Keywords:
Group 13 elements.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (752 pages)
Edition:
1st ed.
ISBN:
9780470976531
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=661765
DDC:
546.67
Language:
English
Note:
The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities -- Contents -- Preface -- List of Contributors -- 1 New Light on the Chemistry of the Group 13 Metals -- 1.1 Reprise of the General Features of Group 13 Elements -- 1.2 Developments in Methodology -- 1.3 Redox Chemistry of the Group 13 Metals: Access to Oxidation States Lower than +3 -- 1.4 Bonding Aspects -- 1.5 Solid Compounds with Specific Electronic, Structural or Other Properties -- 1.6 Coordination Chemistry of M(III) Compounds8,10,12,51,52,318 -- 1.7 Mediation of Organic Transformations by Group 13 Metal Compounds -- References -- 2 The Chemistry of the Group 13 Metals in the +3 Oxidation State: Simple Inorganic Compounds -- 2.1 Introduction -- 2.2 Hydrides -- 2.3 Halides and Pseudo-Halides -- 2.4 Oxides and Oxo- Derivatives -- 2.5 Chalcogenides and Chalco-Derivatives -- 2.6 Compounds with Bonds to Group 15 Atoms -- References -- 3 Formal Oxidation State +3: Organometallic Chemistry -- 3.1 Introduction -- 3.2 Organo Derivatives with a Metal-Carbon Primary Framework -- 3.3 Derivatives with Bonds to Group 15 Elements -- 3.4 Derivatives with Bonds to Group 16 Elements -- 3.5 Organometal Halides -- 3.6 Organometal Hydrides -- 3.7 d-Block and f-Block Compounds with Organo-Group 13 Metal(III) Fragments -- References -- 4 Formal Oxidation State +2: Metal-Metal Bonded Versus Mononuclear Derivatives -- 4.1 Introduction -- 4.2 Subhalides Containing M--M Bonds -- 4.3 Homoleptic Chalcogen Compounds -- 4.4 Homoleptic Dielement Compounds with Pnicogen Atoms Coordinated to theM--MBonds -- 4.5 Heteroleptic Compounds Containing Donor Atoms of Groups 15 to 17 -- 4.6 Homoleptic Dinuclear Organoelement(II) Compounds -- 4.7 Heteroleptic Organoelement(II) Compounds -- 4.8 Mononuclear Element(II) Compounds -- References.
,
5 The Chemistry of the Group 13 Metals in the +1 Oxidation State -- 5.1 Introduction -- 5.2 Aluminium -- 5.3 Gallium -- 5.4 Indium -- 5.5 Thallium -- References -- 6 Mixed or Intermediate Valence Group 13 Metal Compounds -- 6.1 Mixed Valency -- 6.2 Halides -- 6.3 Arene-stabilised Mixed Valent Species -- 6.4 Chalcogenide and Other Non-Halide Salts -- 6.5 Discretely Bonded Systems -- 6.6 Donor-Acceptor Compounds -- 6.7 Conclusions -- References -- 7 Aluminium and Gallium Clusters: Metalloid Clusters and their Relationship to the Bulk Phases, to Naked Clusters and to Nanoscaled Materials -- 7.1 Introduction -- 7.2 Explanations of Special Terms -- 7.3 The Naked Al13ˉ Cluster -- 7.4 Metalloid Al/Ga Clusters -- 7.5 Interactions between Cluster Species within the Crystal -- 7.6 Summary and Outlook -- References -- 8 Simple and Mixed Metal Oxides and Hydroxides: Solids with Extended Structures of Different Dimensionalities and Porosities -- 8.1 Introduction -- 8.2 The Parent Oxides and Hydroxides -- 8.3 Layered Materials -- 8.4 Framework Materials -- References -- 9 Coordination and Solution Chemistry of the Metals: Biological, Medical and Environmental Relevance -- 9.1 Introduction -- 9.2 Hydrides -- 9.3 Halides -- 9.4 Group 13 Complexes of N-donor Ligands -- 9.5 Complexes of the Monovalent M(I) Group 13 Metals -- 9.6 Divalent M(II) Complexes -- 9.7 Chemistry Relevant to Environmental and Biological Systems -- 9.8 Environmental Abundances, Uses and Sources -- 9.9 Biological Systems -- References -- 10 III-V and Related Semiconductor Materials -- 10.1 Introduction -- 10.2 III-Nitrides -- 10.3 III-Phosphides -- 10.4 III-Arsenides -- 10.5 III-Antimonides -- References -- 11 Group 13 Metal-Mediated Organic Reactions -- 11.1 Aluminium -- 11.2 Gallium -- 11.3 Indium -- 11.4 Thallium -- References -- Index -- Colour Plates.
Permalink