Summary
The stoichiometry, kinetics and mechanism of oxidation of N-(2-hydroxyethyl)ethylenediamine triacetate by K5CoIIIW12O40, Fe(phen) sup3+inf3 and Fe(bipy) sup3+inf3 have been studied. Each reaction is first order with respect to the oxidant and the reductant, but retarded by [H+] in the 0.20–1.60 mol dm −3 range. Simple electron exchanges are thought to occur, leading to the decarboxylation of the substrate.
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Ayoko, G.A., Iyun, J.F. & Mamman, S. Oxidation of N-(2-hydroxyethyl)ethylenediamine triacetate by tris(polypyridy)iron(III) complexes and the dodecatungstocobaltate(III) ion. Transition Met Chem 18, 475–477 (1993). https://doi.org/10.1007/BF00136607
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DOI: https://doi.org/10.1007/BF00136607