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  • 1
    Keywords: Forschungsbericht
    Type of Medium: Online Resource
    Pages: Online-Ressource (154 S., 12,3 MB) , Ill., graph. Darst.
    Series Statement: Institutsbericht / Institut für Flugmechanik, Deutsches Zentrum für Luft- und Raumfahrt 2014,5
    Language: German
    Note: Förderkennzeichen BMBF 20H0601D. - Verbund-Nr. 01052154 , Unterschiede zwischen dem gedruckten Dokument und der elektronischen Ressource können nicht ausgeschlossen werden , Systemvoraussetzungen: Acrobat reader.
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Formation of bonelike apatite on zirconia gel in a simulated body fluid (SBF) with ion concentrations almost equal to those in human blood plasma, in modified SBF solutions to have increased pH values, and modified SBF solutions to have increased concentrations of calcium and phosphate ions has been investigated. The zirconia gel forms apatite on its surface in SBF, indicating that Zr-OH groups, abundant on the gel, act as effective apatite nucleation centers. Apatite formation is accelerated by increases in pH and in the concentration of calcium and phosphate ions, which is explained by an increase in the ionic activity product of the apatite in the SBF. These results suggest that zirconia ceramics may exhibit a bone-bonding ability by forming an apatite layer on their surfaces in the living body when they are modified to have many Zr-OH groups on their surfaces.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 1942-1944 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of an alcohol-based (NH4)2S solution [t-C4H9OH+(NH4)2S] treatment on Pt Ohmic contacts to p-type GaN are presented. The specific contact resistance decreased by three orders of magnitude from 2.56×10−2 to 4.71×10−5 Ω cm2 as a result of surface treatment using an alcohol-based (NH4)2S solution compared to that of the untreated sample. The O 1s and Pt 4f core-level peaks in the x-ray photoemission spectra showed that the alcohol-based (NH4)2S treatment was effective in removing of the surface oxide layer. Compared to the untreated sample, the alcohol-based (NH4)2S-treated sample showed a Ga 2p core-level peak which was shifted toward the valence-band edge by 0.25 eV, indicating that the surface Fermi level was shifted toward the valence-band edge. These results suggest that the surface barrier height for hole injection from Pt metal to p-type GaN can be lowered by the surface treatment, thus resulting in a drastic reduction in specific contact resistance. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 1766-1768 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The results of the sulfur treatment of multiple-quantum-well (MQW) light-emitting diodes (LEDs) with (NH4)2S and (NH4)2S+t-C4H9OH solutions prior to the deposition of a light-transmitting p-electrode metal are presented. The room-temperature I–V curves showed that the forward voltages of MQW LEDs treated with the two sulfur solutions decrease by 0.12 and 0.35 V at 20 mA, respectively, compared to the untreated MQW LED, as the result of an improvement in p-Ohmic contact characteristics. The relative light-output power and external quantum efficiency of MQW LEDs increased by a factor of 1.28 for the (NH4)2S treated sample and 2.23 for the (NH4)2S+t-C4H9OH treated sample compared to the untreated sample. In addition, the reverse leakage current characteristic of MQW LEDs was reduced as a result of sulfur treatment. This can be attributed to the passivation of surface and sidewall damages formed after the dry-etching process for a reliable pattern transfer. The present results indicate that the sulfur treatment greatly improves the electrical and optical performance of MQW LEDs. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1520-5002
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Alumina–glass composites that contain oxidized aluminum were investigated to make shrinkage-free, all-ceramic dental porcelain. This was achieved by control of the volume expansion and shrinkage that occur during the aluminum oxidation and densification processes. The dimensional change and strength of the alumina-glass composites were dependent on the aluminum content and particle size. A shrinkage-free sample with a strength of 330 MPa and transmittance of 1.21 was fabricated by using 4-5 vol% of aluminum powder with an average particle size of 6 μ m in the alumina-glass composite made by the In-Ceram method.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The process of apatite formation on the surface of Na2O–SiO2 glass in a body environment was investigated, mainly by X-ray photoelectron spectroscopy, as a function of soaking time in a simulated body fluid (SBF). The glass was found to release Na+ ions via exchange with H3O+ ions in the SBF to form Si—OH groups on its surface. These Si—OH groups induced apatite formation indirectly, by forming calcium silicate and amorphous calcium phosphate. The formation of the calcium silicate and amorphous calcium phosphate is attributed to electrostatic interactions between the Si—OH groups on the glass surface and the calcium and phosphate ions in the SBF.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An essential condition for an artificial material to bond to living bone is the formation of bonelike apatite on its surface in the living body. The bonelike apatite can be reproduced on the bone-bonding material even in an acellular simulated body fluid (SBF) with ion concentrations almost equal to those of human blood plasma. In the present study, the dependence of the apatite-forming abilities of sodium-containing titania gels in a SBF on composition and structure is examined. The sodium-containing titania gels are model substances produced on the surface layer of bioactive titanium metal prepared by sodium hydroxide solution and heat treatments. When sodium-containing titania gels are immersed in the SBF, Na+ ions incorporated in the gels are exchanged with the H3O+ ions in the SBF. This ion exchange causes an accompanying increase in the pH of the SBF and increases its ionic activity product, thus providing favorable conditions for apatite nucleation on the surfaces of the gels. Nevertheless, sodium-containing titania gels that do not contain anatase do not form apatite on their surfaces. Independent of the composition, the gels form apatite on their surfaces in the SBF, specifically when they contain anatase. These results imply that the Ti-OH groups on titania, which have been proposed to be responsible for the apatite formation, are effective for apatite nucleation when they are arranged in a specific structural unit based on the anatase structure.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 192 (1991), S. 1033-1040 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A series of rigid rod-like polyspiroacetals bearing flexible side chains was prepared by interfacial polycondensation of 4,4′-(2,4,8,10-tetraoxaspiro[5,5]undecane-3,9-diyl)diphenol with 2,5-dialkoxy-substituted terephthaloyl dichlorides. The majority of these polymers were soluble in polar solvents like tetrahydrofuran (THF), dimethylformamide (DMF), CHCl3, phenol/CCl4 (1 : 1 by vol.) mixtures, etc. The molecular weights ranged from 7 600 to 15 000 and the melting temperature from 182 to 228°C. Both of the above values decreased with increasing length of the side chains. The TG curves revealed 5% weight loss at 350-370°C under N2 gas atmosphere. Wide-angle X-ray diffractograms showed that all of the polymers have considerable crystallinity at room temperature.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 32 (1996), S. 409-417 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A simple chemical method was established for inducing bioactivity of Ti and its alloys. When pure Ti, Ti-6Al-4V, Ti-6Al-2Nb-Ta, and Ti-15Mo-5Zr-3Al substrates were treated with 10M NaOH aqueous solution and subsequently heat-treated at 600°C, a thin sodium titanate layer was formed on their surfaces. Thus, treated substrates formed a dense and uniform bonelike apatite layer on their surfaces in simulated body fluid (SBF) with ion concentrations nearly equal to those of human blood plasma. This indicates that the alkali- and heat-treated metals bond to living bone through the bonelike apatite layer formed on their surfaces in the body. The apatite formation on the surfaces of Ti and its alloys was assumed to be induced by a hydrated titania which was formed by an ion exchange of the alkali ion in the alkali titanate layer and the hydronium ion in SBF. The resultant surface structure changed gradually from the outermost apatite layer to the inner Ti and its alloys through a hydrated titania and titanium oxide layers. This provides not only the strong bonding of the apatite layer to the substrates but also a uniform gradient of stress transfer from bone to the implants. The present chemical surface modification is therefore expected to allow the use the bioactive Ti and its alloys as artificial bones even under load-bearing conditons. © 1996 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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