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  • 1
    Keywords: Hochschulschrift ; Pazifischer Ozean ; Siliciumisotop ; Neodymisotop ; Biogeochemie
    Type of Medium: Online Resource
    Pages: Online-Ressource
    DDC: 550
    Language: English
    Note: Kiel, Univ., Diss., 2012
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  • 2
    Publication Date: 2018-03-13
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
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    In:  EPIC3Geochemistry, Geophysics, Geosystems, 13(1), pp. n/a-n/a, ISSN: 15252027
    Publication Date: 2018-03-13
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Reyes-Macaya, D., Hoogakker, B., Martinez-Mendez, G., Llanillo, P. J., Grasse, P., Mohtadi, M., Mix, A., Leng, M. J., Struck, U., McCorkle, D. C., Troncoso, M., Gayo, E. M., Lange, C. B., Farias, L., Carhuapoma, W., Graco, M., Cornejo-D’Ottone, M., De Pol Holz, R., Fernandez, C., Narvaez, D., Vargas, C. A., García-Araya, F., Hebbeln, D. Isotopic characterization of water masses in the Southeast Pacific Region: paleoceanographic implications. Journal of Geophysical Research: Oceans, 127(1), (2022): e2021JC017525, https://doi.org/10.1029/2021JC017525.
    Description: In this study, we used stable isotopes of oxygen (δ18O), deuterium (δD), and dissolved inorganic carbon (δ13CDIC) in combination with temperature, salinity, oxygen, and nutrient concentrations to characterize the coastal (71°–78°W) and an oceanic (82°–98°W) water masses (SAAW—Subantarctic Surface Water; STW—Subtropical Water; ESSW—Equatorial Subsurface water; AAIW—Antarctic Intermediate Water; PDW—Pacific Deep Water) of the Southeast Pacific (SEP). The results show that δ18O and δD can be used to differentiate between SAAW-STW, SAAW-ESSW, and ESSW-AAIW. δ13CDIC signatures can be used to differentiate between STW-ESSW (oceanic section), SAAW-ESSW, ESSW-AAIW, and AAIW-PDW. Compared with the oceanic section, our new coastal section highlights differences in both the chemistry and geometry of water masses above 1,000 m. Previous paleoceanographic studies using marine sediments from the SEP continental margin used the present-day hydrological oceanic transect to compare against, as the coastal section was not sufficiently characterized. We suggest that our new results of the coastal section should be used for past characterizations of the SEP water masses that are usually based on continental margin sediment samples.
    Description: R/V Sonne cruises (SO102, SO211 ad SO245) were financed by the German Federal Ministry of Education and Research projects #03G0102A, #03G0211A and #03G0245A. SO261 cruise was funded by the HADES-ERC Advanced Grant (“Benthic diagenesis and microbiology of hadal trenches” Grant agreement No. 669947) awarded to R. N. Glud (SDU, Denmark). SO245 cruise recived contributions from the Max Planck Society (Germany), the German State of Lower Saxony, the National Environmental Research Council of Great Britain and the Science Foundation of Ireland. R/V Meteor cruise M93 was financed by the Sonderforschungsbereich 754 “Climate-Biogeochemistry Interactions in the Tropical Ocean” (www.sfb754.de), which is supported by the Deutsche Forschungsgemeinschaft. “Expedición TAITAO” was financed by the grant “Concurso Nacional de Asignación de Tiempo de Buque ASG-61 Cabo de Hornos” AUB180003, FONDECyT grants 11161091 (DN), 1180954 (CF), and the COPAS Sur-Austral Center (CONICYT PIA APOYO CCTE AFB170006). Sampling at Time-Series station 18 off Concepción during 2015 was funded by several FONDECYT/ANID grants from researchers at the Department of Oceanography and Research Line 5 of COPAS Sur-Austral (UdeC). ANID—Chile National Competition for ship time (AUB 150006/12806) financed the expedition LowpHOX organized by the Millennium Institute of Oceanography (IMO). The expedition Crio1218 was financed by the PPR 137 titled “Proyecto de Estudio Integrado del Afloramiento Costero Frente a Perú" and sponsored by IMARPE-Perú. Additional funding was provided by the ANID—Millennium Science Initiative Program—NCN19_153 (Millennium Nucleus UPWELL), ANID/FONDAP (CR)2 15110009 (LF and EMG), FONDECYT Grant 1210171 (CAV), ANID/FONDAP IDEAL 15150003 (CBL), and the Millennium Institute of Oceanography (IMO, ICN12_019). Dharma A. Reyes-Macaya was supported by Becas Chile (17342817-0), DAAD (57144001) and FARGO project (FAte of ocean oxygenation in a waRminG wOrld, UKRI).
    Keywords: Oxygen and deuterium stable isotopes in seawater ; Carbon stable isotopes in dissolved inorganic carbon ; Southeast Pacific ; Water mass distribution ; Paleoceanography proxies
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2024-01-31
    Description: In this study, we used stable isotopes of oxygen (δ18O), deuterium (δD), and dissolved inorganic carbon (δ13CDIC) in combination with temperature, salinity, oxygen, and nutrient concentrations to characterize the coastal (71°–78°W) and an oceanic (82°–98°W) water masses (SAAW—Subantarctic Surface Water; STW—Subtropical Water; ESSW—Equatorial Subsurface water; AAIW—Antarctic Intermediate Water; PDW—Pacific Deep Water) of the Southeast Pacific (SEP). The results show that δ18O and δD can be used to differentiate between SAAW-STW, SAAW-ESSW, and ESSW-AAIW. δ13CDIC signatures can be used to differentiate between STW-ESSW (oceanic section), SAAW-ESSW, ESSW-AAIW, and AAIW-PDW. Compared with the oceanic section, our new coastal section highlights differences in both the chemistry and geometry of water masses above 1,000 m. Previous paleoceanographic studies using marine sediments from the SEP continental margin used the present-day hydrological oceanic transect to compare against, as the coastal section was not sufficiently characterized. We suggest that our new results of the coastal section should be used for past characterizations of the SEP water masses that are usually based on continental margin sediment samples.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
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  • 6
    Publication Date: 2021-02-08
    Description: Silicon (Si) is the second most abundant element in the Earth’s crust and is an important nutrient in the ocean. The global Si cycle plays a critical role in regulating primary productivity and carbon cycling on the continents and in the oceans. Development of the analytical tools used to study the sources, sinks, and fluxes of the global Si cycle (e.g., elemental and stable isotope ratio data for Ge, Si, Zn, etc.) have recently led to major advances in our understanding of the mechanisms and processes that constrain the cycling of Si in the modern environment and in the past. Here, we provide background on the geochemical tools that are available for studying the Si cycle and highlight our current understanding of the marine, freshwater and terrestrial systems. We place emphasis on the geochemistry (e.g., Al/Si, Ge/Si, Zn/Si, δ13 C, δ15 N, δ18 O, δ30 Si) of dissolved and biogenic Si, present case studies, such as the Silicic Acid Leakage Hypothesis, and discuss challenges associated with the development of these environmental proxies for the global Si cycle. We also discuss how each system within the global Si cycle might change over time (i.e., sources, sinks, and processes) and the potential technical and conceptual limitations that need to be considered for future studies.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2020-02-06
    Description: Highlights • High lithogenic input in surface waters in the Panama Basin results in radiogenic εNd of up to +4.3. • Radiogenic Nd derived from particles can reset the Nd IC of water masses within time scales years. • Lithogenic input of REEs and corresponding Nd IC in surface waters are seasonally influenced. The distribution of dissolved rare earth elements (REEs) and neodymium isotopes (εNd) in the open ocean traces water mass mixing and provides information on lithogenic inputs to the source regions of the water masses. However, the processes influencing the REE budget at the ocean margins, in particular source and sink mechanisms, are not yet well quantified. In this study the first dissolved REE concentrations and Nd isotope compositions of seawater from the Panama Basin (RV Meteor cruise M90) in the Eastern Equatorial Pacific (EEP) are presented. The EEP is characterized by one of the world's largest oxygen minimum zones (OMZs). It is dominated by high particle fluxes that are expected to enhance the removal of REEs from the water column by scavenging. The measured REE concentrations peak at the surface indicating high lithogenic input, which is supported by shale-normalized REE patterns in surface waters and highly radiogenic εNd signatures ranging between +1.4 and +4.3, the latter value constituting the most radiogenic value measured for seawater to date. In contrast, intermediate and deep water REE concentrations are low compared to other Pacific Basins and suggest enhanced removal via scavenging associated with high particle fluxes. The εNd signatures of intermediate and deep waters are less radiogenic than surface waters ranging between −1.4 and +1.3 but significantly more radiogenic than source water masses in the EEP. The εNd signatures consequently do not reflect mixing of intermediate and deep water masses entering the Panama Basin but can only be explained by lithogenic inputs originating from source rocks with highly radiogenic Nd isotope signatures such as the Central American Volcanic Arc (εNd=+3 to +10). Our data demonstrate significant surface input via continental particles, which are partially dissolved in the water column and thereby release REEs and particularly radiogenic Nd isotope signatures to the subsurface ocean. Data obtained from a re-occupied station in the southern Panama Basin for the first time shows that these processes can partially reset water mass Nd isotope and REE signatures of the entire water column proximal to continental sources on time scales of a few years.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2019-09-23
    Description: Dissolved silicon isotope compositions have been analysed for the first time in pore waters (δ30SiPW) of three short sediment cores from the Peruvian margin upwelling region with distinctly different biogenic opal content in order to investigate silicon isotope fractionation behaviour during early diagenetic turnover of biogenic opal in marine sediments. The δ30SiPW varies between +1.1‰ and +1.9‰ with the highest values occurring in the uppermost part close to the sediment–water interface. These values are of the same order or higher than the δ30Si of the biogenic opal extracted from the same sediments (+0.3‰ to +1.2‰) and of the overlying bottom waters (+1.1‰ to +1.5‰). Together with dissolved silicic acid concentrations well below biogenic opal saturation, our collective observations are consistent with the formation of authigenic alumino-silicates from the dissolving biogenic opal. Using a numerical transport-reaction model we find that approximately 24% of the dissolving biogenic opal is re-precipitated in the sediments in the form of these authigenic phases at a relatively low precipitation rate of 56 μmol Si cm−2 yr−1. The fractionation factor between the precipitates and the pore waters is estimated at −2.0‰. Dissolved and solid cation concentrations further indicate that off Peru, where biogenic opal concentrations in the sediments are high, the availability of reactive terrigenous material is the limiting factor for the formation of authigenic alumino-silicate phases.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2019-09-23
    Description: The stable silicon isotopic composition (δ30Si) of waters and diatoms has increasingly been used to investigate the biogeochemical cycling of Si in the major ocean basins. Here we present the first Si isotope data set from the northern South China Sea (NSCS), a large marginal sea system in the western North Pacific to examine sources and utilization of silicic acid (Si(OH)4). During two cruises in July–August 2009 (summer) and January 2010 (winter), samples for isotope measurements of dissolved Si(OH)4 (δ30SiSi(OH)4) and of biogenic silica (δ30SiBSi) in suspended particles were collected along a transect perpendicular to the coast from the inner shelf to the deep-water slope, as well as at the South East Asian Time-series Study (SEATS) station located in the NSCS basin. Surface δ30SiSi(OH)4 generally increased from values ∼+2.3‰ on the inner shelf to ∼+2.8‰ above the deep basin, suggesting an increasing utilization of dissolved Si(OH)4 reflecting the transition from eutrophic to oligotrophic conditions. The δ30SiBSi values were systematically lower than the corresponding δ30SiSi(OH)4 in the euphotic zone (above 100 m) on the shelf and slope. In contrast at station SEATS in the NSCS basin, δ30SiBSi signatures in both seasons were within error equal to δ30SiSi(OH)4 in the surface mixed layer (above 50 m) and δ30SiBSi in waters below were significantly higher than the corresponding δ30SiSi(OH)4. By comparing the field data with the Si isotope fractionation revealed by the Rayleigh or the steady state models, we demonstrate the existence of variable Si(OH)4 origins in different areas of the NSCS. Surface waters on the inner shelf were largely fed by nutrients from the Pearl River input. While the primary source of Si(OH)4 for the euphotic zone on the outer shelf and slope was upwelling or vertical mixing from underlying waters, the Si(OH)4 in the surface mixed layer of the NSCS basin might have originated from horizontal mixing with other highly fractionated surface waters. As a consequence, the Si isotope dynamics in the NSCS are largely controlled by variable biological fractionation of Si in waters from different sources with different initial Si isotopic compositions rather than any single source water.
    Type: Article , PeerReviewed
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  • 10
    Publication Date: 2019-09-23
    Description: We combine the stable silicon isotope composition (δ30Si) of diatoms and the radiogenic neodymium isotope compositions (εNd) of past seawater extracted from the authigenic fraction of the sediments (Mn–Fe coatings of particles and benthic foraminifers), as well as the radiogenic isotope compositions (Nd, Sr) of the detrital material itself to reconstruct silicic acid utilisation, water mass mixing, and upwelling intensity from the same marine sediments in the Peruvian upwelling region during the past 20,000 years. Additionally, the sedimentary signals were compared to the water column isotope compositions. Along the Peruvian shelf, the dissolved εNd in the water column ranges from −5.7 to +0.6. The corresponding εNd signatures of the coatings and the benthic foraminifers of the surface sediments range from −4.5 to +1.8 and from −2.5 to +2.2, respectively. The detrital εNd (87Sr/86Sr) signatures range from −6.3 to 0 (0.70508–0.71049). All phases show a trend from more radiogenic εNd values in the north towards less radiogenic values in the south broadly reflecting local weathering inputs and hinterland geology. The εNd signatures of the coatings extracted from sediment core SO147-106KL located in the present day centre of coastal upwelling near 12°S have been essentially constant (−1.5) throughout the past 20,000 years, while the detrital εNd (87Sr/86Sr) varied between values of −0.7 (0.70620) during the Last Glacial and −4.5 (0.70849) during the late Holocene reflecting changes in the origin of the sediment and current transport from a more northerly towards a more southerly source and from overall stronger to weaker upwelling. The δ30Si signature of both total biogenic opal (δ30Siopal) and of hand-picked diatoms (δ30Sidiatom) ranged from +0.3‰ (Last Glacial) to +1.4‰ (late Holocene) confirming large variations in upwelling intensity driving silicic acid utilisation by diatoms. Our combined bSiO2 MAR, δ30Siopal and detrital radiogenic isotope results demonstrate that the strongest El Niño-Southern Oscillation conditions off Peru of the past 20 ka have prevailed during the past 5 ka.
    Type: Article , PeerReviewed
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