ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The stoichiometry, kinetics and mechanism of oxidation of N-(2-hydroxyethyl)ethylenediamine triacetate by K5CoIIIW12O40, Fe(phen) inf3 sup3+ and Fe(bipy) inf3 sup3+ have been studied. Each reaction is first order with respect to the oxidant and the reductant, but retarded by [H+] in the 0.20–1.60 mol dm −3 range. Simple electron exchanges are thought to occur, leading to the decarboxylation of the substrate.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00136607
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