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  • 1
    Online Resource
    Online Resource
    La Vergne :Royal Society of Chemistry, The,
    Keywords: Organometallic chemistry. ; Chemistry, Organic. ; Electronic books.
    Description / Table of Contents: This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.
    Type of Medium: Online Resource
    Pages: 1 online resource (189 pages)
    Edition: 1st ed.
    ISBN: 9781847558466
    Series Statement: Issn Series
    DDC: 547.05
    Language: English
    Note: Organometallic Chemistry -- CONTENTS -- Preface -- Samarium enolates and their application in organic synthesis -- Samarium enolates-an introduction -- Samarium(II) iodide in organic synthesis -- The formation and use of samarium enolates -- Conclusions -- Metal boryl compounds and metal-catalysed borylation processes: synthetic applications and mechanistic considerations -- Introduction -- Synthesis and reactivity of a novel lithium boryl compound -- Copper boryl complexes and Cu-catalysed borylation reactions -- Copper catalysed reduction of CO2 to CO -- Copper catalysed diboration of aldehydes -- Nucleophilicity of copper boryl complexes-a return -- Diboration of unsaturated carbon-carbon bonds employing Cu, Ag, and Au-NHC systems -- β-boryl elimination processes -- Catalysed borylation of C-H bonds -- Conclusions -- Organometallics in ionic liquids-catalysis and coordination chemistry -- A brief introduction to ionic liquids -- Metal-containing ionic liquids and related salts -- Preparative organometallic chemistry in ionic liquids -- Catalysis with metal complexes in ionic liquids -- Mechanistic investigations -- Spectroscopic investigations -- Concluding remarks -- Groups 1 and 11: the alkali and coinage metals -- Alkali metals -- Copper, silver and gold -- Group 2 (Be-Ba) and Group 12 (Zn-Hg) -- Scope and organisation of the reviews for 2004 and 2005 -- Review of 2004 -- Review of 2005 -- Scandium, yttrium and the lanthanides -- Introduction -- Hydrocarbyls of various kinds -- Allyls -- Cyclopentadienyl-based ancillaries -- COT chemistry -- Carborane-based supporting ligands -- Redox chemistry -- Nitrogen-based ancillary ligand systems -- Organometallics in materials synthesis -- Polymerization chemistry -- Spectroscopy -- Gas phase studies -- Theoretical studies -- Organolanthanides in organic synthesis. , Group 14: silicon, germanium, tin and lead -- Introduction -- A silicon-silicon triple bond -- Other multiply bonded Group 14 compounds -- Aromatic compounds -- Transition metal complexes of heavy Group 14 ligands -- Cyclopentadienyl derivatives -- Organo-transition metal cluster complexes -- Introduction -- Spectroscopic studies -- Theory -- Structural studies -- High-nuclearity clusters -- Group 6 -- Group 8 -- Group 9 -- Group 10 -- Group 11 -- Mixed-metal clusters -- Clusters containing three different metals.
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  • 2
    Keywords: Life on other planets--Research--United States--History. ; Unidentified flying objects--Research--United States--History. ; Life on other planets--Research. ; Vie extraterrestre--Recherche--États-Unis--Histoire. ; Ovnis--Recherche--États-Unis--Histoire. ; Vie extraterrestre--Recherche. ; United States--Research--History. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (648 pages)
    Edition: 1st ed.
    ISBN: 9781982196790
    DDC: 999
    Language: English
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  • 3
    Description / Table of Contents: This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry, Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Volume 34 covers literature published up to January 2006
    Type of Medium: Online Resource
    Pages: Online-Ressource (190 p) , ill., strated with chemical structures throughout
    Edition: RSC eBook Collection 1968-2009
    ISBN: 1847558461 , 9781847558466
    Series Statement: Specialist periodical reports v. 34
    Language: English
    Note: Ebook
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © The Authors, 2010. This article is posted here by permission of John Wiley & Sons for personal use, not for redistribution. The definitive version was published in Geophysical Journal International 183 (2010): 313-329, doi:10.1111/j.1365-246X.2010.04720.x.
    Description: The Hawaiian Islands are the canonical example of an age-progressive island chain, formed by volcanism long thought to be fed from a hotspot source that is more or less fixed in the mantle. Geophysical data, however, have so far yielded contradictory evidence on subsurface structure. The substantial bathymetric swell is supportive of an anomalously hot upper mantle, yet seafloor heat flow in the region does not appear to be enhanced. The accumulation of magma beneath pre-existing crust (magmatic underplating) has been suggested to add chemical buoyancy to the swell, but to date the presence of underplating has been constrained only by local active-source experiments. In this study, teleseismic receiver functions derived from seismic events recorded during the PLUME project were analysed to obtain a regional map of crustal structure for the Hawaiian Swell. This method yields results that compare favourably with those from previous studies, but permits a much broader view than possible with active-source seismic experiments. Our results indicate that the crustal structure of the Hawaiian Islands is quite complicated and does not conform to the standard model of sills fed from a central source. We find that a shallow P-to-s conversion, previously hypothesized to result from the volcano-sediment interface, corresponds more closely to the boundary between subaerial and subaqueous extrusive material. Correlation between uplifted bathymetry at ocean-bottom-seismometer locations and presence of underplating suggests that much of the Hawaiian Swell is underplated, whereas a lack of underplating beneath the moat surrounding the island of Hawaii suggests that underplated crust outward of the moat has been fed from below by dykes through the lithosphere rather than by sills spreading from the island centre. Local differences in underplating may reflect focusing of magma-filled dykes in response to stress from volcanic loading. Finally, widespread underplating adds chemical buoyancy to the swell, reducing the amplitude of a mantle thermal anomaly needed to match bathymetry and supporting observations of normal heat flow.
    Description: We are grateful to the Ocean Sciences Division of the U.S. National Science Foundation for their support of this project under grants OCE-0002470, OCE-0002552 and OCE-0002819.
    Keywords: Heat flow ; Body waves ; Hotspots ; Crustal structure
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/postscript
    Format: application/pdf
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1965-1969 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We use the asymmetry of beam coupling with respect to the orientation of the polar axis in a nominally undoped barium titanate crystal to determine the electro-optic and absorptive "gain'' in the usual beam-coupling geometry. For small grating wave vectors, the electro-optic coupling vanishes but the absorptive coupling remains finite and positive. Positive absorptive coupling at small grating wave vectors is correlated with the light-induced transparency of the crystal described herein. The intensity and grating wave vector dependence of the electro-optic and absorptive coupling, and the light-induced transparency are consistent with a model incorporating deep and shallow levels.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1471-4159
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Abstract: Levels of dopamine (DA), 3,4-dihydroxyphenylacetic acid (DOPAC), homovanillic acid (HVA), noradrenaline (NA), 3-methoxy-4-hydroxyphenylglycol (MHPG), and 5-hydroxyindoleacetic acid (5-HIAA) in the CSF of patients with Huntington's disease (HD) were measured by HPLC. CSF DA, DOPAC, and MHPG levels were found to be increased in HD patients. Levels of HVA, 5-HIAA, and NA in the CSF of HD patients did not differ from those of controls. Changes in CSF DA and DOPAC levels were consistent with previous findings of increased DA tissue content in some brain areas of patients with HD. These results suggest that CSF DOPAC levels could be a more reliable index of over-active dopaminergic brain systems in HD than CSF HVA levels.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 63 (1993), S. 3598-3600 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report intensity dependent absorption and transparency as a function of wavelength for barium titanate. The BaTiO3 crystal examined has an as-grown, light-blue color due to an absorption centered at 690 nm, and when reduced in a partial pressure of 10−15 atm of oxygen it has a yellow-orange color due to an absorption centered at 470 nm. Both energy levels are active in the reduced sample as revealed in the spectrum of the intensity dependent changes in absorption.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 1079-1081 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Optical low coherence reflectometry is applied to measure with μm precision the type, position and length of gratings inside a barium-titanate crystal producing self-pumped phase conjugation. In this particular crystal it shows the presence of an internal resonator due to reflections on faces of the crystal. Moreover, it was possible to measure the simultaneous presence of transmission and reflection gratings with conjugation efficiencies of 40% and 3%, respectively. The spectral reflectivity of the transmission grating is Gaussian-like with a full width at half-maximum=1.5 nm. The six reflection gratings, each with a length of 116±6 μm, are due to the multimode spectrum of the writing laser.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 63 (1993), S. 3399-3401 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present concrete evidence for the formation of ferroelectric domain gratings induced by photorefractive space-charge electric fields in top-seeded solution-grown barium titanate crystals. These domain gratings are not destroyed by light and, by applying a field, can be reconverted into photorefractive gratings that diffract much more light than the photorefractive gratings that create them, as much as 67% of an incident beam.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1398-9995
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Background Eighty households in the Latrobe Valley, Victoria, Australia, were sampled for house-dust-mite allergen (Der p 1). Allergen levels vary greatly between houses within climate regions. The reasons for this are not well understood. Methods House-dust-mite allergen samples were collected on six occasions between March 1994 and February 1995, All participating households contained at least one child between 7 and 14 years with a total of 148 subjects, 53 of whom were asthmatic. A detailed house survey was performed during every sampling visit, and a dwelling questionnaire was completed. Relative humidity was measured at the time of sample collection. Results The median bed allergen level was 30 ng/g during the first sampling period. Significantly higher allergen levels were associated with wool bedding and inner-spring mattresses (p 〈 0.001). As estimated from a multiple linear regression model, up to 70% reduction in bed allergen levels may be achieved by avoiding wool bedding and inner-spring mattresses. Other risk factors for high allergen levels included high indoor relative humidity, presence of substantial visible mould growth, brick cladding, and concrete slab foundation of the house. Conclusions Avoiding wool bedding and replacing inner-spring mattresses with foam could substantially reduce bed allergen levels.
    Type of Medium: Electronic Resource
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