal sand transport onto the basalt plains, coeval with enhanced aeolian activity in the semi-arid Australian dunefields. Our combined reconstruction of aeolian deposition and trajectory modelling confirms the extended LGM hypothesis and indicates a northward migration of westerly winds over southeastern Australia during this period.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2024-02-07
    Description: Atmospheric methane (CH4) has changed considerably in the time between the last glacial maximum (LGM) and the preindustrial (PI) periods. We investigate these changes in transient experiments with an Earth system model capable of simulating the global methane cycle interactively, focusing on the rapid changes during the deglaciation, especially pronounced in the Bølling–Allerød (BA) and Younger Dryas (YD) periods. We consider all relevant natural sources and sinks of methane and examine the drivers of changes in methane emissions as well as in the atmospheric lifetime of methane. We find that the evolution of atmospheric methane is largely driven by emissions from tropical wetlands, while variations in the methane atmospheric lifetime are small but not negligible. Our model reproduces most changes in atmospheric methane very well, with the exception of the mid-Holocene decrease in methane, although the timing of ice-sheet meltwater fluxes needs to be adjusted slightly in order to exactly reproduce the variations in the BA and YD.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2023-08-01
    Description: Methane (CH4) is the second most important naturally occurring greenhouse gas (GHG) after carbon dioxide (Myhre G et al 2013 Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (Cambridge: Cambridge University Press) pp 659–740). For both GHGs, the present-day budget is dominated by anthropogenic emissions (Friedlingstein P et al 2019 Earth Syst. Sci. Data 11 1783–838; Saunois M et al 2020 Earth Syst. Sci. Data 12 1561–623). For CO2 it is well established that the projected future rise in atmospheric concentration is near exclusively determined by anthropogenic emissions (Ciais P et al 2013 Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Inter-governmental Panel on Climate Change (Cambridge: Cambridge University Press) pp 465–570). For methane, this appears to be the common assumption, too, but whether this assumption is true has never been shown conclusively. Here, we investigate the evolution of atmospheric methane until 3000 CE under five Shared Socioeconomic Pathway (SSP) scenarios, for the first time using a methane-enabled state-of-the-art Earth System Model (ESM). We find that natural methane emissions, i.e. methane emissions from the biosphere, rise strongly as a reaction to climate warming, thus leading to atmospheric methane concentrations substantially higher than assumed in the scenarios used for CMIP6. We also find that the natural emissions become larger than the anthropogenic ones in most scenarios, showing that natural emissions cannot be neglected.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2018-07-03
    Description: This work is devoted to the study of the process of partial oxidation of aluminum powder with hydrogen generation and the production of a metal-ceramic product that can be used in the production of various manufacturers such as additive manufacturing (AM) engineering technologies, machine building and so on. The released hydrogen can be effectively used in the form of an energy carrier that will contribute to reducing the cost of production and reduce the cost of the final product.
    Print ISSN: 1755-1307
    Electronic ISSN: 1755-1315
    Topics: Geography , Geosciences , Physics
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